IDEAS home Printed from https://ideas.repec.org/a/eee/rensus/v82y2018ip3p2408-2425.html
   My bibliography  Save this article

Traversing the history of solid catalysts for heterogeneous synthesis of 5-hydroxymethylfurfural from carbohydrate sugars: A review

Author

Listed:
  • Agarwal, Bhumica
  • Kailasam, Kamalakannan
  • Sangwan, Rajender Singh
  • Elumalai, Sasikumar

Abstract

5-Hydroxymethylfurfural (HMF) belongs to the group of “drop-in biofuels” and platform molecule of prime importance. Synthesis of HMF from various sugar sources has traversed a long span of time and has witnessed various modifications viz., use of heterogeneous catalysts over homogeneous catalysts, employment of organic phase over aqueous, introduction of biphasic systems to overcome side reaction limitations and still counting. Every modification has been carried out with the objective of improved selectivity and product synthesis, cost and energy optimization, and a shift towards greener process over existing methods. Use of lignocellulosic biomass instead of commercial sugars also finds applicability in direct HMF synthesis along with levulinic acid, furfural etc. However, low yields from these abundant, cheap and readily available sugar sources are still ideal for scale-up of the process strategies. Among large pool of studies available in this area, current review presents the advantages imparted towards HMF synthesis with the advent of heterogeneous catalysis over the course of time and various reaction systems evolved to meet the steeping demand of HMF, specifically from common carbohydrate sources. Special attention has been paid to understand the mechanism of modifications imparted to various solid catalysts for improved HMF synthesis.

