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Selective hydrogenolysis of lignin-derived aryl ethers over Co/C@N catalysts

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  • Song, Qing-Lu
  • Zhao, Yun-Peng
  • Wu, Fa-Peng
  • Li, Guo-Sheng
  • Fan, Xing
  • Wang, Rui-Yu
  • Cao, Jing-Pei
  • Wei, Xian-Yong

Abstract

Low aromaticity and a large number of oxygen-bridged bonds among the aromatic structural units of lignin make it possible to obtain chemicals directly. A novel Co/C@N catalyst with high activity towards hydrogenolysis of lignin-derived aryl ethers was synthesized according to the pyrolysis process of a predesigned ZIF-67. According to the results of characterization by powder X-ray diffraction (XRD), N2 adsorption-desorption, scanning electron microscopy (SEM), transmission electron microscopy (TEM), and X-ray photoelectron spectroscopy (XPS), Co was reduced by the carbonized organic linker of ZIF-67, and N was doped into the carbon skeleton of the catalyst. The effects of holding time, temperature, and initial H2 pressure on the catalytic performance of Co/C@N were evaluated in the selective hydrogenolysis of benzyl phenyl ether (BPE). BPE was completely converted and the selectivity of monomer reached to 98.2% under optimized reaction conditions. The Calk-O bond in BPE was first dissociated to form toluene and phenol, and then phenol was rapidly hydrogenated to form cyclohexanol. Furthermore, the Co/C@N catalyst shows high activity for hydroprocessing and selective cleavage of other lignin-derived aryl ethers, including phenylethyl phenyl, diphenyl ether, dibenzyl ether, dinaphthalene ether, guaiacol, anisole and veratrole.

Suggested Citation

  • Song, Qing-Lu & Zhao, Yun-Peng & Wu, Fa-Peng & Li, Guo-Sheng & Fan, Xing & Wang, Rui-Yu & Cao, Jing-Pei & Wei, Xian-Yong, 2020. "Selective hydrogenolysis of lignin-derived aryl ethers over Co/C@N catalysts," Renewable Energy, Elsevier, vol. 148(C), pages 729-738.
    • Handle: RePEc:eee:renene:v:148:y:2020:i:c:p:729-738
    DOI: 10.1016/j.renene.2019.10.160
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    References listed on IDEAS

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    1. Katharine Sanderson, 2011. "Lignocellulose: A chewy problem," Nature, Nature, vol. 474(7352), pages 12-14, June.
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    1. Zhu, Chen & Cao, Jing-Pei & Feng, Xiao-Bo & Zhao, Xiao-Yan & Yang, Zhen & Li, Jun & Zhao, Ming & Zhao, Yun-Peng & Bai, Hong-Cun, 2021. "Theoretical insight into the hydrogenolysis mechanism of lignin dimer compounds based on experiments," Renewable Energy, Elsevier, vol. 163(C), pages 1831-1837.
    2. Kumar, Avnish & Biswas, Bijoy & Saini, Komal & Kumar, Adarsh & Kumar, Jitendra & Krishna, Bhavya B. & Bhaskar, Thallada, 2021. "Py-GC/MS study of prot lignin with cobalt impregnated titania, ceria and zirconia catalysts," Renewable Energy, Elsevier, vol. 172(C), pages 121-129.

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