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Influence of NaCl Concentration on Food-Waste Biochar Structure and Templating Effects

Author

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  • Ye-Eun Lee

    (Division of Environment and Plant Engineering, Korea Institute of Civil Engineering and Building Technology, 283 Goyang- daero, Ilsanseo-gu Goyang-si, Gyeonggi-do 10223, Korea
    Department of Construction Environment Engineering, University of Science and Technology, 217 Gajeong-ro, Yuseong-gu, Daejeon 34113, Korea)

  • Jun-Ho Jo

    (Division of Environment and Plant Engineering, Korea Institute of Civil Engineering and Building Technology, 283 Goyang- daero, Ilsanseo-gu Goyang-si, Gyeonggi-do 10223, Korea)

  • I-Tae Kim

    (Division of Environment and Plant Engineering, Korea Institute of Civil Engineering and Building Technology, 283 Goyang- daero, Ilsanseo-gu Goyang-si, Gyeonggi-do 10223, Korea)

  • Yeong-Seok Yoo

    (Division of Environment and Plant Engineering, Korea Institute of Civil Engineering and Building Technology, 283 Goyang- daero, Ilsanseo-gu Goyang-si, Gyeonggi-do 10223, Korea
    Department of Construction Environment Engineering, University of Science and Technology, 217 Gajeong-ro, Yuseong-gu, Daejeon 34113, Korea)

Abstract

Food-waste-derived biochar structures obtained through pyrolysis and with different NaCl concentrations were investigated. Increased NaCl concentration in the samples inhibited cellulose and lignin decomposition, ultimately increasing the biochar yield by 2.7% for 20%-NaCl concentration. NaCl added in solution state exhibited templating effects, with maximum increases in the Brunauer–Emmett–Teller (BET) surface area and pore volume of 1.23 to 3.50 m 2 ∙g −1 and 0.002 to 0.007 cm 3 ∙g −1 , respectively, after washing. Adding a high concentration (20%) of NaCl reduced the BET surface area. In contrast, the mean pore diameter increased owing to the increased NaCl clustering area. Increased NaCl clustering with increased added NaCl was shown to have positive effects on NaCl removal by washing. Furthermore, as the NaCl adhered to the KCl scattered in the food waste, a high NaCl concentration also had positive effects on KCl removal. This study reports on an investigation on the effects of varying NaCl concentrations injected in solution form on the structure of food-waste biochar during pyrolysis. The templating effect was considered using both added NaCl and NaCl already contained in the food waste, with implementation of a desalination process essential for food-waste treatment for recycling.

Suggested Citation

  • Ye-Eun Lee & Jun-Ho Jo & I-Tae Kim & Yeong-Seok Yoo, 2018. "Influence of NaCl Concentration on Food-Waste Biochar Structure and Templating Effects," Energies, MDPI, vol. 11(9), pages 1-16, September.
  • Handle: RePEc:gam:jeners:v:11:y:2018:i:9:p:2341-:d:167920
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    References listed on IDEAS

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    1. Ye-Eun Lee & Jun-Ho Jo & I-Tae Kim & Yeong-Seok Yoo, 2017. "Chemical Characteristics and NaCl Component Behavior of Biochar Derived from the Salty Food Waste by Water Flushing," Energies, MDPI, vol. 10(10), pages 1-15, October.
    2. Chamseddine Guizani & Mejdi Jeguirim & Sylvie Valin & Lionel Limousy & Sylvain Salvador, 2017. "Biomass Chars: The Effects of Pyrolysis Conditions on Their Morphology, Structure, Chemical Properties and Reactivity," Energies, MDPI, vol. 10(6), pages 1-18, June.
    3. Shi-Xiang Zhao & Na Ta & Xu-Dong Wang, 2017. "Effect of Temperature on the Structural and Physicochemical Properties of Biochar with Apple Tree Branches as Feedstock Material," Energies, MDPI, vol. 10(9), pages 1-15, August.
    4. Patrick Brassard & Stéphane Godbout & Vijaya Raghavan & Joahnn H. Palacios & Michèle Grenier & Dan Zegan, 2017. "The Production of Engineered Biochars in a Vertical Auger Pyrolysis Reactor for Carbon Sequestration," Energies, MDPI, vol. 10(3), pages 1-15, February.
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    Cited by:

    1. Mejdi Jeguirim & Lionel Limousy, 2019. "Biomass Chars: Elaboration, Characterization and Applications II," Energies, MDPI, vol. 12(3), pages 1-6, January.
    2. Ye-Eun Lee & Yoonah Jeong & Dong-Chul Shin & Kwang-Ho Ahn & Jin-Hong Jung & I-Tae Kim, 2021. "Fabrication of Mg-Doped Sargassum Biochar for Phosphate and Ammonium Recovery," Sustainability, MDPI, vol. 13(22), pages 1-15, November.

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