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Storage degradation of palm-derived biodiesels: Its effects on chemical properties and engine performance

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  • Pattamaprom, C.
  • Pakdee, W.
  • Ngamjaroen, S.

Abstract

Palm olein and palm stearin are co-products of palm oil refining processes having different melting point ranges. This study compares the storage degradation characteristics of biodiesels derived from these two palm products, which are palm olein and palm stearin, in terms of chemical properties, engine performance and exhaust emission. The degradation study was carried out by keeping biodiesels in dark closed-lid containers at room temperature for up to 6 months. It was found that the oxygen present in the container led to slow degradation of biodiesels through oxidative reaction with the double bonds in biodiesel. Within 6 months, the majority of oxidative products were composed of shorter hydroperoxide compounds and other short secondary products. These changes resulted in lower heating value and higher density of biodiesels, which in turn caused reductions in fuel combustion efficiency and fuel economy. In terms of emission, the degraded biodiesel produced more complete combustion as indicated by lower emissions of black smoke and carbon monoxide but with higher emission of NOx. In terms of palm oil type, even though palm olein biodiesel possessed higher degree of unsaturation and produced higher peroxide value and acid values from the degradation, its combustion efficiency and fuel economy were still superior to the biodiesel produced from palm stearin possibly due to its higher chain lengths.

Suggested Citation

  • Pattamaprom, C. & Pakdee, W. & Ngamjaroen, S., 2012. "Storage degradation of palm-derived biodiesels: Its effects on chemical properties and engine performance," Renewable Energy, Elsevier, vol. 37(1), pages 412-418.
    • Handle: RePEc:eee:renene:v:37:y:2012:i:1:p:412-418
    DOI: 10.1016/j.renene.2011.05.032
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    References listed on IDEAS

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    1. Moser, Bryan R., 2011. "Influence of extended storage on fuel properties of methyl esters prepared from canola, palm, soybean and sunflower oils," Renewable Energy, Elsevier, vol. 36(4), pages 1221-1226.
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    2. Bagchi, Sourav Kumar & Patnaik, Reeza & Sonkar, Sashi & Koley, Shankha & Rao, P. Srinivasa & Mallick, Nirupama, 2019. "Qualitative biodiesel production from a locally isolated chlorophycean microalga Scenedesmus obliquus (Turpin) Kützing GA 45 under closed raceway pond cultivation," Renewable Energy, Elsevier, vol. 139(C), pages 976-987.
    3. Varatharajan, K. & Cheralathan, M., 2012. "Influence of fuel properties and composition on NOx emissions from biodiesel powered diesel engines: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(6), pages 3702-3710.
    4. How, H.G. & Teoh, Y.H. & Krishnan, B. Navaneetha & Le, T.D. & Nguyen, H.T. & Prabhu, C., 2021. "Prediction of optimum Palm Oil Methyl Ester fuel blend for compression ignition engine using Response Surface Methodology," Energy, Elsevier, vol. 234(C).
    5. Cavalheiro, Leandro Fontoura & Misutsu, Marcelo Yukio & Rial, Rafael Cardoso & Viana, Luíz Henrique & Oliveira, Lincoln Carlos Silva, 2020. "Characterization of residues and evaluation of the physico chemical properties of soybean biodiesel and biodiesel: Diesel blends in different storage conditions," Renewable Energy, Elsevier, vol. 151(C), pages 454-462.
    6. Fabián Vargas & Armando Pérez & Rene Delgado & Emilio Hernández & José Alejandro Suástegui, 2019. "Performance Analysis of a Compression Ignition Engine Using Mixture Biodiesel Palm and Diesel," Sustainability, MDPI, vol. 11(18), pages 1-26, September.
    7. Si, Buchun & Watson, Jamison & Wang, Zixin & Wang, Tengfei & Acero Triana, Juan S. & Zhang, Yuanhui, 2024. "Storage stability of biocrude oil fractional distillates derived from the hydrothermal liquefaction of food waste," Renewable Energy, Elsevier, vol. 220(C).
    8. Roveda, Ana Carolina & Comin, Marina & Caires, Anderson Rodrigues Lima & Ferreira, Valdir Souza & Trindade, Magno Aparecido Gonçalves, 2016. "Thermal stability enhancement of biodiesel induced by a synergistic effect between conventional antioxidants and an alternative additive," Energy, Elsevier, vol. 109(C), pages 260-265.
    9. Thangaraja, J. & Anand, K. & Mehta, Pramod S., 2016. "Biodiesel NOx penalty and control measures - a review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 61(C), pages 1-24.
    10. Mathimani, Thangavel & Uma, Lakshmanan & Prabaharan, Dharmar, 2015. "Homogeneous acid catalysed transesterification of marine microalga Chlorella sp. BDUG 91771 lipid – An efficient biodiesel yield and its characterization," Renewable Energy, Elsevier, vol. 81(C), pages 523-533.
    11. Wenchao, Wang & Yuling, Zhai & Fashe, Li & Ying, Li, 2020. "Application and analysis of rapid determination of oxidative degradation of biodiesel by surface tension and UV absorbance," Renewable Energy, Elsevier, vol. 152(C), pages 1431-1438.
    12. Anahas, Antonyraj Matharasi Perianaika & Muralitharan, Gangatharan, 2019. "Central composite design (CCD) optimization of phytohormones supplementation for enhanced cyanobacterial biodiesel production," Renewable Energy, Elsevier, vol. 130(C), pages 749-761.

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