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Membrane separation processes for dehydration of bioethanol from fermentation broths: Recent developments, challenges, and prospects

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  • Khalid, Azqa
  • Aslam, Muhammad
  • Qyyum, Muhammad Abdul
  • Faisal, Abrar
  • Khan, Asim Laeeq
  • Ahmed, Faisal
  • Lee, Moonyong
  • Kim, Jeonghwan
  • Jang, Nulee
  • Chang, In Seop
  • Bazmi, Aqeel Ahmed
  • Yasin, Muhammad

Abstract

Bioethanol has garnered a great interest as a potential energy source, mainly due to its sustainable and green nature. Generally, bioethanol is produced through the microbial conversion of biomass and biomass derived syngas. However, the dehydration and purification steps for achieving fuel-grade ethanol from the microbial production process consume tremendous amounts of energy. This high energy consumption limits the feasibility of microbial ethanol production on the commercial scale. In this context, selection of an optimal technology for product separation is essential for successful commercialization of microbially produced bioethanol. This article presents the recent developments in dehydration and purification technologies for bioethanol production using distillation and membrane based separation. Distillation and pervaporation are analyzed on the basis of the overall energy requirement, consumption, and economics. Pervaporation-assisted distillation approaches are also examined from the perspective of process systems engineering, including factors affecting the system performance. Furthermore, the role of simulation in technological development along with available mathematical models is discussed, and commercial status of pervaporation based separation is presented. Finally, the current status of the existing technology, challenges, and future research directions are identified from the perspective of achieving process sustainability on the industrial scale. Economic comparison between distillation and different hybrid schemes revealed that integrating distillation with membrane based separation techniques reduce the bioethanol production cost. Moreover, hybrid schemes that combine distillation with pervaporation, and steam stripping with vapor permeation are proved to be the best combinations for the cheapest bioethanol production.

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  • Khalid, Azqa & Aslam, Muhammad & Qyyum, Muhammad Abdul & Faisal, Abrar & Khan, Asim Laeeq & Ahmed, Faisal & Lee, Moonyong & Kim, Jeonghwan & Jang, Nulee & Chang, In Seop & Bazmi, Aqeel Ahmed & Yasin, , 2019. "Membrane separation processes for dehydration of bioethanol from fermentation broths: Recent developments, challenges, and prospects," Renewable and Sustainable Energy Reviews, Elsevier, vol. 105(C), pages 427-443.
    • Handle: RePEc:eee:rensus:v:105:y:2019:i:c:p:427-443
    DOI: 10.1016/j.rser.2019.02.002
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    2. Hongshen Li & Hongrui Liu & Shizhong Li, 2021. "Feasibility Study on Bioethanol Production by One Phase Transition Separation Based on Advanced Solid-State Fermentation," Energies, MDPI, vol. 14(19), pages 1-14, October.
    3. Hongshen Li & Hongrui Liu & Yufang Li & Jilin Nan & Chen Shi & Shizhong Li, 2021. "Combined Vapor Permeation and Continuous Solid-State Distillation for Energy-Efficient Bioethanol Production," Energies, MDPI, vol. 14(8), pages 1-15, April.
    4. Khanongnuch, Ramita & Abubackar, Haris Nalakath & Keskin, Tugba & Gungormusler, Mine & Duman, Gozde & Aggarwal, Ayushi & Behera, Shishir Kumar & Li, Lu & Bayar, Büşra & Rene, Eldon R., 2022. "Bioprocesses for resource recovery from waste gases: Current trends and industrial applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 156(C).
    5. Bakhtyari, Ali & Bardool, Roghayeh & Rahimpour, Mohammad Reza & Iulianelli, Adolfo, 2021. "Dehydration of bio-alcohols in an enhanced membrane-assisted reactor: A rigorous sensitivity analysis and multi-objective optimization," Renewable Energy, Elsevier, vol. 177(C), pages 519-543.
    6. Farah Hadjkacem & Guillaume Pierre & Gwendoline Christophe & Jihen Elleuch & Imen Fendri & Zakaria Boual & Mohamed Didi Ould El Hadj & Zainab El Alaoui-Talibi & Cherkaoui El Modafar & Pascal Dubessay , 2022. "Bioconversion of the Brown Tunisian Seaweed Halopteris scoparia : Application to Energy," Energies, MDPI, vol. 15(12), pages 1-16, June.
    7. Mohsin Raza & Abrar Inayat & Ashfaq Ahmed & Farrukh Jamil & Chaouki Ghenai & Salman R. Naqvi & Abdallah Shanableh & Muhammad Ayoub & Ammara Waris & Young-Kwon Park, 2021. "Progress of the Pyrolyzer Reactors and Advanced Technologies for Biomass Pyrolysis Processing," Sustainability, MDPI, vol. 13(19), pages 1-42, October.

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