IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v154y2020icp1122-1131.html
   My bibliography  Save this article

Synergism effect of first row transition metals in experimental and theoretical activity of NiM/rGO alloys at hydrogen evolution reaction in alkaline electrolyzer

Author

Listed:
  • Kamali, Saeedeh
  • Zhiani, Mohammad
  • Tavakol, Hossein

Abstract

A series of nanostructure alloys composed of Ni with a non-precious metal (M: Co, Fe, Mn, Cr, Cu and Zn) on the reduced graphene oxide as NiM/rGO are synthesized through a facile solvothermal procedure. Hydrogen evolution reaction (HER) activity of prepared electrocatalysts is evaluated by various electrochemical techniques and performance in alkaline anion exchange membrane (AAEM) electrolyzer. Among the prepared NiM/rGO series, NiCo/rGO electrocatalsyt with Ni/Co mol ratio of 3/1 exhibits the highest HER activity. The measured overpotential at 10 mA cm−2 for a low catalyst loading electrode of NiCo/rGO is as much as 137 mV less than Ni/rGO. The potential of electrolytic cell with Co3O4/rGO and NiCo/rGO electrodes as the anode and cathode, at 0.1 A cm−2 is 1.9 V, lower than that of cell with the same anode but Ni/rGO as the cathode (2.2 V). The differences in NiM/rGO series HER activities are interpreted by various theories such as hypo-hyper-d-electronic combinations, M-H band strength and metals locations in volcano plot. Density functional theory results are also applied along with the experimental data for the explanation of NiM/rGO series HER activity trend. The results confirm the competency of employed procedure for assembling nickel alloys electrodes for alkaline water electrolysis.

Suggested Citation

  • Kamali, Saeedeh & Zhiani, Mohammad & Tavakol, Hossein, 2020. "Synergism effect of first row transition metals in experimental and theoretical activity of NiM/rGO alloys at hydrogen evolution reaction in alkaline electrolyzer," Renewable Energy, Elsevier, vol. 154(C), pages 1122-1131.
  • Handle: RePEc:eee:renene:v:154:y:2020:i:c:p:1122-1131
    DOI: 10.1016/j.renene.2020.03.031
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148120303530
    Download Restriction: Full text for ScienceDirect subscribers only

