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Optimization and oxidative stability of biodiesel production from rice bran oil

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  • El Boulifi, N.
  • Bouaid, A.
  • Martinez, M.
  • Aracil, J.

Abstract

Biorefinery approach is introduced for the biodiesel production by utilizing low cost raw material, such as rice bran oil (RBO). The valorization of RBO was carried out by homogeneous transesterification process using response surface methodology (RSM) based on a two-variable central composition design (CCD). The process variables, temperature and catalyst concentration were found to have significant influence on biodiesel yield. The optimum combination derived via RSM for high ester yield (99.4%) was found to be 0.75% wt catalyst concentration at a reaction temperature of 45 °C. As biodiesel chemically is a long-chain alkyl methyl esters, its long-term fuel properties have become of great concern to the fuel industry. In order to determine the effects of long storage on oxidation stability, RBO biodiesel sample was stored for 24 months and the different physical–chemical properties were checked with respect to time. The results show that the acid value (AV), peroxide value (PV), and viscosity (ν) increased while the iodine value (IV) decreased. Based on results, correlations were obtained in terms of AV, IV, PV and ν as a function of time. Those correlations can be used to predict how long time biodiesel can safely be stored. AV, IV and PV of the biodiesel sample which was stored were within the limits in European biodiesel specifications (EN 14214).

Suggested Citation

  • El Boulifi, N. & Bouaid, A. & Martinez, M. & Aracil, J., 2013. "Optimization and oxidative stability of biodiesel production from rice bran oil," Renewable Energy, Elsevier, vol. 53(C), pages 141-147.
    • Handle: RePEc:eee:renene:v:53:y:2013:i:c:p:141-147
    DOI: 10.1016/j.renene.2012.11.005
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    1. Canakci, Mustafa & Erdil, Ahmet & Arcaklioglu, Erol, 2006. "Performance and exhaust emissions of a biodiesel engine," Applied Energy, Elsevier, vol. 83(6), pages 594-605, June.
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    5. Khairul Azly Zahan & Manabu Kano, 2018. "Biodiesel Production from Palm Oil, Its By-Products, and Mill Effluent: A Review," Energies, MDPI, vol. 11(8), pages 1-25, August.
    6. Sajjadi, Baharak & Raman, Abdul Aziz Abdul & Arandiyan, Hamidreza, 2016. "A comprehensive review on properties of edible and non-edible vegetable oil-based biodiesel: Composition, specifications and prediction models," Renewable and Sustainable Energy Reviews, Elsevier, vol. 63(C), pages 62-92.
    7. Tan, Yie Hua & Abdullah, Mohammad Omar & Nolasco-Hipolito, Cirilo & Ahmad Zauzi, Nur Syuhada, 2017. "Application of RSM and Taguchi methods for optimizing the transesterification of waste cooking oil catalyzed by solid ostrich and chicken-eggshell derived CaO," Renewable Energy, Elsevier, vol. 114(PB), pages 437-447.
    8. Praepilas Dujjanutat & Nithinun Srihanun & Papasanee Muanruksa & James Winterburn & Pakawadee Kaewkannetra, 2023. "Transesterification and Hydrotreating Reactions of Rice Bran Oil for Bio-Hydrogenated Diesel Production," Energies, MDPI, vol. 16(3), pages 1-14, January.
    9. Fernandes, David M. & Squissato, André L. & Lima, Alexandre F. & Richter, Eduardo M. & Munoz, Rodrigo A.A., 2019. "Corrosive character of Moringa oleifera Lam biodiesel exposed to carbon steel under simulated storage conditions," Renewable Energy, Elsevier, vol. 139(C), pages 1263-1271.
    10. Nesma M. Helal & Hesham F. Alharby & Basmah M. Alharbi & Atif. A. Bamagoos & Ahmed M. Hashim, 2020. "Thymelaea hirsuta and Echinops spinosus : Xerophytic Plants with High Potential for First-Generation Biodiesel Production," Sustainability, MDPI, vol. 12(3), pages 1-16, February.
    11. Saluja, Rajesh Kumar & Kumar, Vineet & Sham, Radhey, 2016. "Stability of biodiesel – A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 62(C), pages 866-881.

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