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High-yield production of biodiesel by non-catalytic supercritical methanol transesterification of crude castor oil (Ricinus communis)

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  • Román-Figueroa, Celián
  • Olivares-Carrillo, Pilar
  • Paneque, Manuel
  • Palacios-Nereo, Francisco Javier
  • Quesada-Medina, Joaquín

Abstract

The synthesis of biodiesel from crude castor oil in a catalyst-free process using supercritical methanol in a batch reactor was investigated, studying the evolution of intermediate products as well as the conversion of triglycerides and the yield of FAMEs (fatty acid methyl esters) (biodiesel). Experiments were carried out in a temperature range of 250–350 °C (10–43 MPa) at reaction times of 15–90 min for a methanol-to-oil molar ratio of 43:1. Maintaining thermal stability of biodiesel is one of the most important concerns in high-yield supercritical biodiesel production. Hence, thermal decomposition degree of FAMEs was also investigated in different reaction conditions. The maximum yield of FAMEs (96.5%) was obtained at 300 °C (21 MPa) and 90 min. Under these conditions, the conversion of triglycerides was complete, the yield of intermediate products was low (3.29 and 1.41% for monoglycerides and diglycerides, respectively), and thermal decomposition of FAMEs did not occur. The maximum degree of thermal decomposition (80.9%) was produced at 350 °C (43 MPa) and 90 min. Methyl ricinoleate, whose fatty acid chain was the most abundant (88.09 mol%) in castor oil, was very unstable above 300 °C and 60 min, leading to low yields of FAMEs under these conditions.

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  • Román-Figueroa, Celián & Olivares-Carrillo, Pilar & Paneque, Manuel & Palacios-Nereo, Francisco Javier & Quesada-Medina, Joaquín, 2016. "High-yield production of biodiesel by non-catalytic supercritical methanol transesterification of crude castor oil (Ricinus communis)," Energy, Elsevier, vol. 107(C), pages 165-171.
  • Handle: RePEc:eee:energy:v:107:y:2016:i:c:p:165-171
    DOI: 10.1016/j.energy.2016.03.136
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    6. Sakdasri, Winatta & Sawangkeaw, Ruengwit & Ngamprasertsith, Somkiat, 2018. "Techno-economic analysis of biodiesel production from palm oil with supercritical methanol at a low molar ratio," Energy, Elsevier, vol. 152(C), pages 144-153.
    7. Sina Faizollahzadeh Ardabili & Bahman Najafi & Meysam Alizamir & Amir Mosavi & Shahaboddin Shamshirband & Timon Rabczuk, 2018. "Using SVM-RSM and ELM-RSM Approaches for Optimizing the Production Process of Methyl and Ethyl Esters," Energies, MDPI, vol. 11(11), pages 1-19, October.
    8. Torrentes-Espinoza, G. & Miranda, B.C. & Vega-Baudrit, J. & Mata-Segreda, Julio F., 2017. "Castor oil (Ricinus communis) supercritical methanolysis," Energy, Elsevier, vol. 140(P1), pages 426-435.
    9. Zhu, Qing-li & Gu, Heng & Ke, Zengguang, 2018. "Congeneration biodiesel, ricinine and nontoxic meal from castor seed," Renewable Energy, Elsevier, vol. 120(C), pages 51-59.
    10. Matea Bačić & Anabela Ljubić & Martin Gojun & Anita Šalić & Ana Jurinjak Tušek & Bruno Zelić, 2021. "Continuous Integrated Process of Biodiesel Production and Purification—The End of the Conventional Two-Stage Batch Process?," Energies, MDPI, vol. 14(2), pages 1-17, January.
    11. Lam, Su Shiung & Wan Mahari, Wan Adibah & Cheng, Chin Kui & Omar, Rozita & Chong, Cheng Tung & Chase, Howard A., 2016. "Recovery of diesel-like fuel from waste palm oil by pyrolysis using a microwave heated bed of activated carbon," Energy, Elsevier, vol. 115(P1), pages 791-799.
    12. Andreo-Martínez, Pedro & Ortiz-Martínez, Víctor Manuel & García-Martínez, Nuria & de los Ríos, Antonia Pérez & Hernández-Fernández, Francisco José & Quesada-Medina, Joaquín, 2020. "Production of biodiesel under supercritical conditions: State of the art and bibliometric analysis," Applied Energy, Elsevier, vol. 264(C).
    13. Zulqarnain & Muhammad Ayoub & Mohd Hizami Mohd Yusoff & Muhammad Hamza Nazir & Imtisal Zahid & Mariam Ameen & Farooq Sher & Dita Floresyona & Eduardus Budi Nursanto, 2021. "A Comprehensive Review on Oil Extraction and Biodiesel Production Technologies," Sustainability, MDPI, vol. 13(2), pages 1-28, January.
    14. Aboelazayem, Omar & Gadalla, Mamdouh & Saha, Basudeb, 2018. "Valorisation of high acid value waste cooking oil into biodiesel using supercritical methanolysis: Experimental assessment and statistical optimisation on typical Egyptian feedstock," Energy, Elsevier, vol. 162(C), pages 408-420.

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