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Semi-continuous mechanochemical process for biodiesel production under heterogeneous catalysis using calcium diglyceroxide

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  • Malpartida, Irene
  • Maireles-Torres, Pedro
  • Vereda, Carlos
  • Rodríguez-Maroto, José M.
  • Halloumi, Samy
  • Lair, Valentin
  • Thiel, Julien
  • Lacoste, François

Abstract

This work is aimed at the development of a semi-continuous mechanochemical process for biodiesel production and the subsequent valorization of glycerol, its by-product, via its conversion into calcium diglyceroxide using the same mechanochemical reactor. This basic solid catalyzes the methanolysis of vegetable oils. The implementation of a semi-continuous process allows both the preparation of the solid catalyst and the methanolysis process, overcoming the miscibility problems of methanol and oil. Thus, a biodiesel yield higher than 90% is reached using a methanol:oil molar ratio close to stoichiometric value and 1.5 wt. % catalyst, after passing through the reactor with a flow rate between 4 and 45 L/h. This new process for biodiesel production can easily be scaled up and applied to the conversion of used cooking oils, without any significant yield decrease. A cost study was also performed, demonstrating that this is more economical than the conventional batch stirring-based process.

Suggested Citation

  • Malpartida, Irene & Maireles-Torres, Pedro & Vereda, Carlos & Rodríguez-Maroto, José M. & Halloumi, Samy & Lair, Valentin & Thiel, Julien & Lacoste, François, 2020. "Semi-continuous mechanochemical process for biodiesel production under heterogeneous catalysis using calcium diglyceroxide," Renewable Energy, Elsevier, vol. 159(C), pages 117-126.
    • Handle: RePEc:eee:renene:v:159:y:2020:i:c:p:117-126
    DOI: 10.1016/j.renene.2020.05.020
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    1. Banković-Ilić, Ivana B. & Stamenković, Olivera S. & Veljković, Vlada B., 2012. "Biodiesel production from non-edible plant oils," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(6), pages 3621-3647.
    2. Gui, M.M. & Lee, K.T. & Bhatia, S., 2008. "Feasibility of edible oil vs. non-edible oil vs. waste edible oil as biodiesel feedstock," Energy, Elsevier, vol. 33(11), pages 1646-1653.
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    1. Zamani, Ali Salehi & Saidi, Majid & Najafabadi, Ali Taheri, 2023. "Selective production of diesel-like alkanes via Neem seed oil hydrodeoxygenation over Ni/MgSiO3 catalyst," Renewable Energy, Elsevier, vol. 209(C), pages 462-470.
    2. Tariq, Muhammad & Qureshi, Ahmad Kaleem & Karim, Shaista & Sirajuddin, Muhammad & Abbas, Naseem & Imran, Muhammad & Shirazi, Jaffir Hussain, 2021. "Synthesis, characterization and fuel parameters analysis of linseed oil biodiesel using cadmium oxide nanoparticles," Energy, Elsevier, vol. 222(C).

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