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In-situ transesterification of rapeseed and cost indicators for biodiesel production

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  • Abo El-Enin, S.A.
  • Attia, N.K.
  • El-Ibiari, N.N.
  • El-Diwani, G.I.
  • El-Khatib, K.M.

Abstract

In the present work the alkali in-situ transesterification of rapeseed with methanol for the production of biodiesel fuel was studied. Experiments were designed to determine how variations in molar ratio of methanol to oil in seeds, amount of alkali catalyst, time and temperature affected the yield. Good results (90%) conversion of seed lipid to fatty acid methyl ester was obtained at 0.02N catalyst concentration, 720/1 methanol to rapeseed oil molar ratio, 1h reaction time and 65°C reaction temperature. The results were in agreement with the values measured by 1H NMR spectroscopy. A mass balance and a preliminary feasibility study were investigated. A techno-economic analysis of the process for production of biodiesel from rapeseed with a capacity of 50,000t/yr was presented to investigate the profitability indicators of the production capacity. The techno-economic indicators showed that total capital investment of $16,065,000, gross profit/year of $14,630,300, and percentage simple rate of return (%SRR) was 79.5% for a constant estimated price of $945/t while the specific biodiesel prices for SRR% of 10 and 50 were $722 and $850 respectively.

Suggested Citation

  • Abo El-Enin, S.A. & Attia, N.K. & El-Ibiari, N.N. & El-Diwani, G.I. & El-Khatib, K.M., 2013. "In-situ transesterification of rapeseed and cost indicators for biodiesel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 18(C), pages 471-477.
    • Handle: RePEc:eee:rensus:v:18:y:2013:i:c:p:471-477
    DOI: 10.1016/j.rser.2012.10.033
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    References listed on IDEAS

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    1. Atapour, Mehdi & Kariminia, Hamid-Reza, 2011. "Characterization and transesterification of Iranian bitter almond oil for biodiesel production," Applied Energy, Elsevier, vol. 88(7), pages 2377-2381, July.
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    1. Sitepu, Eko K. & Heimann, Kirsten & Raston, Colin L. & Zhang, Wei, 2020. "Critical evaluation of process parameters for direct biodiesel production from diverse feedstock," Renewable and Sustainable Energy Reviews, Elsevier, vol. 123(C).
    2. Chakraborty, Rajat & Gupta, Abhishek.K. & Chowdhury, Ratul, 2014. "Conversion of slaughterhouse and poultry farm animal fats and wastes to biodiesel: Parametric sensitivity and fuel quality assessment," Renewable and Sustainable Energy Reviews, Elsevier, vol. 29(C), pages 120-134.
    3. Violeta Makareviciene & Egle Sendzikiene & Milda Gumbyte, 2020. "Application of Simultaneous Oil Extraction and Transesterification in Biodiesel Fuel Synthesis: A Review," Energies, MDPI, vol. 13(9), pages 1-16, May.
    4. Gang Xu & Feifei Liang & Yongping Yang & Yue Hu & Kai Zhang & Wenyi Liu, 2014. "An Improved CO 2 Separation and Purification System Based on Cryogenic Separation and Distillation Theory," Energies, MDPI, vol. 7(5), pages 1-19, May.
    5. Go, Alchris Woo & Sutanto, Sylviana & Ong, Lu Ki & Tran-Nguyen, Phuong Lan & Ismadji, Suryadi & Ju, Yi-Hsu, 2016. "Developments in in-situ (trans) esterification for biodiesel production: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 60(C), pages 284-305.
    6. Migle Santaraite & Egle Sendzikiene & Violeta Makareviciene & Kiril Kazancev, 2020. "Biodiesel Production by Lipase-Catalyzed in Situ Transesterification of Rapeseed Oil Containing a High Free Fatty Acid Content with Ethanol in Diesel Fuel Media," Energies, MDPI, vol. 13(10), pages 1-12, May.

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