IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v167y2021icp580-590.html
   My bibliography  Save this article

Graphite-based shape-stabilized composites for phase change material applications

Author

Listed:
  • Ohayon-Lavi, Avia
  • Lavi, Adi
  • Alatawna, Amr
  • Ruse, Efrat
  • Ziskind, Gennady
  • Regev, Oren

Abstract

Phase Change Materials (PCM) possess high heat storage density, but commonly have low thermal conductivity that results in poor heat transfer. Another common problem is the shape stabilization of the storage medium. These problems could be solved by loading the medium with thermally conductive fillers, such as graphite, and encapsulating it in a thermally conductive polymer matrix shell, hence enhancing the thermal properties of both. We suggest a ternary system in which a graphite-epoxy composite provides an encapsulating scaffold to the paraffin, which is also loaded with graphite-based filler. Various graphite-based fillers differing in sizes and geometry were explored, aiming at optimizing their intrinsic properties, such as defect density, and consequently enhancing the thermal properties of the PCM as a whole. It was demonstrated that by judicious choice of the filler, enhancement is achieved for the thermal conductivity of: (1) the shell (epoxy-graphite flakes composite) by 4000% compared to the neat epoxy; (2) the medium (paraffin-graphite flakes composite) by > 2000% compared to the neat paraffin; and (3) the integrated PCM system (paraffin-epoxy-graphite flakes composite) by 1000% compared to that of neat paraffin. The PCM composite is completely preserved during phase change cycling.