    File URL: https://libkey.io/10.1016/j.renene.2020.03.031?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Hussein, Ahmed Kadhim, 2015. "Applications of nanotechnology in renewable energies—A comprehensive overview and understanding," Renewable and Sustainable Energy Reviews, Elsevier, vol. 42(C), pages 460-476.
    2. Gholami, Tahereh & Salavati-Niasari, Masoud & Salehabadi, Ali & Amiri, Mahnaz & Shabani-Nooshabadi, Mehdi & Rezaie, Mehran, 2018. "Electrochemical hydrogen storage properties of NiAl2O4/NiO nanostructures using TiO2, SiO2 and graphene by auto-combustion method using green tea extract," Renewable Energy, Elsevier, vol. 115(C), pages 199-207.
    3. Li, Tian-Feng & Wang, Xi-Qing & Jiao, Jiao & Liu, Ju-Zhao & Zhang, Hua-Xia & Niu, Li-Li & Zhao, Chun-Jian & Gu, Cheng-Bo & Efferth, Thomas & Fu, Yu-Jie, 2018. "Catalytic transesterification of Pistacia chinensis seed oil using HPW immobilized on magnetic composite graphene oxide/cellulose microspheres," Renewable Energy, Elsevier, vol. 127(C), pages 1017-1025.
    4. Ensafi, Ali A. & Zandi-Atashbar, N. & Mohamadi, Z. & Abdolmaleki, A. & Rezaei, B., 2017. "Pt-Pd nanoparticles decorated sulfonated graphene-poly(3,4-ethylene dioxythiophene) nanocomposite, An efficient HER electrocatalyst," Energy, Elsevier, vol. 126(C), pages 88-96.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Zhao, Meng-Jie & Li, Er-Mei & Deng, Ning & Hu, Yingjie & Li, Chao-Xiong & Li, Bing & Li, Fang & Guo, Zhen-Guo & He, Jian-Bo, 2022. "Indirect electrodeposition of a NiMo@Ni(OH)2MoOx composite catalyst for superior hydrogen production in acidic and alkaline electrolytes," Renewable Energy, Elsevier, vol. 191(C), pages 370-379.
    2. Xue, Xiaojun & Lu, Di & Liu, Yifan & Chen, Heng & Pan, Peiyuan & Xu, Gang & Zhou, Zunkai & Dong, Yuehong, 2023. "Thermodynamic and economic analysis of new compressed air energy storage system integrated with water electrolysis and H2-Fueled solid oxide fuel cell," Energy, Elsevier, vol. 263(PE).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Rajesh Banu Jeyakumar & Godvin Sharmila Vincent, 2022. "Recent Advances and Perspectives of Nanotechnology in Anaerobic Digestion: A New Paradigm towards Sludge Biodegradability," Sustainability, MDPI, vol. 14(12), pages 1-18, June.
    2. Liu, Ju-Zhao & Cui, Qi & Kang, Yu-Fei & Meng, Yao & Gao, Ming-Zhu & Efferth, Thomas & Fu, Yu-Jie, 2019. "Euonymus maackii Rupr. Seed oil as a new potential non-edible feedstock for biodiesel," Renewable Energy, Elsevier, vol. 133(C), pages 261-267.
    3. Li, Jigang & Guo, Yanru & Jiang, Xiaojing & Li, Shuan & Li, Xingguo, 2020. "Hydrogen storage performances, kinetics and microstructure of Ti1.02Cr1.0Fe0.7-xMn0.3Alx alloy by Al substituting for Fe," Renewable Energy, Elsevier, vol. 153(C), pages 1140-1154.
    4. Ghofrani-Isfahani, Parisa & Baniamerian, Hamed & Tsapekos, Panagiotis & Alvarado-Morales, Merlin & Kasama, Takeshi & Shahrokhi, Mohammad & Vossoughi, Manouchehr & Angelidaki, Irini, 2020. "Effect of metal oxide based TiO2 nanoparticles on anaerobic digestion process of lignocellulosic substrate," Energy, Elsevier, vol. 191(C).
    5. Xie, Wenlei & Li, Jiangbo, 2023. "Magnetic solid catalysts for sustainable and cleaner biodiesel production: A comprehensive review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 171(C).
    6. Helmi, Fatemeh & Helmi, Maryam & Hemmati, Alireza, 2022. "Phosphomolybdic acid/chitosan as acid solid catalyst using for biodiesel production from pomegranate seed oil via microwave heating system: RSM optimization and kinetic study," Renewable Energy, Elsevier, vol. 189(C), pages 881-898.
    7. Gustavo Furtado Pereira & Aline da Silva Oliveira & Kelly Cristiane Gomes & José Félix Silva Neto & Thiago Araújo Simões & Antônio Farias Leal & Sandro Marden Torres & Marçal Rosas Florentino Lima Fil, 2022. "Selective Absorbing Surface Based on CrO 3 : Evaluation of Substrates Treatment Influence on the Films Optical Properties," Energies, MDPI, vol. 16(1), pages 1-17, December.
    8. Islam, M.R. & Shabani, B. & Rosengarten, G. & Andrews, J., 2015. "The potential of using nanofluids in PEM fuel cell cooling systems: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 48(C), pages 523-539.
    9. Banković–Ilić, Ivana B. & Miladinović, Marija R. & Stamenković, Olivera S. & Veljković, Vlada B., 2017. "Application of nano CaO–based catalysts in biodiesel synthesis," Renewable and Sustainable Energy Reviews, Elsevier, vol. 72(C), pages 746-760.
    10. Hanaei, Hengameh & Assadi, M. Khalaji & Saidur, R., 2016. "Highly efficient antireflective and self-cleaning coatings that incorporate carbon nanotubes (CNTs) into solar cells: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 59(C), pages 620-635.
    11. Mohammadi-Ganjgah, Ali & Shaterian, Maryam & Bahrami, Hamed & Rasuli, Reza & Yavari, Shabnam & Ghasemi, Razieh & Parvizi, Ziba, 2024. "Electrospun synthesis of polyaniline and titanium dioxide nanofibers as potential electrode materials in electrochemical hydrogen storage," Renewable Energy, Elsevier, vol. 226(C).
    12. Soltani, M. & Moradi Kashkooli, Farshad & Alian Fini, Mehdi & Gharapetian, Derrick & Nathwani, Jatin & Dusseault, Maurice B., 2022. "A review of nanotechnology fluid applications in geothermal energy systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 167(C).
    13. Pacheco-Torgal, F., 2017. "High tech startup creation for energy efficient built environment," Renewable and Sustainable Energy Reviews, Elsevier, vol. 71(C), pages 618-629.
    14. Zhu, Guihua & Wang, Lingling & Bing, Naici & Xie, Huaqing & Yu, Wei, 2019. "Enhancement of photothermal conversion performance using nanofluids based on bimetallic Ag-Au alloys in nitrogen-doped graphitic polyhedrons," Energy, Elsevier, vol. 183(C), pages 747-755.
    15. Barbón, A. & Fernández-Rubiera, J.A. & Martínez-Valledor, L. & Pérez-Fernández, A. & Bayón, L., 2021. "Design and construction of a solar tracking system for small-scale linear Fresnel reflector with three movements," Applied Energy, Elsevier, vol. 285(C).
    16. Ganzoury, Mohamed A. & Allam, Nageh K., 2015. "Impact of nanotechnology on biogas production: A mini-review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 50(C), pages 1392-1404.
    17. Mohamed Sannad & Ahmed Kadhim Hussein & Awatef Abidi & Raad Z. Homod & Uddhaba Biswal & Bagh Ali & Lioua Kolsi & Obai Younis, 2022. "Numerical Study of MHD Natural Convection inside a Cubical Cavity Loaded with Copper-Water Nanofluid by Using a Non-Homogeneous Dynamic Mathematical Model," Mathematics, MDPI, vol. 10(12), pages 1-28, June.
    18. Liu, Na & Guan, JianCheng, 2016. "Policy and innovation: Nanoenergy technology in the USA and China," Energy Policy, Elsevier, vol. 91(C), pages 220-232.
    19. Dugaria, Simone & Bortolato, Matteo & Del Col, Davide, 2018. "Modelling of a direct absorption solar receiver using carbon based nanofluids under concentrated solar radiation," Renewable Energy, Elsevier, vol. 128(PB), pages 495-508.
    20. Ahmadlouydarab, Majid & Ebadolahzadeh, Mohammad & Muhammad Ali, Hafiz, 2020. "Effects of utilizing nanofluid as working fluid in a lab-scale designed FPSC to improve thermal absorption and efficiency," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 540(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:154:y:2020:i:c:p:1122-1131. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.