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Molybdenum hybrid – Nanocrystals supported on modified Laponite composite as superior catalyst for vapour phase hydrodeoxygenation of clove oil

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  • Krishnan, P. Santhana
  • Tamizhdurai, P.
  • Theres, G. Sonia
  • Shanthi, K.

Abstract

Valorisation of bio-oil to sustainable energy through hydrodeoxygenation process has been attracted much attention in the development of bio-refineries. The present work emphasizes on the development of a highly active heterogeneous catalyst for hydrodeoxygenation reaction with modified Laponite-γ-alumina and SBA-15 – γ-alumina composites as support for Mo and NiMo catalysts using Mo–inorganic–organic hybrid nanocrystals (HNCs) prepared under hydrothermal condition. The synthesized catalysts were characterised using N2–physisorption, XRD, FT–IR, Raman, HRTEM, TPD/TPR, H2 pulse chemisorption and XPS techniques. The catalysts were evaluated for HDO of eugenol (Lignin model compound, Clove oil) at 400 °C under atmospheric pressure. The physicochemical characterization of the support composites revealed that Mo-HNC supported on modified Laponite exhibited extraordinary stability, metal-support interaction and metal dispersion over the support. The catalytic activity results revealed that the Laponite composite supported NiMo-HNC catalyst performed complete conversion of eugenol with enhanced % selectivity to 3- and 4-propyl phenol (mono-deoxygenated products) and to benzene and 4-propyl cyclohexene (complete deoxygenated products). Thereby, a new Mo-HNC supported modified Laponite composite catalyst has been successfully developed. The role of the HNC-Mo preparation method, textural properties, morphology of Laponite composite catalysts have been demonstrated for efficient HDO of clove oil.

Suggested Citation

  • Krishnan, P. Santhana & Tamizhdurai, P. & Theres, G. Sonia & Shanthi, K., 2020. "Molybdenum hybrid – Nanocrystals supported on modified Laponite composite as superior catalyst for vapour phase hydrodeoxygenation of clove oil," Renewable Energy, Elsevier, vol. 148(C), pages 451-466.
    • Handle: RePEc:eee:renene:v:148:y:2020:i:c:p:451-466
    DOI: 10.1016/j.renene.2019.10.052
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    1. Azadi, Pooya & Inderwildi, Oliver R. & Farnood, Ramin & King, David A., 2013. "Liquid fuels, hydrogen and chemicals from lignin: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 21(C), pages 506-523.
    2. Ericsson, Karin & Nilsson, Lars J. & Nilsson, Måns, 2011. "New energy strategies in the Swedish pulp and paper industry--The role of national and EU climate and energy policies," Energy Policy, Elsevier, vol. 39(3), pages 1439-1449, March.
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