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Zinc glycerolate: An unconventional heterogeneous catalyst for the glycerolysis of fatty acids in biodiesel production

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  • Liang, Xiaojiang
  • Fei, Haotian
  • Zhou, Chenxuan
  • Ye, Xuelei
  • Xie, Qinglong
  • Wu, Zhenyu
  • Yu, Shangzhi
  • Duan, Ying
  • Nie, Yong

Abstract

In this work, an efficient and green glycerolysis reaction catalyzed by zinc glycerolate was developed to prepare biodiesel from oleic acid. The active phase of zinc glycerolate was investigated by XRD, FTIR, 1H NMR, and 13C NMR. An interesting result was obtained that zinc glycerolate was first dissolved to form zinc oleate and then regenerated to zinc glycerolate during the reaction, which was essential for the conversion of oleic acid. The relationship between dissolved zinc glycerolate and conversion of oleic acid was determined. The regeneration of zinc glycerolate was achieved when the molar ratio of glycerol to oleic acid was higher than 0.6:1. A plausible pathway for the glycerolysis reaction catalyzed by zinc glycerolate was proposed. Zinc glycerolate could be recycled 10 times with no obvious decrease in catalytic activity, and the oleic acid conversion of 98% was achieved. In addition, zinc glycerolate was applied to catalyze glycerolysis reaction of different feedstock and demonstrated excellent performance. The results show that zinc glycerolate is a promising catalyst in glycerolysis reaction for biodiesel production.

Suggested Citation

  • Liang, Xiaojiang & Fei, Haotian & Zhou, Chenxuan & Ye, Xuelei & Xie, Qinglong & Wu, Zhenyu & Yu, Shangzhi & Duan, Ying & Nie, Yong, 2023. "Zinc glycerolate: An unconventional heterogeneous catalyst for the glycerolysis of fatty acids in biodiesel production," Renewable Energy, Elsevier, vol. 218(C).
    • Handle: RePEc:eee:renene:v:218:y:2023:i:c:s0960148123010546
    DOI: 10.1016/j.renene.2023.119140
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    1. Sundus, F. & Fazal, M.A. & Masjuki, H.H., 2017. "Tribology with biodiesel: A study on enhancing biodiesel stability and its fuel properties," Renewable and Sustainable Energy Reviews, Elsevier, vol. 70(C), pages 399-412.
    2. Roschat, Wuttichai & Siritanon, Theeranun & Yoosuk, Boonyawan & Sudyoadsuk, Taweesak & Promarak, Vinich, 2017. "Rubber seed oil as potential non-edible feedstock for biodiesel production using heterogeneous catalyst in Thailand," Renewable Energy, Elsevier, vol. 101(C), pages 937-944.
    3. Ong, Zhi Chao & Mohd Mishani, Mohd Bakar & Chong, Wen Tong & Soon, Roon Sheng & Ong, Hwai Chyuan & Ismail, Zubaidah, 2017. "Identification of optimum Calophyllum inophyllum bio-fuel blend in diesel engine using advanced vibration analysis technique," Renewable Energy, Elsevier, vol. 109(C), pages 295-304.
    4. Kwong, Tsz-Lung & Yung, Ka-Fu, 2016. "One-step production of biodiesel through simultaneous esterification and transesterification from highly acidic unrefined feedstock over efficient and recyclable ZnO nanostar catalyst," Renewable Energy, Elsevier, vol. 90(C), pages 450-457.
    5. Ismet Ugursal, V., 2014. "Energy consumption, associated questions and some answers," Applied Energy, Elsevier, vol. 130(C), pages 783-792.
    6. El-sherif, Ahmed A. & Hamad, Amany M. & Shams-Eldin, Engy & Mohamed, Heba Allah Abdelnabi Eid & Ahmed, Asmaa M. & Mohamed, Maha A. & Abdelaziz, Youssef S. & Sayed, Fatma Al-Zahraa & El qassem Mahmoud,, 2023. "Power of recycling waste cooking oil into biodiesel via green CaO-based eggshells/Ag heterogeneous nanocatalyst," Renewable Energy, Elsevier, vol. 202(C), pages 1412-1423.
    7. Huang, GuanHua & Chen, Feng & Wei, Dong & Zhang, XueWu & Chen, Gu, 2010. "Biodiesel production by microalgal biotechnology," Applied Energy, Elsevier, vol. 87(1), pages 38-46, January.
    8. Atadashi, I.M. & Aroua, M.K. & Aziz, A. Abdul, 2011. "Biodiesel separation and purification: A review," Renewable Energy, Elsevier, vol. 36(2), pages 437-443.
    9. Mamtani, Kapil & Shahbaz, Kaveh & Farid, Mohammed M., 2021. "Glycerolysis of free fatty acids: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 137(C).
    10. Mueanmas, Chokchai & Nikhom, Ruamporn & Petchkaew, Anida & Iewkittayakorn, Jutarut & Prasertsit, Kulchanart, 2019. "Extraction and esterification of waste coffee grounds oil as non-edible feedstock for biodiesel production," Renewable Energy, Elsevier, vol. 133(C), pages 1414-1425.
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