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Influence of Lewis and Brønsted acid catalysts in the transformation of hexoses into 5-ethoxymethylfurfural

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  • Torres-Olea, Benjamín
  • Fúnez-Núñez, Inmaculada
  • García-Sancho, Cristina
  • Cecilia, Juan Antonio
  • Moreno-Tost, Ramón
  • Maireles-Torres, Pedro

Abstract

Several sulfonated polymers, which are typical Brønsted acid catalysts, have been employed in the production of two biofuels: 5-ethoxymethylfurfural (EMF) and ethyl levulinate (EL) as main byproduct, and the catalytic results have been attributed to their different chemical and morphological properties. The Purolite CT275DR attained the best results from 5-hydroxymethylfurfural (HMF) with a 63% EMF yield after 16 h at 100 °C thanks to their more abundant superficial acid sites. Moreover, Purolite CT275DR was able to efficiently dehydrate and etherify fructose, with a total EMF plus EL yield of 65% after 24 h at 100 °C. When glucose or galactose were used as feedstock, alumina was utilized to provide Lewis acid sites, necessary for the transformation of aldoses in solution enabling a combined biofuel yield (EMF plus EL) of 40% from glucose after 24 h at 140 °C. With the study of the role of each catalyst, both Brønsted and Lewis acid catalysts (resin and alumina, respectively) were required to obtain considerable EMF yields from aldoses. The reutilization of the catalysts employed for 5 catalytic runs demonstrated that Purolite CT275DR suffers no appreciable loss of activity, but alumina showed progressive losses in activity in each cycle due to carbonaceous deposits and catalyst loss.

Suggested Citation

  • Torres-Olea, Benjamín & Fúnez-Núñez, Inmaculada & García-Sancho, Cristina & Cecilia, Juan Antonio & Moreno-Tost, Ramón & Maireles-Torres, Pedro, 2023. "Influence of Lewis and Brønsted acid catalysts in the transformation of hexoses into 5-ethoxymethylfurfural," Renewable Energy, Elsevier, vol. 207(C), pages 588-600.
    • Handle: RePEc:eee:renene:v:207:y:2023:i:c:p:588-600
    DOI: 10.1016/j.renene.2023.03.036
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    References listed on IDEAS

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    1. Dowaki, Taishi & Guo, Haixin & Smith, Richard Lee, 2022. "Lignin-derived biochar solid acid catalyst for fructose conversion into 5-ethoxymethylfurfural," Renewable Energy, Elsevier, vol. 199(C), pages 1534-1542.
    2. Yang, Yu & Abu-Omar, Mahdi M. & Hu, Changwei, 2012. "Heteropolyacid catalyzed conversion of fructose, sucrose, and inulin to 5-ethoxymethylfurfural, a liquid biofuel candidate," Applied Energy, Elsevier, vol. 99(C), pages 80-84.
    3. Zuo, Miao & Jia, Wenlong & Feng, Yunchao & Zeng, Xianhai & Tang, Xing & Sun, Yong & Lin, Lu, 2021. "Effective selectivity conversion of glucose to furan chemicals in the aqueous deep eutectic solvent," Renewable Energy, Elsevier, vol. 164(C), pages 23-33.
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    2. Chai, Yu & Tian, Xin-Yu & Zheng, Xiao-Ping & Du, Ya-Peng & Zhang, Yu-Cang & Zheng, Yan-Zhen, 2024. "An effective approach for chitosan conversion to 5-hydroxymethylfurfural catalyzed by bio-based organic acid with ionic liquids additive," Renewable Energy, Elsevier, vol. 221(C).
    3. Vinícius Bertoncello Molon & Bruno Luís Ferreira & Carolina Colombo Tedesco & Maria Gabriele Delagustin & Thiago Barcellos, 2024. "Microwave-Assisted Production of 5-Hydroxymethylfurfural from Fructose Using Sulfamic Acid as a Green Catalyst," Sustainability, MDPI, vol. 16(2), pages 1-12, January.

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