Suggested Citation

  • Ohayon-Lavi, Avia & Lavi, Adi & Alatawna, Amr & Ruse, Efrat & Ziskind, Gennady & Regev, Oren, 2021. "Graphite-based shape-stabilized composites for phase change material applications," Renewable Energy, Elsevier, vol. 167(C), pages 580-590.
    • Handle: RePEc:eee:renene:v:167:y:2021:i:c:p:580-590
    DOI: 10.1016/j.renene.2020.11.117
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148120318693
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2020.11.117?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Castellón, Cecilia & Medrano, Marc & Roca, Joan & Cabeza, Luisa F. & Navarro, Maria E. & Fernández, Ana I. & Lázaro, Ana & Zalba, Belen, 2010. "Effect of microencapsulated phase change material in sandwich panels," Renewable Energy, Elsevier, vol. 35(10), pages 2370-2374.
    2. Cabeza, L.F. & Castell, A. & Barreneche, C. & de Gracia, A. & Fernández, A.I., 2011. "Materials used as PCM in thermal energy storage in buildings: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(3), pages 1675-1695, April.
    3. Zhou, D. & Zhao, C.Y. & Tian, Y., 2012. "Review on thermal energy storage with phase change materials (PCMs) in building applications," Applied Energy, Elsevier, vol. 92(C), pages 593-605.
    4. Kenisarin, Murat M., 2010. "High-temperature phase change materials for thermal energy storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(3), pages 955-970, April.
    5. Zhang, Zhengguo & Shi, Guoquan & Wang, Shuping & Fang, Xiaoming & Liu, Xiaohong, 2013. "Thermal energy storage cement mortar containing n-octadecane/expanded graphite composite phase change material," Renewable Energy, Elsevier, vol. 50(C), pages 670-675.
    6. Li, Min & Wu, Zhishen, 2012. "A review of intercalation composite phase change material: Preparation, structure and properties," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(4), pages 2094-2101.
    7. Li, Chuanchang & Xie, Baoshan & He, Zhangxing & Chen, Jian & Long, Yi, 2019. "3D structure fungi-derived carbon stabilized stearic acid as a composite phase change material for thermal energy storage," Renewable Energy, Elsevier, vol. 140(C), pages 862-873.
    8. Zhang, Lei & Zhu, Jiaoqun & Zhou, Weibing & Wang, Jun & Wang, Yan, 2012. "Thermal and electrical conductivity enhancement of graphite nanoplatelets on form-stable polyethylene glycol/polymethyl methacrylate composite phase change materials," Energy, Elsevier, vol. 39(1), pages 294-302.
    9. Li, Wei & Zhang, Rong & Jiang, Nan & Tang, Xiao-fen & Shi, Hai-feng & Zhang, Xing-xiang & Zhang, Yuankai & Dong, Lin & Zhang, Ningxin, 2013. "Composite macrocapsule of phase change materials/expanded graphite for thermal energy storage," Energy, Elsevier, vol. 57(C), pages 607-614.
    10. Kuznik, Frédéric & Virgone, Joseph & Johannes, Kevyn, 2011. "In-situ study of thermal comfort enhancement in a renovated building equipped with phase change material wallboard," Renewable Energy, Elsevier, vol. 36(5), pages 1458-1462.
    11. Xia, L. & Zhang, P. & Wang, R.Z., 2010. "Numerical heat transfer analysis of the packed bed latent heat storage system based on an effective packed bed model," Energy, Elsevier, vol. 35(5), pages 2022-2032.
    12. Sharma, Atul & Tyagi, V.V. & Chen, C.R. & Buddhi, D., 2009. "Review on thermal energy storage with phase change materials and applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 13(2), pages 318-345, February.
    13. Kim, Ki-bum & Choi, Kyung-wook & Kim, Young-jin & Lee, Ki-hyung & Lee, Kwan-soo, 2010. "Feasibility study on a novel cooling technique using a phase change material in an automotive engine," Energy, Elsevier, vol. 35(1), pages 478-484.
    14. Fan, Li-Wu & Fang, Xin & Wang, Xiao & Zeng, Yi & Xiao, Yu-Qi & Yu, Zi-Tao & Xu, Xu & Hu, Ya-Cai & Cen, Ke-Fa, 2013. "Effects of various carbon nanofillers on the thermal conductivity and energy storage properties of paraffin-based nanocomposite phase change materials," Applied Energy, Elsevier, vol. 110(C), pages 163-172.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Tamilselvi, R. & Lekshmi, G.S. & Padmanathan, N. & Selvaraj, V. & Bazaka, O. & Levchenko, I. & Bazaka, K. & Mandhakini, M., 2022. "NiFe2O4 / rGO nanocomposites produced by soft bubble assembly for energy storage and environmental remediation," Renewable Energy, Elsevier, vol. 181(C), pages 1386-1401.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Ge, Haoshan & Li, Haiyan & Mei, Shengfu & Liu, Jing, 2013. "Low melting point liquid metal as a new class of phase change material: An emerging frontier in energy area," Renewable and Sustainable Energy Reviews, Elsevier, vol. 21(C), pages 331-346.
    2. Memon, Shazim Ali, 2014. "Phase change materials integrated in building walls: A state of the art review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 31(C), pages 870-906.
