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Synergism effect of first row transition metals in experimental and theoretical activity of NiM/rGO alloys at hydrogen evolution reaction in alkaline electrolyzer

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  • Kamali, Saeedeh
  • Zhiani, Mohammad
  • Tavakol, Hossein

Abstract

A series of nanostructure alloys composed of Ni with a non-precious metal (M: Co, Fe, Mn, Cr, Cu and Zn) on the reduced graphene oxide as NiM/rGO are synthesized through a facile solvothermal procedure. Hydrogen evolution reaction (HER) activity of prepared electrocatalysts is evaluated by various electrochemical techniques and performance in alkaline anion exchange membrane (AAEM) electrolyzer. Among the prepared NiM/rGO series, NiCo/rGO electrocatalsyt with Ni/Co mol ratio of 3/1 exhibits the highest HER activity. The measured overpotential at 10 mA cm−2 for a low catalyst loading electrode of NiCo/rGO is as much as 137 mV less than Ni/rGO. The potential of electrolytic cell with Co3O4/rGO and NiCo/rGO electrodes as the anode and cathode, at 0.1 A cm−2 is 1.9 V, lower than that of cell with the same anode but Ni/rGO as the cathode (2.2 V). The differences in NiM/rGO series HER activities are interpreted by various theories such as hypo-hyper-d-electronic combinations, M-H band strength and metals locations in volcano plot. Density functional theory results are also applied along with the experimental data for the explanation of NiM/rGO series HER activity trend. The results confirm the competency of employed procedure for assembling nickel alloys electrodes for alkaline water electrolysis.

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  • Kamali, Saeedeh & Zhiani, Mohammad & Tavakol, Hossein, 2020. "Synergism effect of first row transition metals in experimental and theoretical activity of NiM/rGO alloys at hydrogen evolution reaction in alkaline electrolyzer," Renewable Energy, Elsevier, vol. 154(C), pages 1122-1131.
    • Handle: RePEc:eee:renene:v:154:y:2020:i:c:p:1122-1131
    DOI: 10.1016/j.renene.2020.03.031
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    References listed on IDEAS

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    1. Hussein, Ahmed Kadhim, 2015. "Applications of nanotechnology in renewable energies—A comprehensive overview and understanding," Renewable and Sustainable Energy Reviews, Elsevier, vol. 42(C), pages 460-476.
    2. Gholami, Tahereh & Salavati-Niasari, Masoud & Salehabadi, Ali & Amiri, Mahnaz & Shabani-Nooshabadi, Mehdi & Rezaie, Mehran, 2018. "Electrochemical hydrogen storage properties of NiAl2O4/NiO nanostructures using TiO2, SiO2 and graphene by auto-combustion method using green tea extract," Renewable Energy, Elsevier, vol. 115(C), pages 199-207.
    3. Li, Tian-Feng & Wang, Xi-Qing & Jiao, Jiao & Liu, Ju-Zhao & Zhang, Hua-Xia & Niu, Li-Li & Zhao, Chun-Jian & Gu, Cheng-Bo & Efferth, Thomas & Fu, Yu-Jie, 2018. "Catalytic transesterification of Pistacia chinensis seed oil using HPW immobilized on magnetic composite graphene oxide/cellulose microspheres," Renewable Energy, Elsevier, vol. 127(C), pages 1017-1025.
    4. Ensafi, Ali A. & Zandi-Atashbar, N. & Mohamadi, Z. & Abdolmaleki, A. & Rezaei, B., 2017. "Pt-Pd nanoparticles decorated sulfonated graphene-poly(3,4-ethylene dioxythiophene) nanocomposite, An efficient HER electrocatalyst," Energy, Elsevier, vol. 126(C), pages 88-96.
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    1. Zhao, Meng-Jie & Li, Er-Mei & Deng, Ning & Hu, Yingjie & Li, Chao-Xiong & Li, Bing & Li, Fang & Guo, Zhen-Guo & He, Jian-Bo, 2022. "Indirect electrodeposition of a NiMo@Ni(OH)2MoOx composite catalyst for superior hydrogen production in acidic and alkaline electrolytes," Renewable Energy, Elsevier, vol. 191(C), pages 370-379.
    2. Xue, Xiaojun & Lu, Di & Liu, Yifan & Chen, Heng & Pan, Peiyuan & Xu, Gang & Zhou, Zunkai & Dong, Yuehong, 2023. "Thermodynamic and economic analysis of new compressed air energy storage system integrated with water electrolysis and H2-Fueled solid oxide fuel cell," Energy, Elsevier, vol. 263(PE).

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