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Halide Pb-Free Double–Perovskites: Ternary vs. Quaternary Stoichiometry

Author

Listed:
  • Maurizia Palummo

    (Dipartimento di Fisica and INFN, Universitá di Roma “Tor Vergata”, Via della Ricerca Scientifica 1, 00133 Roma, Italy)

  • Daniele Varsano

    (Centro S3, Istituto Nanoscienze-Consiglio Nazionale delle Ricerche (CNR-NANO), Via Campi 213/A, 41125 Modena, Italy)

  • Eduardo Berríos

    (Instituto de Química y Bioquímica, Facultad de Ciencias, Universidad de Valparaíso, Avenida Gran Bretaña, 1111 Playa Ancha, Valparaíso 2360102, Chile)

  • Koichi Yamashita

    (Element Strategy Initiative for Catalysts and Batteries (ESICB), Kyoto University, Nishikyo-ku, Kyoto 615-8245, Japan)

  • Giacomo Giorgi

    (Department of Civil and Environmental Engineering, University of Perugia (DICA), Via G. Duranti, 93, 06125 Perugia, Italy
    CNR-SCITEC, 06123 Perugia, Italy)

Abstract

In view of their applicability in optoelectronics, we review here the relevant structural, electronic, and optical features of the inorganic Pb-free halide perovskite class. In particular, after discussing the reasons that have motivated their introduction in opposition to their more widely investigated organic-inorganic counterparts, we highlight milestones already achieved in their synthesis and characterization and show how the use of ab initio ground and excited state methods is relevant in predicting their properties and in disclosing yet unsolved issues which characterize both ternary and quaternary stoichiometry double-perovskites.

Suggested Citation

  • Maurizia Palummo & Daniele Varsano & Eduardo Berríos & Koichi Yamashita & Giacomo Giorgi, 2020. "Halide Pb-Free Double–Perovskites: Ternary vs. Quaternary Stoichiometry," Energies, MDPI, vol. 13(14), pages 1-28, July.
    • Handle: RePEc:gam:jeners:v:13:y:2020:i:14:p:3516-:d:381728
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    References listed on IDEAS

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