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Carbon supported Ag nanoparticles with different particle size as cathode catalysts for anion exchange membrane direct glycerol fuel cells

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  • Wang, Zhichao
  • Xin, Le
  • Zhao, Xusheng
  • Qiu, Yang
  • Zhang, Zhiyong
  • Baturina, Olga A.
  • Li, Wenzhen

Abstract

The effect of Ag particle size on oxygen reduction reaction (ORR) at the cathode was investigated in anion exchange membrane direct glycerol fuel cells (AEM-DGFC) with oxygen as an oxidant. At the anode, high purity glycerol (99.8 wt%) or crude glycerol (88 wt%, from soybean biodiesel) was used as fuel, and commercial Pt/C served as the anode catalyst. A solution phase-based nanocapsule synthesis method was successfully developed to prepare the non-precious Ag/C cathode catalyst, with LiBEt3H as a reducing agent. XRD and TEM characterizations show that as-synthesized Ag nanoparticles (NP) with a size of 2–9 nm are well dispersed on the Vulcan XC-72 carbon black support. Commercial Ag nanoparticles with a size of 20–40 nm were also supported on carbon black as a control sample. The results show that higher peak power density was obtained in AEM-DGFC employing an Ag-NP catalyst with smaller particle size: nanocapsule made Ag-NP > commercial Ag-NP (Alfa Aesar, 99.9%). With the nanocapsule Ag-NP cathode catalyst, the peak power density and open circuit voltage (OCV) of AEM-DGFC with high-purity glycerol at 80 °C are 86 mW cm−2 and 0.73 V, respectively. These are much higher than 45 mW cm−2 and 0.68 V for the AEM-DGFC with the commercial Ag/C cathode catalyst, which can be attributed to the enhanced kinetics and reduced internal resistance. Directly fed with crude glycerol, the AEM-DGFC with the nanocapsule Ag-NP cathode catalyst shows an encouraging peak power density of 66 mW cm−2, which shows great potential of direct use of biodiesel waste fuel for electricity generation.

Suggested Citation

  • Wang, Zhichao & Xin, Le & Zhao, Xusheng & Qiu, Yang & Zhang, Zhiyong & Baturina, Olga A. & Li, Wenzhen, 2014. "Carbon supported Ag nanoparticles with different particle size as cathode catalysts for anion exchange membrane direct glycerol fuel cells," Renewable Energy, Elsevier, vol. 62(C), pages 556-562.
    • Handle: RePEc:eee:renene:v:62:y:2014:i:c:p:556-562
    DOI: 10.1016/j.renene.2013.08.005
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    1. Xuan, Jin & Leung, Michael K.H. & Leung, Dennis Y.C. & Ni, Meng, 2009. "A review of biomass-derived fuel processors for fuel cell systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 13(6-7), pages 1301-1313, August.
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    1. Deng, Hao & Wang, Dawei & Xie, Xu & Zhou, Yibo & Yin, Yan & Du, Qing & Jiao, Kui, 2016. "Modeling of hydrogen alkaline membrane fuel cell with interfacial effect and water management optimization," Renewable Energy, Elsevier, vol. 91(C), pages 166-177.
    2. Yang, Chun & Cao, Wei-Qin & Ji, Xiao-Feng & Wang, Jian & Zhong, Tao-Lin & Wang, Yu & Zhang, Qing, 2020. "In situ fuel phosphorylation facilitates the complete oxidation of glycerol in direct biomass cells," Renewable Energy, Elsevier, vol. 146(C), pages 699-704.

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