Recent Advances in Small-Scale Carbon Capture Systems for Micro-Combined Heat and Power Applications

To restrict global warming and relieve climate change, the world economy requires to decarbonize and reduce carbon dioxide (CO 2 ) emissions to net-zero by mid-century. Carbon capture and storage (CCS), and carbon capture and utilization (CCU), by which CO 2 emissions are captured from sources such as fossil power generation and combustion processes, and further either reused or stored, are recognized worldwide as key technologies for global warming mitigation. This paper provides a review of the latest published literature on small-scale carbon capture (CC) systems as applied in micro combined heat and power cogeneration systems for use in buildings. Previous studies have investigated a variety of small- or micro-scale combined heat and power configurations defined by their prime mover for CC integration. These include the micro gas turbine, the hybrid micro gas turbine and solid-state fuel cell system, and the biomass-fired organic Rankine cycle, all of which have been coupled with a post-combustion, amine-based absorption plant. After these configurations are defined, their performance is discussed. Considerations for optimizing the overall system parameters are identified using the same sources. The paper considers optimization of modifications to the micro gas turbine cycles with exhaust gas recirculation, humidification, and more advanced energy integration for optimal use of waste heat. Related investigations are based largely on numerical studies, with some preliminary experimental work undertaken on the Turbec T100 micro gas turbine. A brief survey is presented of some additional topics, including storage and utilization options, commercially available CC technologies, and direct atmospheric capture. Based on the available literature, it was found that carbon capture for small-scale systems introduces a large energy penalty due to the low concentration of CO 2 in exhaust gases. Further development is required to decrease the energy loss from CC for economic feasibility on a small scale. For the micro gas turbine, exhaust gas recirculation, selective gas recirculation, and humidification were shown to improve overall system economic performance and efficiency. However, the highest global efficiencies were achieved by leveraging turbine exhaust waste heat to reduce the thermal energy requirement for solvent regeneration in the CC plant during low- or zero-heating loads. It was shown that although humidification cycles improved micro gas turbine cycle efficiencies, this may not be the best option to improve global efficiency if turbine waste heat is properly leveraged based on heating demands. The biomass-organic Rankine cycle and hybrid micro gas turbine, and solid-state fuel cell systems with CC, are in early developmental stages and require more research to assess their feasibility. However, the hybrid micro gas turbine and solid-state fuel cell energy system with CC was shown numerically to reach high global efficiency (51.4% LHV). It was also shown that the biomass-fired organic Rankine cycle system could result in negative emissions when coupled with a CC plant. In terms of costs, it was found that utilization through enhanced oil recovery was a promising strategy to offset the cost of carbon capture. Direct atmospheric capture was determined to be less economically feasible than capture from concentrated point sources; however, it has the benefit of negative carbon emissions.