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Study on combustion and emission characteristics of microalgae and its extraction residue with TG-MS

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  • Fang, Peiwen
  • Gong, Zhiqiang
  • Wang, Zhenbo
  • Wang, Zhentong
  • Meng, Fanzhi

Abstract

Experimental study on combustion and emission characteristics of microalgae (M) and the extraction residue (MR) was carried out on a coupled thermogravimetric and mass spectrometer system (TG-MS). TG results showed that combustion process of M and MR can be divided into three stages, including water volatilization, the release and combustion of proteins, carbohydrates and lipids, and minerals decomposition. As the heating rate increased, thermal hysteresis was occurred during combustion of M and MR, especially for M. Friedman method, FWO method and Starink method were used to calculate the apparent activation energy during combustion of M and MR. As the conversion rates increased, the apparent activation energy of M and MR showed different trends. The average apparent activation energy of M and MR in the main combustion stage was 183.41 kJ mol−1 and 144.41 kJ mol−1, respectively. MS results demonstrated that the release of nitrogen-containing compounds of M was more than MR while the release of sulfur-containing compounds was similar during M and MR combustion.

Suggested Citation

  • Fang, Peiwen & Gong, Zhiqiang & Wang, Zhenbo & Wang, Zhentong & Meng, Fanzhi, 2019. "Study on combustion and emission characteristics of microalgae and its extraction residue with TG-MS," Renewable Energy, Elsevier, vol. 140(C), pages 884-894.
    • Handle: RePEc:eee:renene:v:140:y:2019:i:c:p:884-894
    DOI: 10.1016/j.renene.2019.03.114
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    References listed on IDEAS

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    4. Gong, Zhiqiang & Fang, Peiwen & Wang, Zhenbo & Li, Xiaoyu & Wang, Zhentong & Meng, Fanzhi, 2020. "Pyrolysis characteristics and products distribution of haematococcus pluvialis microalgae and its extraction residue," Renewable Energy, Elsevier, vol. 146(C), pages 2134-2141.
    5. Wang, Zhentong & Gong, Zhiqiang & Wang, Wei & Zhang, Zhe, 2020. "Study on combustion characteristics and the migration of heavy metals during the co-combustion of oil sludge char and microalgae residue," Renewable Energy, Elsevier, vol. 151(C), pages 648-658.
    6. Chen, Zhiyun & Liu, Jingyong & Chen, Huashan & Ding, Ziyi & Tang, Xiaojie & Evrendilek, Fatih, 2022. "Oxy-fuel and air atmosphere combustions of Chinese medicine residues: Performances, mechanisms, flue gas emission, and ash properties," Renewable Energy, Elsevier, vol. 182(C), pages 102-118.
    7. Kong, Wenwen & Shen, Boxiong & Ma, Jiao & Kong, Jia & Feng, Shuo & Wang, Zhuozhi & Xiong, Lifu, 2022. "Pyrolysis of Spirulina platensis, Tetradesmus obliquus and Chlorella vulgaris by TG-FTIR and Py-GC/MS: Kinetic analysis and pyrolysis behaviour," Energy, Elsevier, vol. 244(PB).

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