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Graphdiyne(CnH2n-2) based NiS S-scheme heterojunction for efficient photocatalytic hydrogen production

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  • Jin, Zhiliang
  • Jiang, Xudong
  • Liu, Yanan

Abstract

Graphdiyne (g-CnH2n-2), as a novel two-dimension carbon allotrope material composed of sp- and sp2-hybrid carbon network, has been widely explored since it was synthesized for the first time by Li's group in 2010. Here, innovative progress for preparing graphdiyne by using Cu+ contained material as a catalyst is reported and the graphdiyne is coupled with NiS to produce hydrogen from photocatalytic water splitting. The composite photocatalyst NiS/GDY was prepared by simple physical mixing of graphdiyne and NiS in nanorod form, which showed excellent hydrogen production activity. In addition, the S-scheme heterojunction composed of graphdiyne and nanorod NiS effectively utilized the strongly reduced and unwanted electrons, and the addition of graphdiyne also effectively increased the absorption intensity of light. The amount of graphdiyne addition was optimized, and the best hydrogen production activity was achieved when the graphdiyne was 10 wt%. This composite catalyst deepens the application of graphdiyne in photocatalysis.

Suggested Citation

  • Jin, Zhiliang & Jiang, Xudong & Liu, Yanan, 2022. "Graphdiyne(CnH2n-2) based NiS S-scheme heterojunction for efficient photocatalytic hydrogen production," Renewable Energy, Elsevier, vol. 201(P1), pages 854-863.
  • Handle: RePEc:eee:renene:v:201:y:2022:i:p1:p:854-863
    DOI: 10.1016/j.renene.2022.11.004
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    References listed on IDEAS

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    1. Pan, Jiaqi & Liu, Yanyan & Ou, Wei & Li, Shi & Li, Hongli & Wang, Jingjing & Song, Changsheng & Zheng, Yingying & Li, Chaorong, 2020. "The photocatalytic hydrogen evolution enhancement of the MoS2 lamellas modified g-C3N4/SrTiO3 core-shell heterojunction," Renewable Energy, Elsevier, vol. 161(C), pages 340-349.
    2. Dong, Bin & Xie, Jing-Yi & Wang, Nan & Gao, Wen-Kun & Ma, Yu & Chen, Tian-Shu & Yan, Xin-Tong & Li, Qing-Zhong & Zhou, Yu-Lu & Chai, Yong-Ming, 2020. "Zinc ion induced three-dimensional Co9S8 nano-neuron network for efficient hydrogen evolution," Renewable Energy, Elsevier, vol. 157(C), pages 415-423.
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    4. Rui Wang & Miusi Shi & Feiyan Xu & Yun Qiu & Peng Zhang & Kailun Shen & Qin Zhao & Jiaguo Yu & Yufeng Zhang, 2020. "Graphdiyne-modified TiO2 nanofibers with osteoinductive and enhanced photocatalytic antibacterial activities to prevent implant infection," Nature Communications, Nature, vol. 11(1), pages 1-12, December.
    5. Liu, Tianxia & Yang, Kaicheng & Gong, Haiming & Jin, Zhiliang, 2021. "Visible-light driven S-scheme Mn0.2Cd0.8S/CoTiO3 heterojunction for photocatalytic hydrogen evolution," Renewable Energy, Elsevier, vol. 173(C), pages 389-400.
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    1. Guo, Xin & Fan, Linlin & Liu, Yafeng & Jin, Zhiliang, 2024. "In situ XPS confirmed the efficient charge transfer of the CdS/GDY/ZnMoO4 heterojunction based on graphdiyne(CnH2n-2) for photocatalytic hydrogen production," Renewable Energy, Elsevier, vol. 222(C).

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