Suggested Citation

  • Agarwal, Bhumica & Kailasam, Kamalakannan & Sangwan, Rajender Singh & Elumalai, Sasikumar, 2018. "Traversing the history of solid catalysts for heterogeneous synthesis of 5-hydroxymethylfurfural from carbohydrate sugars: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 2408-2425.
    • Handle: RePEc:eee:rensus:v:82:y:2018:i:p3:p:2408-2425
    DOI: 10.1016/j.rser.2017.08.088
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S1364032117312327
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.rser.2017.08.088?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Alipour, Siamak & Omidvarborna, Hamid & Kim, Dong-Shik, 2017. "A review on synthesis of alkoxymethyl furfural, a biofuel candidate," Renewable and Sustainable Energy Reviews, Elsevier, vol. 71(C), pages 908-926.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Cai, Xin & Wang, Zhichao & Ye, Yueyuan & Wang, Duo & Zhang, Zhaoxia & Zheng, Zhifeng & Liu, Yunquan & Li, Shuirong, 2021. "Conversion of chitin biomass into 5-hydroxymethylfurfural: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 150(C).
    2. Du, Ya-Peng & Tian, Xin-Yu & Zheng, Xiao-Ping & Chai, Yu & Zhang, Yu-Cang & Zheng, Yan-Zhen, 2024. "Efficient preparation of 5-hydroxymethylfurfural from cellulose via one-step combination of mechanical and chemical pre-treatment," Renewable Energy, Elsevier, vol. 229(C).
    3. Zhao, Yuan & Lu, Kaifeng & Xu, Hao & Zhu, Lingjun & Wang, Shurong, 2021. "A critical review of recent advances in the production of furfural and 5-hydroxymethylfurfural from lignocellulosic biomass through homogeneous catalytic hydrothermal conversion," Renewable and Sustainable Energy Reviews, Elsevier, vol. 139(C).
    4. Yang, Fengli & Weng, Jushi & Ding, Jiajing & Zhao, Zhiyan & Qin, Lizhen & Xia, Feifei, 2020. "Effective conversion of saccharides into hydroxymethylfurfural catalyzed by a natural clay, attapulgite," Renewable Energy, Elsevier, vol. 151(C), pages 829-836.
    5. Daniel Carreira Batalha & Márcio José da Silva, 2021. "Biodiesel Production over Niobium-Containing Catalysts: A Review," Energies, MDPI, vol. 14(17), pages 1-33, September.
    6. Wang, Ping & Liu, Chaoqi & Chang, Juan & Yin, Qingqiang & Huang, Weiwei & Liu, Yang & Dang, Xiaowei & Gao, Tianzeng & Lu, Fushan, 2019. "Effect of physicochemical pretreatments plus enzymatic hydrolysis on the composition and morphologic structure of corn straw," Renewable Energy, Elsevier, vol. 138(C), pages 502-508.
    7. Zuo, Miao & Jia, Wenlong & Feng, Yunchao & Zeng, Xianhai & Tang, Xing & Sun, Yong & Lin, Lu, 2021. "Effective selectivity conversion of glucose to furan chemicals in the aqueous deep eutectic solvent," Renewable Energy, Elsevier, vol. 164(C), pages 23-33.
    8. Wang, Zhihao & Xia, Shengpeng & Wang, Xiaobo & Fan, Yuyang & Zhao, Kun & Wang, Shuang & Zhao, Zengli & Zheng, Anqing, 2024. "Catalytic production of 5-hydroxymethylfurfural from lignocellulosic biomass: Recent advances, challenges and opportunities," Renewable and Sustainable Energy Reviews, Elsevier, vol. 196(C).
    9. Wiranarongkorn, K. & Im-orb, K. & Patcharavorachot, Y. & Maréchal, F. & Arpornwichanop, A., 2023. "Comparative techno-economic and energy analyses of integrated biorefinery processes of furfural and 5-hydroxymethylfurfural from biomass residue," Renewable and Sustainable Energy Reviews, Elsevier, vol. 175(C).
    10. Kirtika Kohli & Ravindra Prajapati & Brajendra K. Sharma, 2019. "Bio-Based Chemicals from Renewable Biomass for Integrated Biorefineries," Energies, MDPI, vol. 12(2), pages 1-40, January.
    11. Hu, Di & Zhang, Man & Xu, Hong & Wang, Yuchen & Yan, Kai, 2021. "Recent advance on the catalytic system for efficient production of biomass-derived 5-hydroxymethylfurfural," Renewable and Sustainable Energy Reviews, Elsevier, vol. 147(C).
    12. Tuan Hoang, Anh & Viet Pham, Van, 2021. "2-Methylfuran (MF) as a potential biofuel: A thorough review on the production pathway from biomass, combustion progress, and application in engines," Renewable and Sustainable Energy Reviews, Elsevier, vol. 148(C).
    13. Hu, Lei & Wu, Zhen & Jiang, Yetao & Wang, Xiaoyu & He, Aiyong & Song, Jie & Xu, Jiming & Zhou, Shouyong & Zhao, Yijiang & Xu, Jiaxing, 2020. "Recent advances in catalytic and autocatalytic production of biomass-derived 5-hydroxymethylfurfural," Renewable and Sustainable Energy Reviews, Elsevier, vol. 134(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Dowaki, Taishi & Guo, Haixin & Smith, Richard Lee, 2022. "Lignin-derived biochar solid acid catalyst for fructose conversion into 5-ethoxymethylfurfural," Renewable Energy, Elsevier, vol. 199(C), pages 1534-1542.
    2. Dowaki, Taishi & Guo, Haixin & Smith, Richard Lee, 2023. "Cascade conversion and kinetic modeling of glucose transformation into mixed-biofuels via lignin-derived Lewis-Brønsted acid biochars," Renewable Energy, Elsevier, vol. 217(C).
    3. Kalil Rahiman, M. & Santhoshkumar, S. & Subramaniam, D. & Avinash, A. & Pugazhendhi, Arivalagan, 2022. "Effects of oxygenated fuel pertaining to fuel analysis on diesel engine combustion and emission characteristics," Energy, Elsevier, vol. 239(PD).
    4. Zuo, Miao & Jia, Wenlong & Feng, Yunchao & Zeng, Xianhai & Tang, Xing & Sun, Yong & Lin, Lu, 2021. "Effective selectivity conversion of glucose to furan chemicals in the aqueous deep eutectic solvent," Renewable Energy, Elsevier, vol. 164(C), pages 23-33.
    5. Thombal, Priyanka Raju & Thombal, Raju S. & Han, Sung Soo, 2021. "Comprehensive study on the catalytic methods for furyl alkane synthesis: A promising biodiesel precursor," Renewable and Sustainable Energy Reviews, Elsevier, vol. 135(C).
    6. Sitepu, Eko K. & Heimann, Kirsten & Raston, Colin L. & Zhang, Wei, 2020. "Critical evaluation of process parameters for direct biodiesel production from diverse feedstock," Renewable and Sustainable Energy Reviews, Elsevier, vol. 123(C).
    7. Yan, Puxiang & Wang, Haiyong & Liao, Yuhe & Wang, Chenguang, 2023. "Zeolite catalysts for the valorization of biomass into platform compounds and biochemicals/biofuels: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 178(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:rensus:v:82:y:2018:i:p3:p:2408-2425. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/600126/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.