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CO 2 Electrochemical Reduction by Exohedral N-Pyridine Decorated Metal-Free Carbon Nanotubes

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  • Giulia Tuci

    (Institute of Chemistry of OrganoMetallic Compounds (ICCOM-CNR) and Consorzio INSTM, Via Madonna del Piano, 10-50019 Sesto F.no, Florence, Italy)

  • Jonathan Filippi

    (Institute of Chemistry of OrganoMetallic Compounds (ICCOM-CNR) and Consorzio INSTM, Via Madonna del Piano, 10-50019 Sesto F.no, Florence, Italy)

  • Andrea Rossin

    (Institute of Chemistry of OrganoMetallic Compounds (ICCOM-CNR) and Consorzio INSTM, Via Madonna del Piano, 10-50019 Sesto F.no, Florence, Italy)

  • Lapo Luconi

    (Institute of Chemistry of OrganoMetallic Compounds (ICCOM-CNR) and Consorzio INSTM, Via Madonna del Piano, 10-50019 Sesto F.no, Florence, Italy)

  • Cuong Pham-Huu

    (Institute of Chemistry and Processes for Energy, Environment and Health (ICPEES), UMR 7515 CNRS-University of Strasbourg (UdS), 25, rue Becquerel, CEDEX 02, 67087 Strasbourg, France)

  • Dmitry Yakhvarov

    (Alexander Butlerov Institute of Chemistry, Kazan Federal University, 420008 Kazan, Russia)

  • Francesco Vizza

    (Institute of Chemistry of OrganoMetallic Compounds (ICCOM-CNR) and Consorzio INSTM, Via Madonna del Piano, 10-50019 Sesto F.no, Florence, Italy)

  • Giuliano Giambastiani

    (Institute of Chemistry of OrganoMetallic Compounds (ICCOM-CNR) and Consorzio INSTM, Via Madonna del Piano, 10-50019 Sesto F.no, Florence, Italy
    Institute of Chemistry and Processes for Energy, Environment and Health (ICPEES), UMR 7515 CNRS-University of Strasbourg (UdS), 25, rue Becquerel, CEDEX 02, 67087 Strasbourg, France
    Alexander Butlerov Institute of Chemistry, Kazan Federal University, 420008 Kazan, Russia)

Abstract

Electrochemical CO 2 reduction reaction (CO 2 RR) to fuels and chemicals represents nowadays one of the most challenging solutions for renewable energy storage and utilization. Among the possible reaction pathways, CO 2 -to-CO conversion is the first (2e − ) reduction step towards the production of a key-feedstock that holds great relevance for chemical industry. In this report we describe the electrocatalytic CO 2 -to-CO reduction by a series of tailored N-decorated carbon nanotubes to be employed as chemoselective metal-free electrocatalysts. The choice of an exohedral functionalization tool for the introduction of defined N-groups at the outer surface of carbon nanomaterials warrants a unique control on N-configuration and electronic charge density distribution at the dangling heterocycles. A comparative electrochemical screening of variably N-substituted carbon nanomaterials in CO 2 RR together with an analysis of the electronic charge density distribution at each heterocycle have suggested the existence of a coherent descriptor for the catalyst’s CO faradaic efficiency (FE CO ). Evidence allows to infer that N-configuration (N-pyridinic vs. N-pyrrolic) of exohedral dopants and electronic charge density distribution at the N-neighboring carbon atoms of each heterocycle are directly engaged in the activation and stabilization of CO 2 and its reduction intermediates.

Suggested Citation

  • Giulia Tuci & Jonathan Filippi & Andrea Rossin & Lapo Luconi & Cuong Pham-Huu & Dmitry Yakhvarov & Francesco Vizza & Giuliano Giambastiani, 2020. "CO 2 Electrochemical Reduction by Exohedral N-Pyridine Decorated Metal-Free Carbon Nanotubes," Energies, MDPI, vol. 13(11), pages 1-15, May.
  • Handle: RePEc:gam:jeners:v:13:y:2020:i:11:p:2703-:d:364173
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    References listed on IDEAS

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    1. Bijandra Kumar & Mohammad Asadi & Davide Pisasale & Suman Sinha-Ray & Brian A. Rosen & Richard Haasch & Jeremiah Abiade & Alexander L. Yarin & Amin Salehi-Khojin, 2013. "Renewable and metal-free carbon nanofibre catalysts for carbon dioxide reduction," Nature Communications, Nature, vol. 4(1), pages 1-8, December.
    2. Mohammadi, Amin & Mehrpooya, Mehdi, 2018. "A comprehensive review on coupling different types of electrolyzer to renewable energy sources," Energy, Elsevier, vol. 158(C), pages 632-655.
    3. Jingjie Wu & Sichao Ma & Jing Sun & Jake I. Gold & ChandraSekhar Tiwary & Byoungsu Kim & Lingyang Zhu & Nitin Chopra & Ihab N. Odeh & Robert Vajtai & Aaron Z. Yu & Raymond Luo & Jun Lou & Guqiao Ding , 2016. "A metal-free electrocatalyst for carbon dioxide reduction to multi-carbon hydrocarbons and oxygenates," Nature Communications, Nature, vol. 7(1), pages 1-6, December.
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    Cited by:

    1. Wen Yan & Ming Ma, 2023. "Electrochemical Conversion of Carbon Dioxide," Energies, MDPI, vol. 16(5), pages 1-3, February.

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