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MIL-160 as an Adsorbent for Atmospheric Water Harvesting

Author

Listed:
  • Marina Solovyeva

    (Boreskov Institute of Catalysis, Ac. Lavrentiev av. 5, 630055 Novosiborsk, Russia)

  • Irina Krivosheeva

    (Boreskov Institute of Catalysis, Ac. Lavrentiev av. 5, 630055 Novosiborsk, Russia
    Department of Natural Sciences, Novosibirsk State University, 630090 Novosibirsk, Russia)

  • Larisa Gordeeva

    (Boreskov Institute of Catalysis, Ac. Lavrentiev av. 5, 630055 Novosiborsk, Russia)

  • Yuri Aristov

    (Boreskov Institute of Catalysis, Ac. Lavrentiev av. 5, 630055 Novosiborsk, Russia)

Abstract

Nowadays, the rapidly growing population, climate change, and environment pollution put heavy pressure on fresh water resources. The atmosphere is the immense worldwide and available water source. The Adsorptive Water Harvesting from the Atmosphere (AWHA) method is considered a promising alternative to desalination technologies for remote arid regions. The development of novel adsorbents with advanced water-adsorption properties is a prerequisite for practical realization of this method. Metal–organic frameworks (MOFs) are a novel class of porous crystalline solids that bring a great potential for AWHA due to their extremely high specific surface area, porosity, and tailored adsorption properties. This work addresses MIL-160 as a water adsorbent for AWHA. The water-adsorption equilibrium of MIL-160 was studied by volumetric method, the isosteric heat of adsorption was calculated, and finally, the potential of MIL-160 for AWHA was evaluated for climatic conditions of the deserts of Saudi Arabia, Mongolia, the Sahara, Atacama, and Mojave as reference arid regions. MIL-160 was shown to ensure a maximum specific water productivity of 0.31–0.33 g H2O /g ads per cycle. High fractions of water extracted (0.90–0.98) and collected (0.48–0.97) could be achieved at a regeneration temperature of 80 °C with natural cooling of the condenser by ambient air. The specific energy consumption for water production varied from 3.5 to 6.8 kJ/g, which is acceptable if solar heat is used to drive the desorption. The AWHA method employing MIL-160 is a promising way to achieve a fresh water supply in remote arid areas.

Suggested Citation

  • Marina Solovyeva & Irina Krivosheeva & Larisa Gordeeva & Yuri Aristov, 2021. "MIL-160 as an Adsorbent for Atmospheric Water Harvesting," Energies, MDPI, vol. 14(12), pages 1-15, June.
    • Handle: RePEc:gam:jeners:v:14:y:2021:i:12:p:3586-:d:576190
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    References listed on IDEAS

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    1. Talaat, M.A. & Awad, M.M. & Zeidan, E.B. & Hamed, A.M., 2018. "Solar-powered portable apparatus for extracting water from air using desiccant solution," Renewable Energy, Elsevier, vol. 119(C), pages 662-674.
    2. Hamed, Ahmed M, 2000. "Absorption–regeneration cycle for production of water from air-theoretical approach," Renewable Energy, Elsevier, vol. 19(4), pages 625-635.
    3. Gordeeva, Larisa G. & Solovyeva, Marina V. & Sapienza, Alessio & Aristov, Yuri I., 2020. "Potable water extraction from the atmosphere: Potential of MOFs," Renewable Energy, Elsevier, vol. 148(C), pages 72-80.
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    Cited by:

    1. Marcin Sosnowski & Jaroslaw Krzywanski & Norbert Skoczylas, 2022. "Adsorption Desalination and Cooling Systems: Advances in Design, Modeling and Performance," Energies, MDPI, vol. 15(11), pages 1-6, May.
    2. Ahmed S. Alsaman & Ahmed A. Hassan & Ehab S. Ali & Ramy H. Mohammed & Alaa E. Zohir & Ayman M. Farid & Ayman M. Zakaria Eraqi & Hamdy H. El-Ghetany & Ahmed A. Askalany, 2022. "Hybrid Solar-Driven Desalination/Cooling Systems: Current Situation and Future Trend," Energies, MDPI, vol. 15(21), pages 1-25, October.

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