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Engineered graphene-based mixed matrix membranes to boost CO2 separation performance: Latest developments and future prospects

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  • Pazani, Farhang
  • Salehi Maleh, Mohammad
  • Shariatifar, Mehrdad
  • Jalaly, Maisam
  • Sadrzadeh, Mohtada
  • Rezakazemi, Mashallah

Abstract

Mixed matrix membranes (MMMs) have drawn a great deal of attention as a desirable strategy for efficient gas separation. In this context, graphene-based nanosheets (GNSs) with exceptional structural specifications and molecular separation properties enjoy the promising application in MMMs fabrication. These features endow polymeric matrices with high permselectivity and thermo mechanical stability. Herein, the most recent advances on the application of GNSs-based MMMs for CO2 separation are comprehensively reviewed. Interfacial morphologies and separation mechanisms that affect virtual gas transport properties in the presence of GNS MMMs are proposed. The key factors influencing gas separation concerning GNSs characteristics, including type, lateral size, in-plane pores, and interlayer channels of GNSs, are discussed. As the major part of this review, rational strategies to boost gas separation performance of GNS-MMMs, such as employing various surface modifications and incorporation of other additives as third components, are provided in detail. Finally, the remaining challenges and future outlook of GNSs-based MMMs are outlined.

Suggested Citation

  • Pazani, Farhang & Salehi Maleh, Mohammad & Shariatifar, Mehrdad & Jalaly, Maisam & Sadrzadeh, Mohtada & Rezakazemi, Mashallah, 2022. "Engineered graphene-based mixed matrix membranes to boost CO2 separation performance: Latest developments and future prospects," Renewable and Sustainable Energy Reviews, Elsevier, vol. 160(C).
    • Handle: RePEc:eee:rensus:v:160:y:2022:i:c:s136403212200212x
    DOI: 10.1016/j.rser.2022.112294
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    References listed on IDEAS

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    1. Sreedhar, I. & Vaidhiswaran, R. & Kamani, Bansi. M. & Venugopal, A., 2017. "Process and engineering trends in membrane based carbon capture," Renewable and Sustainable Energy Reviews, Elsevier, vol. 68(P1), pages 659-684.
    2. In Kyu Moon & Junghyun Lee & Rodney S. Ruoff & Hyoyoung Lee, 2010. "Reduced graphene oxide by chemical graphitization," Nature Communications, Nature, vol. 1(1), pages 1-6, December.
    3. Rezakazemi, Mashallah & Arabi Shamsabadi, Ahmad & Lin, Haiqing & Luis, Patricia & Ramakrishna, Seeram & Aminabhavi, Tejraj M., 2021. "Sustainable MXenes-based membranes for highly energy-efficient separations," Renewable and Sustainable Energy Reviews, Elsevier, vol. 143(C).
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