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Optimization of the Relative Humidity of Reactant Gases in Hydrogen Fuel Cells Using Dynamic Impedance Measurements

Author

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  • Ewa Janicka

    (Department of Electrochemistry, Corrosion and Materials Engineering, Faculty of Chemistry, Gdansk University of Technology, 11/12 Narutowicza, 80-233 Gdansk, Poland)

  • Michal Mielniczek

    (Department of Electrochemistry, Corrosion and Materials Engineering, Faculty of Chemistry, Gdansk University of Technology, 11/12 Narutowicza, 80-233 Gdansk, Poland)

  • Lukasz Gawel

    (Department of Electrochemistry, Corrosion and Materials Engineering, Faculty of Chemistry, Gdansk University of Technology, 11/12 Narutowicza, 80-233 Gdansk, Poland)

  • Kazimierz Darowicki

    (Department of Electrochemistry, Corrosion and Materials Engineering, Faculty of Chemistry, Gdansk University of Technology, 11/12 Narutowicza, 80-233 Gdansk, Poland)

Abstract

Water management is a key factor affecting the efficiency of proton exchange membrane fuel cells (PEMFCs). The currently used monitoring methods of PEMFCs provide limited information about which processes or components that humidity has a significant impact upon. Herein, we propose the use of a novel approach of impedance measurements using a multi-sinusoidal perturbation signal, which enables impedance measurements under dynamic operating conditions. The manuscript presents the effect of the relative humidity (RH) of the reactants on the instantaneous impedance of the middle cell in the PEMFC stack as a function of the current load. Analysis of changes in the values of equivalent circuit elements was carried out to determine which process determines the stack’s performance depending on the load range of the fuel cell during operation. Comprehensive impedance analysis showed that to ensure optimal cell operation, the humidity of the reactants should be adjusted depending on the load level. The results showed that at low-current loads, the humidity of gases should be at least 50%, while at high-current loads, the cell should operate optimally at a gas humidity of 30% or lower. The presented methodology provides an important tool for optimizing and monitoring the operation of fuel cells.

Suggested Citation

  • Ewa Janicka & Michal Mielniczek & Lukasz Gawel & Kazimierz Darowicki, 2021. "Optimization of the Relative Humidity of Reactant Gases in Hydrogen Fuel Cells Using Dynamic Impedance Measurements," Energies, MDPI, vol. 14(11), pages 1-11, May.
  • Handle: RePEc:gam:jeners:v:14:y:2021:i:11:p:3038-:d:561160
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    References listed on IDEAS

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    1. Park, Jaeman & Oh, Hwanyeong & Lee, Yoo Il & Min, Kyoungdoug & Lee, Eunsook & Jyoung, Jy-Young, 2016. "Effect of the pore size variation in the substrate of the gas diffusion layer on water management and fuel cell performance," Applied Energy, Elsevier, vol. 171(C), pages 200-212.
    2. Ferreira, Rui B. & Falcão, D.S. & Oliveira, V.B. & Pinto, A.M.F.R., 2017. "1D+3D two-phase flow numerical model of a proton exchange membrane fuel cell," Applied Energy, Elsevier, vol. 203(C), pages 474-495.
    3. Panha, Karachakorn & Fowler, Michael & Yuan, Xiao-Zi & Wang, Haijiang, 2012. "Accelerated durability testing via reactants relative humidity cycling on PEM fuel cells," Applied Energy, Elsevier, vol. 93(C), pages 90-97.
    4. Pei, Pucheng & Li, Yuehua & Xu, Huachi & Wu, Ziyao, 2016. "A review on water fault diagnosis of PEMFC associated with the pressure drop," Applied Energy, Elsevier, vol. 173(C), pages 366-385.
    5. Li, Yuehua & Pei, Pucheng & Wu, Ziyao & Ren, Peng & Jia, Xiaoning & Chen, Dongfang & Huang, Shangwei, 2018. "Approaches to avoid flooding in association with pressure drop in proton exchange membrane fuel cells," Applied Energy, Elsevier, vol. 224(C), pages 42-51.
    6. Chen Zhang & Wen Li & Mingruo Hu & Xiaofang Cheng & Kai He & Lei Mao, 2020. "A Comparative Study of Using Polarization Curve Models in Proton Exchange Membrane Fuel Cell Degradation Analysis," Energies, MDPI, vol. 13(15), pages 1-16, July.
    7. Li, Yuehua & Pei, Pucheng & Wu, Ziyao & Xu, Huachi & Chen, Dongfang & Huang, Shangwei, 2017. "Novel approach to determine cathode two-phase-flow pressure drop of proton exchange membrane fuel cell and its application on water management," Applied Energy, Elsevier, vol. 190(C), pages 713-724.
    8. Ying Tian & Qiang Zou & Jin Han, 2021. "Data-Driven Fault Diagnosis for Automotive PEMFC Systems Based on the Steady-State Identification," Energies, MDPI, vol. 14(7), pages 1-17, March.
    9. Ikechukwu S. Anyanwu & Yuze Hou & Wenmiao Chen & Fengwen Pan & Qing Du & Jin Xuan & Kui Jiao, 2019. "Numerical Investigation of Liquid Water Transport Dynamics in Novel Hybrid Sinusoidal Flow Channel Designs for PEMFC," Energies, MDPI, vol. 12(21), pages 1-20, October.
    10. Antonio Sorrentino & Kai Sundmacher & Tanja Vidakovic-Koch, 2020. "Polymer Electrolyte Fuel Cell Degradation Mechanisms and Their Diagnosis by Frequency Response Analysis Methods: A Review," Energies, MDPI, vol. 13(21), pages 1-28, November.
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    Cited by:

    1. Arkadiusz Szewczyk & Łukasz Gaweł & Kazimierz Darowicki & Janusz Smulko, 2021. "Assessment of Fuel Cells’ State of Health by Low-Frequency Noise Measurements," Energies, MDPI, vol. 14(24), pages 1-11, December.
    2. Hoang Nghia Vu & Dinh Hoang Trinh & Dat Truong Le Tri & Sangseok Yu, 2023. "Bypass Configurations of Membrane Humidifiers for Water Management in PEM Fuel Cells," Energies, MDPI, vol. 16(19), pages 1-17, October.
    3. Sarjuni, C.A. & Lim, B.H. & Majlan, E.H. & Rosli, M.I., 2024. "A review: Fluid dynamic and mass transport behaviour in a proton exchange membrane fuel cell stack," Renewable and Sustainable Energy Reviews, Elsevier, vol. 193(C).

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