IDEAS home Printed from https://ideas.repec.org/a/eee/rensus/v133y2020ics1364032120305359.html
   My bibliography  Save this article

Progress and potential of metal-organic frameworks (MOFs) as novel desiccants for built environment control: A review

Author

Listed:
  • Zu, Kan
  • Qin, Menghao
  • Cui, Shuqing

Abstract

The regulation of the balance of the sensible and latent loads remains a critical problem for built environment control. Unlike the traditional vapor compression system that features high-energy consumption and environmental-unfriendly processes, desiccants represent an alternative air-conditioning method that takes advantage of the low-grade energy, decreases the energy consumption and even employs use of water vapor. Though the desiccant-based systems can achieve spatial moisture transfer through the periodic adsorption/desorption process, however, the water-stable desiccants with high water uptake and mildly reversible adsorption are required, and the traditional desiccants cannot meet these requirements. In this respect, metal-organic frameworks (MOFs), possessing a variety of structures and precise functional ability to optimize their properties, are promising porous materials exhibiting high potential for rational design and sorption-based applications. In this review, intrinsic properties and prevalent water adsorption mechanisms of the potential micro/mesoporous MOF desiccants have been elucidated. Subsequently, the selection criteria of the promising MOF desiccants for water loading removal from air in the built environment is proposed and some currently available water-stable MOFs based on different working humidity ranges have been analyzed for the potential humidity control from the aspects of microstructure, isotherms and regeneration conditions. Finally, approaches for screening the well-suited MOFs from material and system levels is presented. Overall, the cases of actual applications in the active or passive way have confirmed that MOF-based systems can effectively regulate the humidity load within the desirable range, thus, underlining the high potential of large-scale applications in the near future.

