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Thermodynamic Performance of a Double-Effect Absorption Refrigeration Cycle Based on a Ternary Working Pair: Lithium Bromide + Ionic Liquids + Water

Author

Listed:
  • Yiqun Li

    (School of Energy and Environmental Engineering, University of Science and Technology Beijing, Beijing 100083, China)

  • Na Li

    (State Grid Energy Conservation Service CO., Ltd., Beijing 100052, China)

  • Chunhuan Luo

    (School of Energy and Environmental Engineering, University of Science and Technology Beijing, Beijing 100083, China
    Beijing Engineering Research Center for Energy Saving and Environmental Protection, University of Science and Technology Beijing, Beijing 100083, China)

  • Qingquan Su

    (School of Energy and Environmental Engineering, University of Science and Technology Beijing, Beijing 100083, China
    Beijing Engineering Research Center for Energy Saving and Environmental Protection, University of Science and Technology Beijing, Beijing 100083, China)

Abstract

For an absorption cycle, a ternary working pair LiBr–[BMIM]Cl(2.5:1)/H 2 O was proposed as a new working pair to replace LiBr/H 2 O. The thermodynamic properties including specific heat capacity, specific enthalpy, density, and viscosity were systematically measured and fitted by the least-squares method. The thermodynamic performance of a double-effect absorption refrigeration cycle based on LiBr–[BMIM]Cl(2.5:1)/H 2 O was investigated under different refrigeration temperatures from 5 °C to 12 °C. Results showed that the ternary working pair LiBr–[BMIM]Cl(2.5:1)/H 2 O had advantages in the operating temperature range and corrosivity. Compared with LiBr/H 2 O, the operating temperature range was 20 °C larger, and the corrosion rates of carbon steel and copper were reduced by more than 50% at 453.15 K. However, the double-effect absorption refrigeration cycle with LiBr–[BMIM]Cl(2.5:1)/H 2 O achieved a coefficient of performance ( COPc ) from 1.09 to 1.46 and an exergetic coefficient of performance ( ECOPc ) from 0.244 to 0.238, which were smaller than those based on LiBr/H 2 O due to the higher generation temperature and larger flow ratio.

Suggested Citation

  • Yiqun Li & Na Li & Chunhuan Luo & Qingquan Su, 2019. "Thermodynamic Performance of a Double-Effect Absorption Refrigeration Cycle Based on a Ternary Working Pair: Lithium Bromide + Ionic Liquids + Water," Energies, MDPI, vol. 12(21), pages 1-21, November.
    • Handle: RePEc:gam:jeners:v:12:y:2019:i:21:p:4200-:d:283272
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    References listed on IDEAS

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    1. Yin, Juan & Shi, Lin & Zhu, Ming-Shan & Han, Li-Zhong, 2000. "Performance analysis of an absorption heat transformer with different working fluid combinations," Applied Energy, Elsevier, vol. 67(3), pages 281-292, November.
    2. Sun, Jian & Fu, Lin & Zhang, Shigang, 2012. "A review of working fluids of absorption cycles," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(4), pages 1899-1906.
    3. Garousi Farshi, L. & Mahmoudi, S.M.S. & Rosen, M.A., 2013. "Exergoeconomic comparison of double effect and combined ejector-double effect absorption refrigeration systems," Applied Energy, Elsevier, vol. 103(C), pages 700-711.
    4. Medrano, M. & Bourouis, M. & Coronas, A., 2001. "Double-lift absorption refrigeration cycles driven by low-temperature heat sources using organic fluid mixtures as working pairs," Applied Energy, Elsevier, vol. 68(2), pages 173-185, February.
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    2. Zhou, Xinpei & Chen, Wei & Zhang, Bin, 2022. "Proposed hybrid system with integrated SOFC, gas turbine, and compressor-assisted absorption refrigerator using [mmim]DMP/CH3OH as working fluid," Energy, Elsevier, vol. 261(PB).

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