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A green approach for enhancing the electrocatalytic activity and stability of NiFe2O4/CB nanospheres towards hydrogen production

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  • Munonde, Tshimangadzo S.
  • Zheng, Haitao
  • Matseke, Mphoma S.
  • Nomngongo, Philiswa N.
  • Wang, Yi
  • Tsiakaras, Panagiotis

Abstract

Among the exfoliation processes applied on layered materials, it is the first time to explore the ultrasonic exfoliation in water for improving the catalytic properties of NiFe2O4/CB (CB = carbon black) nanospheres towards the electrocatalytic hydrogen evolution reaction (HER) in acidic media. It is found that after exfoliation, the overpotential of HER on NiFe2O4/CB nanospheres is improved by about 90 mV at a current density of 10 mA cm−2. Moreover, the exfoliated NiFe2O4/CB nanospheres are not only more stable than the commercial Pt/C catalyst, but also they exhibit an overpotential improvement of about 100 mV at 50 mA cm−2, after 6000 CV cycles.

Suggested Citation

  • Munonde, Tshimangadzo S. & Zheng, Haitao & Matseke, Mphoma S. & Nomngongo, Philiswa N. & Wang, Yi & Tsiakaras, Panagiotis, 2020. "A green approach for enhancing the electrocatalytic activity and stability of NiFe2O4/CB nanospheres towards hydrogen production," Renewable Energy, Elsevier, vol. 154(C), pages 704-714.
    • Handle: RePEc:eee:renene:v:154:y:2020:i:c:p:704-714
    DOI: 10.1016/j.renene.2020.03.022
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    References listed on IDEAS

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    1. Yao, Qilu & Yang, Kangkang & Nie, Wendan & Li, Yaxing & Lu, Zhang-Hui, 2020. "Highly efficient hydrogen generation from hydrazine borane via a MoOx-promoted NiPd nanocatalyst," Renewable Energy, Elsevier, vol. 147(P1), pages 2024-2031.
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    1. Zhao, Meng-Jie & Li, Er-Mei & Deng, Ning & Hu, Yingjie & Li, Chao-Xiong & Li, Bing & Li, Fang & Guo, Zhen-Guo & He, Jian-Bo, 2022. "Indirect electrodeposition of a NiMo@Ni(OH)2MoOx composite catalyst for superior hydrogen production in acidic and alkaline electrolytes," Renewable Energy, Elsevier, vol. 191(C), pages 370-379.

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