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Large guanidinium cation mixed with methylammonium in lead iodide perovskites for 19% efficient solar cells

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  • Alexander D. Jodlowski

    (Ecole Polytechnique Fédérale de Lausanne (EPFL)
    Instituto Universitario de Investigación en Química Fina y Nanoquímica IUQFN, Universidad de Córdoba, Campus de Rabanales, Edificio Marie Curie)

  • Cristina Roldán-Carmona

    (Ecole Polytechnique Fédérale de Lausanne (EPFL))

  • Giulia Grancini

    (Ecole Polytechnique Fédérale de Lausanne (EPFL))

  • Manuel Salado

    (Ecole Polytechnique Fédérale de Lausanne (EPFL)
    Abengoa Research, Abengoa, C/ Energía Solar no. 1)

  • Maryline Ralaiarisoa

    (Humboldt-Universität zu Berlin, Institut für Physik & IRIS Adlershof
    Devision Renewable Energies)

  • Shahzada Ahmad

    (Abengoa Research, Abengoa, C/ Energía Solar no. 1)

  • Norbert Koch

    (Humboldt-Universität zu Berlin, Institut für Physik & IRIS Adlershof
    Devision Renewable Energies)

  • Luis Camacho

    (Instituto Universitario de Investigación en Química Fina y Nanoquímica IUQFN, Universidad de Córdoba, Campus de Rabanales, Edificio Marie Curie)

  • Gustavo de Miguel

    (Instituto Universitario de Investigación en Química Fina y Nanoquímica IUQFN, Universidad de Córdoba, Campus de Rabanales, Edificio Marie Curie)

  • Mohammad Khaja Nazeeruddin

    (Ecole Polytechnique Fédérale de Lausanne (EPFL))

Abstract

Organic–inorganic lead halide perovskites have shown photovoltaic performances above 20% in a range of solar cell architectures while offering simple and low-cost processability. Despite the multiple ionic compositions that have been reported so far, the presence of organic constituents is an essential element in all of the high-efficiency formulations, with the methylammonium and formamidinium cations being the sole efficient options available to date. In this study, we demonstrate improved material stability after the incorporation of a large organic cation, guanidinium, into the MAPbI3 crystal structure, which delivers average power conversion efficiencies over 19%, and stabilized performance for 1,000 h under continuous light illumination, a fundamental step within the perovskite field.

Suggested Citation

  • Alexander D. Jodlowski & Cristina Roldán-Carmona & Giulia Grancini & Manuel Salado & Maryline Ralaiarisoa & Shahzada Ahmad & Norbert Koch & Luis Camacho & Gustavo de Miguel & Mohammad Khaja Nazeeruddi, 2017. "Large guanidinium cation mixed with methylammonium in lead iodide perovskites for 19% efficient solar cells," Nature Energy, Nature, vol. 2(12), pages 972-979, December.
    • Handle: RePEc:nat:natene:v:2:y:2017:i:12:d:10.1038_s41560-017-0054-3
    DOI: 10.1038/s41560-017-0054-3
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    Cited by:

    1. Yurui Wang & Renxing Lin & Xiaoyu Wang & Chenshuaiyu Liu & Yameen Ahmed & Zilong Huang & Zhibin Zhang & Hongjiang Li & Mei Zhang & Yuan Gao & Haowen Luo & Pu Wu & Han Gao & Xuntian Zheng & Manya Li & , 2023. "Oxidation-resistant all-perovskite tandem solar cells in substrate configuration," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    2. Takeo Oku & Satsuki Kandori & Masaya Taguchi & Atsushi Suzuki & Masanobu Okita & Satoshi Minami & Sakiko Fukunishi & Tomoharu Tachikawa, 2020. "Polysilane-Inserted Methylammonium Lead Iodide Perovskite Solar Cells Doped with Formamidinium and Potassium," Energies, MDPI, vol. 13(18), pages 1-11, September.
    3. Huang, Gongyi & Liang, Ying & Sun, Xiaofang & Xu, Chuanzhong & Yu, Fei, 2020. "Analyzing S-Shaped I–V characteristics of solar cells by solving three-diode lumped-parameter equivalent circuit model explicitly," Energy, Elsevier, vol. 212(C).
    4. Maurizia Palummo & Daniele Varsano & Eduardo Berríos & Koichi Yamashita & Giacomo Giorgi, 2020. "Halide Pb-Free Double–Perovskites: Ternary vs. Quaternary Stoichiometry," Energies, MDPI, vol. 13(14), pages 1-28, July.
    5. Nicolae Filipoiu & Tudor Luca Mitran & Dragos Victor Anghel & Mihaela Florea & Ioana Pintilie & Andrei Manolescu & George Alexandru Nemnes, 2021. "Investigation of Opto-Electronic Properties and Stability of Mixed-Cation Mixed-Halide Perovskite Materials with Machine-Learning Implementation," Energies, MDPI, vol. 14(17), pages 1-19, September.
    6. Pietro Caprioglio & Joel A. Smith & Robert D. J. Oliver & Akash Dasgupta & Saqlain Choudhary & Michael D. Farrar & Alexandra J. Ramadan & Yen-Hung Lin & M. Greyson Christoforo & James M. Ball & Jonas , 2023. "Open-circuit and short-circuit loss management in wide-gap perovskite p-i-n solar cells," Nature Communications, Nature, vol. 14(1), pages 1-13, December.

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