Suggested Citation

  • Zu, Kan & Qin, Menghao & Cui, Shuqing, 2020. "Progress and potential of metal-organic frameworks (MOFs) as novel desiccants for built environment control: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 133(C).
    • Handle: RePEc:eee:rensus:v:133:y:2020:i:c:s1364032120305359
    DOI: 10.1016/j.rser.2020.110246
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S1364032120305359
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.rser.2020.110246?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Yuan, Yanping & Zhang, Haiquan & Yang, Fan & Zhang, Nan & Cao, Xiaoling, 2016. "Inorganic composite sorbents for water vapor sorption: A research progress," Renewable and Sustainable Energy Reviews, Elsevier, vol. 54(C), pages 761-776.
    2. Hua, L.J. & Ge, T.S. & Wang, R.Z., 2019. "Extremely high efficient heat pump with desiccant coated evaporator and condenser," Energy, Elsevier, vol. 170(C), pages 569-579.
    3. Daou, K. & Wang, R.Z. & Xia, Z.Z., 2006. "Desiccant cooling air conditioning: a review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 10(2), pages 55-77, April.
    4. La, D. & Dai, Y.J. & Li, Y. & Wang, R.Z. & Ge, T.S., 2010. "Technical development of rotary desiccant dehumidification and air conditioning: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(1), pages 130-147, January.
    5. Vivekh, P. & Kumja, M. & Bui, D.T. & Chua, K.J., 2018. "Recent developments in solid desiccant coated heat exchangers – A review," Applied Energy, Elsevier, vol. 229(C), pages 778-803.
    6. Ge, T.S. & Dai, Y.J. & Wang, R.Z., 2014. "Review on solar powered rotary desiccant wheel cooling system," Renewable and Sustainable Energy Reviews, Elsevier, vol. 39(C), pages 476-497.
    7. Karmakar, Avishek & Prabakaran, Vivekh & Zhao, Dan & Chua, Kian Jon, 2020. "A review of metal-organic frameworks (MOFs) as energy-efficient desiccants for adsorption driven heat-transformation applications," Applied Energy, Elsevier, vol. 269(C).
    8. Chua, K.J. & Chou, S.K. & Yang, W.M. & Yan, J., 2013. "Achieving better energy-efficient air conditioning – A review of technologies and strategies," Applied Energy, Elsevier, vol. 104(C), pages 87-104.
    9. Jagirdar, Mrinal & Lee, Poh Seng, 2018. "Mathematical modeling and performance evaluation of a desiccant coated fin-tube heat exchanger," Applied Energy, Elsevier, vol. 212(C), pages 401-415.
    10. Kabeel, A.E., 2009. "Adsorption–desorption operations of multilayer desiccant packed bed for dehumidification applications," Renewable Energy, Elsevier, vol. 34(1), pages 255-265.
    11. Zheng, X. & Ge, T.S. & Wang, R.Z., 2014. "Recent progress on desiccant materials for solid desiccant cooling systems," Energy, Elsevier, vol. 74(C), pages 280-294.
    12. Xu, F. & Bian, Z.F. & Ge, T.S. & Dai, Y.J. & Wang, C.H. & Kawi, S., 2019. "Analysis on solar energy powered cooling system based on desiccant coated heat exchanger using metal-organic framework," Energy, Elsevier, vol. 177(C), pages 211-221.
    13. Zhang, Tao & Liu, Xiaohua & Jiang, Yi, 2014. "Development of temperature and humidity independent control (THIC) air-conditioning systems in China—A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 29(C), pages 793-803.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Ge, Lurong & Ge, Tianshu & Wang, Ruzhu, 2022. "Facile synthesis of Al-based MOF and its applications in desiccant coated heat exchangers," Renewable and Sustainable Energy Reviews, Elsevier, vol. 157(C).
    2. Chen, Wanhe & Yin, Yonggao & Zhao, Xingwang & Fan, Fangsu & Cao, Bowen & Ji, Qiang & Xu, Guoying, 2023. "Sepiolite based humidity-control coating specially for alleviate the condensation problem of radiant cooling panel," Energy, Elsevier, vol. 272(C).
    3. Shahvari, Saba Zakeri & Clark, Jordan D., 2023. "Approaching theoretical maximum energy performance for desiccant dehumidification using staged and optimized metal-organic frameworks," Applied Energy, Elsevier, vol. 331(C).
    4. Chung, Jun Yeob & Park, Myeong Hyeon & Hong, Seong Ho & Baek, Jaehyun & Han, Changho & Lee, Sewon & Kang, Yong Tae & Kim, Yongchan, 2023. "Comparative performance evaluation of multi-objective optimized desiccant wheels coated with MIL-100 (Fe) and silica gel composite," Energy, Elsevier, vol. 283(C).
    5. Abdelkareem, Mohammad Ali & Abbas, Qaisar & Sayed, Enas Taha & Shehata, N. & Parambath, J.B.M. & Alami, Abdul Hai & Olabi, A.G., 2024. "Recent advances on metal-organic frameworks (MOFs) and their applications in energy conversion devices: Comprehensive review," Energy, Elsevier, vol. 299(C).
    6. Zu, Kan & Qin, Menghao, 2022. "Optimization of the hygrothermal performance of novel metal-organic framework (MOF) based humidity pump: A CFD approach," Energy, Elsevier, vol. 259(C).
    7. Mohammed, Ramy H. & Rezk, Ahmed & Askalany, Ahmed & Ali, Ehab S. & Zohir, A.E. & Sultan, Muhammad & Ghazy, Mohamed & Abdelkareem, Mohammad Ali & Olabi, A.G., 2021. "Metal-organic frameworks in cooling and water desalination: Synthesis and application," Renewable and Sustainable Energy Reviews, Elsevier, vol. 149(C).
    8. Harrouz, Jean Paul & Ghali, Kamel & Keniar, Khoudor & Ghaddar, Nesreen, 2023. "Numerical and experimental investigation of thermosyphon-driven liquid desiccant loop performance for sustainable indoor humidity removal," Applied Energy, Elsevier, vol. 343(C).
