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Polyurethane/graphite nano-platelet composites for thermal energy storage

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  • Pielichowska, Kinga
  • Bieda, Jakub
  • Szatkowski, Piotr

Abstract

In this work new polyurethane-based phase change materials containing segments of poly(ethylene glycol) with average molar mass of 8000 g/mol with and without chain extender and modified with graphite nano-platelets have been fabricated and characterized. Structure, morphology and phase behaviour of these solid-solid phase change materials were investigated, as well as the thermal stability and conductivity. The heat of phase transition was in the range of 118.0–164.5 J/g for polyurethane without chain extender and 128.0–148.5 J/g for polyurethane with chain extender. The highest heat of phase transition and crystallinity were found for system modified with 0.3% of graphite nano-platelets in polyurethane without chain extender. Modulated differential scanning calorimetry results showed some changes in the phase transition behaviour and the crystallinity of the polyurethane matrix due to graphite nano-platelets confinement effect. Enhancements in the thermal stability in polyurethane modified with graphite nano-platelets, attributed to the barrier effect, were found based on thermogravimetric analysis data. The thermal conductivity increased with an increase of graphite nano-platelets content for both polyurethane systems, with and without chain extender, which is important for modern thermal energy storage applications.

Suggested Citation

  • Pielichowska, Kinga & Bieda, Jakub & Szatkowski, Piotr, 2016. "Polyurethane/graphite nano-platelet composites for thermal energy storage," Renewable Energy, Elsevier, vol. 91(C), pages 456-465.
    • Handle: RePEc:eee:renene:v:91:y:2016:i:c:p:456-465
    DOI: 10.1016/j.renene.2016.01.076
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    References listed on IDEAS

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    1. Fan, Liwu & Khodadadi, J.M., 2011. "Thermal conductivity enhancement of phase change materials for thermal energy storage: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(1), pages 24-46, January.
    2. Fan, Li-Wu & Fang, Xin & Wang, Xiao & Zeng, Yi & Xiao, Yu-Qi & Yu, Zi-Tao & Xu, Xu & Hu, Ya-Cai & Cen, Ke-Fa, 2013. "Effects of various carbon nanofillers on the thermal conductivity and energy storage properties of paraffin-based nanocomposite phase change materials," Applied Energy, Elsevier, vol. 110(C), pages 163-172.
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    1. Zhang, Sheng & Ocłoń, Paweł & Klemeš, Jiří Jaromír & Michorczyk, Piotr & Pielichowska, Kinga & Pielichowski, Krzysztof, 2022. "Renewable energy systems for building heating, cooling and electricity production with thermal energy storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 165(C).

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