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Non-isothermal pyrolysis of the mixtures of waste automobile lubricating oil and polystyrene in a stirred batch reactor

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  • Kim, Seung-Soo
  • Kim, Jinsoo
  • Jeon, Jong-Ki
  • Park, Young-Kwon
  • Park, Chan-Jin

Abstract

Kinetic tests on pyrolysis of the mixture of waste automobile lubricating oil (WALO) and polystyrene (PS) were carried out with a thermogravimetric analysis (TGA) technique at a heating rate of 0.5 °C/min, 1.0 °C/min and 2.0 °C/min in a stirred batch reactor. WALO and PS were mainly decomposed 400–455 °C and 370–410 °C, respectively. The mixture of WALO and PS, however, was decomposed between 355 °C and 470 °C, and decomposition proceeded in two broad steps. The apparent activation energies for the pyrolysis of WALO/PS mixture were in the range of 176 kJ mol−1–369 kJ mol−1 at various conversions of 1–100%. The effect of heating rate on the product distribution was studied. The carbon number distribution of the produced oil shifted slightly to light hydrocarbons with a decrease in heating rate. The selectivity of hydrocarbons corresponding to the styrene monomer was high for the pyrolysis of the WALO/PS mixture.

Suggested Citation

  • Kim, Seung-Soo & Kim, Jinsoo & Jeon, Jong-Ki & Park, Young-Kwon & Park, Chan-Jin, 2013. "Non-isothermal pyrolysis of the mixtures of waste automobile lubricating oil and polystyrene in a stirred batch reactor," Renewable Energy, Elsevier, vol. 54(C), pages 241-247.
    • Handle: RePEc:eee:renene:v:54:y:2013:i:c:p:241-247
    DOI: 10.1016/j.renene.2012.08.001
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    References listed on IDEAS

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    1. Lam, Su Shiung & Russell, Alan D. & Chase, Howard A., 2010. "Microwave pyrolysis, a novel process for recycling waste automotive engine oil," Energy, Elsevier, vol. 35(7), pages 2985-2991.
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    1. Vuk Petronijević & Aleksandar Đorđević & Miladin Stefanović & Slavko Arsovski & Zdravko Krivokapić & Milan Mišić, 2020. "Energy Recovery through End-of-Life Vehicles Recycling in Developing Countries," Sustainability, MDPI, vol. 12(21), pages 1-26, October.
    2. Natacha Phetyim & Sommai Pivsa-Art, 2018. "Prototype Co-Pyrolysis of Used Lubricant Oil and Mixed Plastic Waste to Produce a Diesel-Like Fuel," Energies, MDPI, vol. 11(11), pages 1-11, November.

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