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Pilot-scale pyrolysis and activation of typical biomass chips in an interconnected dual fluidized bed: Comparison and analysis of products

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Listed:
  • Zhou, Chunbao
  • Chen, Yuanxiang
  • Xing, Xuyang
  • Chen, Lei
  • Liu, Chenglong
  • Chao, Li
  • Yao, Bang
  • Zhang, Yingwen
  • Dai, Jianjun
  • Liu, Yang
  • Wang, Jun
  • Dong, Jie
  • Li, Yunxiang
  • Fan, Dekai
  • Wang, Long
  • Li, Yan

Abstract

A 150 kg/h novel pilot dual fluidized bed (DFB) was designed, constructed, and commissioned. In this study, six types of biomass chips were investigated and compared in interconnected pyrolysis and activation/gasification systems using dolomite as bed material, and employing steam and flue gas as activation agents. The maximum iodine and methylene blue adsorption capacities were 436.79 mg/g (pear wood char) and 203.65 mg/g (walnut wood char), respectively, indicating high adsorption capacity of char. The carbon fixation ratios were 34.70–53.75 wt%, and the maximum lower heating value of 9.34 MJ/Nm3 was achieved for pyrolysis gas with the highest CO and H2 contents of 44.30 vol% and 16.18 vol%, respectively. The maximum phenolic compounds reached 73.46% for mesquite wood chips oil. Oils collected from the riser contained fewer organic species compared to oil from pyrolyzer. Furthermore, energy efficiencies were found to range from 66.70% to 84.91%, and the total energy yields were 67.12–87.08%. The internal rate of return and payback period of the process were 33.25–44.29% and 3.0–2.2 years, respectively. Co-production of activated biochar, combustible gas, and oils from the interconnected DFB system exemplifies noteworthy environmental and economic advantages for sustainable energy practices.

Suggested Citation

  • Zhou, Chunbao & Chen, Yuanxiang & Xing, Xuyang & Chen, Lei & Liu, Chenglong & Chao, Li & Yao, Bang & Zhang, Yingwen & Dai, Jianjun & Liu, Yang & Wang, Jun & Dong, Jie & Li, Yunxiang & Fan, Dekai & Wan, 2024. "Pilot-scale pyrolysis and activation of typical biomass chips in an interconnected dual fluidized bed: Comparison and analysis of products," Renewable Energy, Elsevier, vol. 225(C).
    • Handle: RePEc:eee:renene:v:225:y:2024:i:c:s096014812400404x
    DOI: 10.1016/j.renene.2024.120339
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