    9. Ge, Lurong & Feng, Yaohui & Wu, Jiarong & Wang, Ruzhu & Ge, Tianshu, 2024. "Performance evaluation of MIL-101(Cr) based desiccant-coated heat exchangers for efficient dehumidification," Energy, Elsevier, vol. 289(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Feng, Y.H. & Dai, Y.J. & Wang, R.Z. & Ge, T.S., 2022. "Insights into desiccant-based internally-cooled dehumidification using porous sorbents: From a modeling viewpoint," Applied Energy, Elsevier, vol. 311(C).
    2. Shamim, Jubair A. & Hsu, Wei-Lun & Paul, Soumyadeep & Yu, Lili & Daiguji, Hirofumi, 2021. "A review of solid desiccant dehumidifiers: Current status and near-term development goals in the context of net zero energy buildings," Renewable and Sustainable Energy Reviews, Elsevier, vol. 137(C).
    3. Vivekh, P. & Kumja, M. & Bui, D.T. & Chua, K.J., 2018. "Recent developments in solid desiccant coated heat exchangers – A review," Applied Energy, Elsevier, vol. 229(C), pages 778-803.
    4. Wang, Cong & Yang, Bianfeng & Ji, Xu & Zhang, Ren & Wu, Hailong, 2022. "Study on activated carbon/silica gel/lithium chloride composite desiccant for solid dehumidification," Energy, Elsevier, vol. 251(C).
    5. Hua, Lingji & Wang, Ruzhu, 2022. "An exergy analysis and parameter optimization of solid desiccant heat pumps recovering the condensation heat for desiccant regeneration and heat transfer enhancement," Energy, Elsevier, vol. 238(PB).
    6. Zhang, Yu & Wang, Weining & Zheng, Xu & Cai, Jinliang, 2024. "Recent progress on composite desiccants for adsorption-based dehumidification," Energy, Elsevier, vol. 302(C).
    7. Ge, Lurong & Ge, Tianshu & Wang, Ruzhu, 2022. "Facile synthesis of Al-based MOF and its applications in desiccant coated heat exchangers," Renewable and Sustainable Energy Reviews, Elsevier, vol. 157(C).
    8. Gao, D.C. & Sun, Y.J. & Ma, Z. & Ren, H., 2021. "A review on integration and design of desiccant air-conditioning systems for overall performance improvements," Renewable and Sustainable Energy Reviews, Elsevier, vol. 141(C).
    9. Ge, Lurong & Feng, Yaohui & Wu, Jiarong & Wang, Ruzhu & Ge, Tianshu, 2024. "Performance evaluation of MIL-101(Cr) based desiccant-coated heat exchangers for efficient dehumidification," Energy, Elsevier, vol. 289(C).
    10. Venegas, Tomas & Qu, Ming & Nawaz, Kashif & Wang, Lingshi, 2021. "Critical review and future prospects for desiccant coated heat exchangers: Materials, design, and manufacturing," Renewable and Sustainable Energy Reviews, Elsevier, vol. 151(C).
    11. Vivekh, P. & Bui, D.T. & Islam, M.R. & Zaw, K. & Chua, K.J., 2020. "Experimental performance and energy efficiency investigation of composite superabsorbent polymer and potassium formate coated heat exchangers," Applied Energy, Elsevier, vol. 275(C).
    12. Zouaoui, Ahlem & Zili-Ghedira, Leila & Ben Nasrallah, Sassi, 2016. "Open solid desiccant cooling air systems: A review and comparative study," Renewable and Sustainable Energy Reviews, Elsevier, vol. 54(C), pages 889-917.
    13. Jani, D.B. & Mishra, Manish & Sahoo, P.K., 2017. "Application of artificial neural network for predicting performance of solid desiccant cooling systems – A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 80(C), pages 352-366.
    14. Chen, W.D. & Vivekh, P. & Liu, M.Z. & Kumja, M. & Chua, K.J., 2021. "Energy improvement and performance prediction of desiccant coated dehumidifiers based on dimensional and scaling analysis," Applied Energy, Elsevier, vol. 303(C).
    15. Mahmood, Muhammad H. & Sultan, Muhammad & Miyazaki, Takahiko & Koyama, Shigeru & Maisotsenko, Valeriy S., 2016. "Overview of the Maisotsenko cycle – A way towards dew point evaporative cooling," Renewable and Sustainable Energy Reviews, Elsevier, vol. 66(C), pages 537-555.
    16. Karmakar, Avishek & Prabakaran, Vivekh & Zhao, Dan & Chua, Kian Jon, 2020. "A review of metal-organic frameworks (MOFs) as energy-efficient desiccants for adsorption driven heat-transformation applications," Applied Energy, Elsevier, vol. 269(C).
    17. Muhammad Aleem & Ghulam Hussain & Muhammad Sultan & Takahiko Miyazaki & Muhammad H. Mahmood & Muhammad I. Sabir & Abdul Nasir & Faizan Shabir & Zahid M. Khan, 2020. "Experimental Investigation of Desiccant Dehumidification Cooling System for Climatic Conditions of Multan (Pakistan)," Energies, MDPI, vol. 13(21), pages 1-23, October.
    18. Abou-Ziyan, H. & Abd El-Raheim, D. & Mahmoud, O. & Fatouh, M., 2017. "Performance characteristics of thin-multilayer activated alumina bed," Applied Energy, Elsevier, vol. 190(C), pages 29-42.
    19. Zeng, Cheng & Liu, Shuli & Shukla, Ashish, 2017. "A review on the air-to-air heat and mass exchanger technologies for building applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 75(C), pages 753-774.
    20. Shahvari, Saba Zakeri & Clark, Jordan D., 2023. "Approaching theoretical maximum energy performance for desiccant dehumidification using staged and optimized metal-organic frameworks," Applied Energy, Elsevier, vol. 331(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:rensus:v:133:y:2020:i:c:s1364032120305359. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/600126/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.