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Use of Gas Adsorption and Inversion Methods for Shale Pore Structure Characterization

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  • Bryan X. Medina-Rodriguez

    (Department of Chemical Engineering, University of Wyoming, Laramie, WY 82071, USA)

  • Vladimir Alvarado

    (Department of Chemical Engineering, University of Wyoming, Laramie, WY 82071, USA)

Abstract

The analysis of porosity and pore structure of shale rocks has received special attention in the last decades as unconventional reservoir hydrocarbons have become a larger parcel of the oil and gas market. A variety of techniques are available to provide a satisfactory description of these porous media. Some techniques are based on saturating the porous rock with a fluid to probe the pore structure. In this sense, gases have played an important role in porosity and pore structure characterization, particularly for the analysis of pore size and shapes and storage or intake capacity. In this review, we discuss the use of various gases, with emphasis on N 2 and CO 2 , for characterization of shale pore architecture. We describe the state of the art on the related inversion methods for processing the corresponding isotherms and the procedure to obtain surface area and pore-size distribution. The state of the art is based on the collation of publications in the last 10 years. Limitations of the gas adsorption technique and the associated inversion methods as well as the most suitable scenario for its application are presented in this review. Finally, we discuss the future of gas adsorption for shale characterization, which we believe will rely on hybridization with other techniques to overcome some of the limitations.

Suggested Citation

  • Bryan X. Medina-Rodriguez & Vladimir Alvarado, 2021. "Use of Gas Adsorption and Inversion Methods for Shale Pore Structure Characterization," Energies, MDPI, vol. 14(10), pages 1-24, May.
    • Handle: RePEc:gam:jeners:v:14:y:2021:i:10:p:2880-:d:555930
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    References listed on IDEAS

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    1. Yujie Yuan & Reza Rezaee, 2019. "Comparative Porosity and Pore Structure Assessment in Shales: Measurement Techniques, Influencing Factors and Implications for Reservoir Characterization," Energies, MDPI, vol. 12(11), pages 1-14, May.
    2. Chen, Shangbin & Zhu, Yanming & Wang, Hongyan & Liu, Honglin & Wei, Wei & Fang, Junhua, 2011. "Shale gas reservoir characterisation: A typical case in the southern Sichuan Basin of China," Energy, Elsevier, vol. 36(11), pages 6609-6616.
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    Cited by:

    1. Xiaoyan Zou & Xianqing Li & Jizhen Zhang & Huantong Li & Man Guo & Pei Zhao, 2021. "Characteristics of Pore Structure and Gas Content of the Lower Paleozoic Shale from the Upper Yangtze Plate, South China," Energies, MDPI, vol. 14(22), pages 1-29, November.
    2. Danlong Li & Meiyan Fu & Yun Huang & Dong Wu & Rui Xue, 2021. "The Characteristics and Main Controlling Factors for the Formation of Micropores in Shale from the Niutitang Formation, Wenshuicun Section, Southwest China," Energies, MDPI, vol. 14(23), pages 1-19, November.

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