IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v207y2023icp588-600.html
   My bibliography  Save this article

Influence of Lewis and Brønsted acid catalysts in the transformation of hexoses into 5-ethoxymethylfurfural

Author

Listed:
  • Torres-Olea, Benjamín
  • Fúnez-Núñez, Inmaculada
  • García-Sancho, Cristina
  • Cecilia, Juan Antonio
  • Moreno-Tost, Ramón
  • Maireles-Torres, Pedro

Abstract

Several sulfonated polymers, which are typical Brønsted acid catalysts, have been employed in the production of two biofuels: 5-ethoxymethylfurfural (EMF) and ethyl levulinate (EL) as main byproduct, and the catalytic results have been attributed to their different chemical and morphological properties. The Purolite CT275DR attained the best results from 5-hydroxymethylfurfural (HMF) with a 63% EMF yield after 16 h at 100 °C thanks to their more abundant superficial acid sites. Moreover, Purolite CT275DR was able to efficiently dehydrate and etherify fructose, with a total EMF plus EL yield of 65% after 24 h at 100 °C. When glucose or galactose were used as feedstock, alumina was utilized to provide Lewis acid sites, necessary for the transformation of aldoses in solution enabling a combined biofuel yield (EMF plus EL) of 40% from glucose after 24 h at 140 °C. With the study of the role of each catalyst, both Brønsted and Lewis acid catalysts (resin and alumina, respectively) were required to obtain considerable EMF yields from aldoses. The reutilization of the catalysts employed for 5 catalytic runs demonstrated that Purolite CT275DR suffers no appreciable loss of activity, but alumina showed progressive losses in activity in each cycle due to carbonaceous deposits and catalyst loss.

Suggested Citation

  • Torres-Olea, Benjamín & Fúnez-Núñez, Inmaculada & García-Sancho, Cristina & Cecilia, Juan Antonio & Moreno-Tost, Ramón & Maireles-Torres, Pedro, 2023. "Influence of Lewis and Brønsted acid catalysts in the transformation of hexoses into 5-ethoxymethylfurfural," Renewable Energy, Elsevier, vol. 207(C), pages 588-600.
    • Handle: RePEc:eee:renene:v:207:y:2023:i:c:p:588-600
    DOI: 10.1016/j.renene.2023.03.036
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148123003221
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2023.03.036?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Dowaki, Taishi & Guo, Haixin & Smith, Richard Lee, 2022. "Lignin-derived biochar solid acid catalyst for fructose conversion into 5-ethoxymethylfurfural," Renewable Energy, Elsevier, vol. 199(C), pages 1534-1542.
    2. Yang, Yu & Abu-Omar, Mahdi M. & Hu, Changwei, 2012. "Heteropolyacid catalyzed conversion of fructose, sucrose, and inulin to 5-ethoxymethylfurfural, a liquid biofuel candidate," Applied Energy, Elsevier, vol. 99(C), pages 80-84.
    3. Zuo, Miao & Jia, Wenlong & Feng, Yunchao & Zeng, Xianhai & Tang, Xing & Sun, Yong & Lin, Lu, 2021. "Effective selectivity conversion of glucose to furan chemicals in the aqueous deep eutectic solvent," Renewable Energy, Elsevier, vol. 164(C), pages 23-33.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Zhu, Jishen & Jiang, Weiqiang & Yuan, Zong & Lu, Jie & Ding, Jincheng, 2024. "Esterification of tall oil fatty acid catalyzed by Zr4+-CER in fixed bed membrane reactor," Renewable Energy, Elsevier, vol. 221(C).
    2. Chai, Yu & Tian, Xin-Yu & Zheng, Xiao-Ping & Du, Ya-Peng & Zhang, Yu-Cang & Zheng, Yan-Zhen, 2024. "An effective approach for chitosan conversion to 5-hydroxymethylfurfural catalyzed by bio-based organic acid with ionic liquids additive," Renewable Energy, Elsevier, vol. 221(C).
    3. Vinícius Bertoncello Molon & Bruno Luís Ferreira & Carolina Colombo Tedesco & Maria Gabriele Delagustin & Thiago Barcellos, 2024. "Microwave-Assisted Production of 5-Hydroxymethylfurfural from Fructose Using Sulfamic Acid as a Green Catalyst," Sustainability, MDPI, vol. 16(2), pages 1-12, January.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Dowaki, Taishi & Guo, Haixin & Smith, Richard Lee, 2023. "Cascade conversion and kinetic modeling of glucose transformation into mixed-biofuels via lignin-derived Lewis-Brønsted acid biochars," Renewable Energy, Elsevier, vol. 217(C).
    2. Xiao, Jing & Wu, Luoming & Wu, Ying & Liu, Bing & Dai, Lu & Li, Zhong & Xia, Qibin & Xi, Hongxia, 2014. "Effect of gasoline composition on oxidative desulfurization using a phosphotungstic acid/activated carbon catalyst with hydrogen peroxide," Applied Energy, Elsevier, vol. 113(C), pages 78-85.
    3. Klanarong, Nattha & Saito, Nagahiro & Prasertsung, Isarawut & Damrongsakkul, Siriporn, 2023. "Conversion of fructose to 5-hydroxymethylfurfural using solution plasma process," Renewable Energy, Elsevier, vol. 218(C).
    4. Hu, Lei & Lin, Lu & Wu, Zhen & Zhou, Shouyong & Liu, Shijie, 2017. "Recent advances in catalytic transformation of biomass-derived 5-hydroxymethylfurfural into the innovative fuels and chemicals," Renewable and Sustainable Energy Reviews, Elsevier, vol. 74(C), pages 230-257.
    5. Hafizi, Hamid & Walker, Gavin & Collins, Maurice N., 2022. "Efficient production of 5-ethoxymethylfurfural from 5-hydroxymethylfurfural and carbohydrates over lewis/brønsted hybrid magnetic dendritic fibrous silica core-shell catalyst," Renewable Energy, Elsevier, vol. 183(C), pages 459-471.
    6. Alipour, Siamak & Omidvarborna, Hamid & Kim, Dong-Shik, 2017. "A review on synthesis of alkoxymethyl furfural, a biofuel candidate," Renewable and Sustainable Energy Reviews, Elsevier, vol. 71(C), pages 908-926.
    7. Yu, Yixuan & Liu, Huai & Zhang, Junhua & Zhang, Heng & Sun, Yong & Peng, Lincai, 2023. "Highly efficient, amorphous bimetal Ni-Fe borides-catalyzed hydrogenolysis of 5-hydroxymethylfurfural into 2,5-dimethylfuran," Renewable Energy, Elsevier, vol. 209(C), pages 453-461.
    8. Peng, Lincai & Huangfu, Xin & Liu, Yao & Liu, Huai & Zhang, Junhua, 2022. "Natural lignocellulose welded Zr–Al bimetallic hybrids for the sustainable conversion of xylose to alkyl levulinate," Renewable Energy, Elsevier, vol. 193(C), pages 357-366.
    9. di Bitonto, Luigi & Locaputo, Vito & D'Ambrosio, Valeria & Pastore, Carlo, 2020. "Direct Lewis-Brønsted acid ethanolysis of sewage sludge for production of liquid fuels," Applied Energy, Elsevier, vol. 259(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:207:y:2023:i:c:p:588-600. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.