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Progress and potential of metal-organic frameworks (MOFs) as novel desiccants for built environment control: A review

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  • Zu, Kan
  • Qin, Menghao
  • Cui, Shuqing

Abstract

The regulation of the balance of the sensible and latent loads remains a critical problem for built environment control. Unlike the traditional vapor compression system that features high-energy consumption and environmental-unfriendly processes, desiccants represent an alternative air-conditioning method that takes advantage of the low-grade energy, decreases the energy consumption and even employs use of water vapor. Though the desiccant-based systems can achieve spatial moisture transfer through the periodic adsorption/desorption process, however, the water-stable desiccants with high water uptake and mildly reversible adsorption are required, and the traditional desiccants cannot meet these requirements. In this respect, metal-organic frameworks (MOFs), possessing a variety of structures and precise functional ability to optimize their properties, are promising porous materials exhibiting high potential for rational design and sorption-based applications. In this review, intrinsic properties and prevalent water adsorption mechanisms of the potential micro/mesoporous MOF desiccants have been elucidated. Subsequently, the selection criteria of the promising MOF desiccants for water loading removal from air in the built environment is proposed and some currently available water-stable MOFs based on different working humidity ranges have been analyzed for the potential humidity control from the aspects of microstructure, isotherms and regeneration conditions. Finally, approaches for screening the well-suited MOFs from material and system levels is presented. Overall, the cases of actual applications in the active or passive way have confirmed that MOF-based systems can effectively regulate the humidity load within the desirable range, thus, underlining the high potential of large-scale applications in the near future.

Suggested Citation

  • Zu, Kan & Qin, Menghao & Cui, Shuqing, 2020. "Progress and potential of metal-organic frameworks (MOFs) as novel desiccants for built environment control: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 133(C).
    • Handle: RePEc:eee:rensus:v:133:y:2020:i:c:s1364032120305359
    DOI: 10.1016/j.rser.2020.110246
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    1. Karmakar, Avishek & Prabakaran, Vivekh & Zhao, Dan & Chua, Kian Jon, 2020. "A review of metal-organic frameworks (MOFs) as energy-efficient desiccants for adsorption driven heat-transformation applications," Applied Energy, Elsevier, vol. 269(C).
    2. Yuan, Yanping & Zhang, Haiquan & Yang, Fan & Zhang, Nan & Cao, Xiaoling, 2016. "Inorganic composite sorbents for water vapor sorption: A research progress," Renewable and Sustainable Energy Reviews, Elsevier, vol. 54(C), pages 761-776.
    3. Kabeel, A.E., 2009. "Adsorption–desorption operations of multilayer desiccant packed bed for dehumidification applications," Renewable Energy, Elsevier, vol. 34(1), pages 255-265.
    4. Chua, K.J. & Chou, S.K. & Yang, W.M. & Yan, J., 2013. "Achieving better energy-efficient air conditioning – A review of technologies and strategies," Applied Energy, Elsevier, vol. 104(C), pages 87-104.
    5. Jagirdar, Mrinal & Lee, Poh Seng, 2018. "Mathematical modeling and performance evaluation of a desiccant coated fin-tube heat exchanger," Applied Energy, Elsevier, vol. 212(C), pages 401-415.
    6. La, D. & Dai, Y.J. & Li, Y. & Wang, R.Z. & Ge, T.S., 2010. "Technical development of rotary desiccant dehumidification and air conditioning: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(1), pages 130-147, January.
    7. Hua, L.J. & Ge, T.S. & Wang, R.Z., 2019. "Extremely high efficient heat pump with desiccant coated evaporator and condenser," Energy, Elsevier, vol. 170(C), pages 569-579.
    8. Zheng, X. & Ge, T.S. & Wang, R.Z., 2014. "Recent progress on desiccant materials for solid desiccant cooling systems," Energy, Elsevier, vol. 74(C), pages 280-294.
    9. Vivekh, P. & Kumja, M. & Bui, D.T. & Chua, K.J., 2018. "Recent developments in solid desiccant coated heat exchangers – A review," Applied Energy, Elsevier, vol. 229(C), pages 778-803.
    10. Ge, T.S. & Dai, Y.J. & Wang, R.Z., 2014. "Review on solar powered rotary desiccant wheel cooling system," Renewable and Sustainable Energy Reviews, Elsevier, vol. 39(C), pages 476-497.
    11. Daou, K. & Wang, R.Z. & Xia, Z.Z., 2006. "Desiccant cooling air conditioning: a review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 10(2), pages 55-77, April.
    12. Xu, F. & Bian, Z.F. & Ge, T.S. & Dai, Y.J. & Wang, C.H. & Kawi, S., 2019. "Analysis on solar energy powered cooling system based on desiccant coated heat exchanger using metal-organic framework," Energy, Elsevier, vol. 177(C), pages 211-221.
    13. Zhang, Tao & Liu, Xiaohua & Jiang, Yi, 2014. "Development of temperature and humidity independent control (THIC) air-conditioning systems in China—A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 29(C), pages 793-803.
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    3. Shahvari, Saba Zakeri & Clark, Jordan D., 2023. "Approaching theoretical maximum energy performance for desiccant dehumidification using staged and optimized metal-organic frameworks," Applied Energy, Elsevier, vol. 331(C).
    4. Chung, Jun Yeob & Park, Myeong Hyeon & Hong, Seong Ho & Baek, Jaehyun & Han, Changho & Lee, Sewon & Kang, Yong Tae & Kim, Yongchan, 2023. "Comparative performance evaluation of multi-objective optimized desiccant wheels coated with MIL-100 (Fe) and silica gel composite," Energy, Elsevier, vol. 283(C).
    5. Abdelkareem, Mohammad Ali & Abbas, Qaisar & Sayed, Enas Taha & Shehata, N. & Parambath, J.B.M. & Alami, Abdul Hai & Olabi, A.G., 2024. "Recent advances on metal-organic frameworks (MOFs) and their applications in energy conversion devices: Comprehensive review," Energy, Elsevier, vol. 299(C).
    6. Zu, Kan & Qin, Menghao, 2022. "Optimization of the hygrothermal performance of novel metal-organic framework (MOF) based humidity pump: A CFD approach," Energy, Elsevier, vol. 259(C).
    7. Mohammed, Ramy H. & Rezk, Ahmed & Askalany, Ahmed & Ali, Ehab S. & Zohir, A.E. & Sultan, Muhammad & Ghazy, Mohamed & Abdelkareem, Mohammad Ali & Olabi, A.G., 2021. "Metal-organic frameworks in cooling and water desalination: Synthesis and application," Renewable and Sustainable Energy Reviews, Elsevier, vol. 149(C).
    8. Harrouz, Jean Paul & Ghali, Kamel & Keniar, Khoudor & Ghaddar, Nesreen, 2023. "Numerical and experimental investigation of thermosyphon-driven liquid desiccant loop performance for sustainable indoor humidity removal," Applied Energy, Elsevier, vol. 343(C).
    9. Ge, Lurong & Feng, Yaohui & Wu, Jiarong & Wang, Ruzhu & Ge, Tianshu, 2024. "Performance evaluation of MIL-101(Cr) based desiccant-coated heat exchangers for efficient dehumidification," Energy, Elsevier, vol. 289(C).

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