    3. Zeinelabdein, Rami & Omer, Siddig & Gan, Guohui, 2018. "Critical review of latent heat storage systems for free cooling in buildings," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 2843-2868.
    4. Soares, N. & Santos, P. & Gervásio, H. & Costa, J.J. & Simões da Silva, L., 2017. "Energy efficiency and thermal performance of lightweight steel-framed (LSF) construction: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 78(C), pages 194-209.
    5. Jankowski, Nicholas R. & McCluskey, F. Patrick, 2014. "A review of phase change materials for vehicle component thermal buffering," Applied Energy, Elsevier, vol. 113(C), pages 1525-1561.
    6. Chandel, S.S. & Agarwal, Tanya, 2017. "Review of current state of research on energy storage, toxicity, health hazards and commercialization of phase changing materials," Renewable and Sustainable Energy Reviews, Elsevier, vol. 67(C), pages 581-596.
    7. Khadiran, Tumirah & Hussein, Mohd Zobir & Zainal, Zulkarnain & Rusli, Rafeadah, 2016. "Advanced energy storage materials for building applications and their thermal performance characterization: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 57(C), pages 916-928.
    8. Kenisarin, Murat & Mahkamov, Khamid, 2016. "Passive thermal control in residential buildings using phase change materials," Renewable and Sustainable Energy Reviews, Elsevier, vol. 55(C), pages 371-398.
    9. Yuan, Yanping & Zhang, Nan & Li, Tianyu & Cao, Xiaoling & Long, Weiyue, 2016. "Thermal performance enhancement of palmitic-stearic acid by adding graphene nanoplatelets and expanded graphite for thermal energy storage: A comparative study," Energy, Elsevier, vol. 97(C), pages 488-497.
    10. Rostami, Sara & Afrand, Masoud & Shahsavar, Amin & Sheikholeslami, M. & Kalbasi, Rasool & Aghakhani, Saeed & Shadloo, Mostafa Safdari & Oztop, Hakan F., 2020. "A review of melting and freezing processes of PCM/nano-PCM and their application in energy storage," Energy, Elsevier, vol. 211(C).
    11. Lizana, Jesús & Chacartegui, Ricardo & Barrios-Padura, Angela & Ortiz, Carlos, 2018. "Advanced low-carbon energy measures based on thermal energy storage in buildings: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 3705-3749.
    12. Li, Min & Mu, Boyuan, 2019. "Effect of different dimensional carbon materials on the properties and application of phase change materials: A review," Applied Energy, Elsevier, vol. 242(C), pages 695-715.
    13. Mohamed, Shamseldin A. & Al-Sulaiman, Fahad A. & Ibrahim, Nasiru I. & Zahir, Md. Hasan & Al-Ahmed, Amir & Saidur, R. & Yılbaş, B.S. & Sahin, A.Z., 2017. "A review on current status and challenges of inorganic phase change materials for thermal energy storage systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 70(C), pages 1072-1089.
    14. Yang, Jialin & Yang, Lijun & Xu, Chao & Du, Xiaoze, 2016. "Experimental study on enhancement of thermal energy storage with phase-change material," Applied Energy, Elsevier, vol. 169(C), pages 164-176.
    15. He, Fang & Wang, Xiaodong & Wu, Dezhen, 2014. "New approach for sol–gel synthesis of microencapsulated n-octadecane phase change material with silica wall using sodium silicate precursor," Energy, Elsevier, vol. 67(C), pages 223-233.
    16. Johra, Hicham & Heiselberg, Per, 2017. "Influence of internal thermal mass on the indoor thermal dynamics and integration of phase change materials in furniture for building energy storage: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 69(C), pages 19-32.
    17. Silva, Tiago & Vicente, Romeu & Amaral, Cláudia & Figueiredo, António, 2016. "Thermal performance of a window shutter containing PCM: Numerical validation and experimental analysis," Applied Energy, Elsevier, vol. 179(C), pages 64-84.
    18. Zhang, Lei & Zhu, Jiaoqun & Zhou, Weibing & Wang, Jun & Wang, Yan, 2012. "Thermal and electrical conductivity enhancement of graphite nanoplatelets on form-stable polyethylene glycol/polymethyl methacrylate composite phase change materials," Energy, Elsevier, vol. 39(1), pages 294-302.
    19. Fu, Lulu & Wang, Qianhao & Ye, Rongda & Fang, Xiaoming & Zhang, Zhengguo, 2017. "A calcium chloride hexahydrate/expanded perlite composite with good heat storage and insulation properties for building energy conservation," Renewable Energy, Elsevier, vol. 114(PB), pages 733-743.
    20. Mousavi, Seyedmostafa & Rismanchi, Behzad & Brey, Stefan & Aye, Lu, 2021. "PCM embedded radiant chilled ceiling: A state-of-the-art review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 151(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:167:y:2021:i:c:p:580-590. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.