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Simultaneous production of glucose, furfural, and ethanol organosolv lignin for total utilization of high recalcitrant biomass by organosolv pretreatment

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  • Choi, June-Ho
  • Jang, Soo-Kyeong
  • Kim, Jong-Hwa
  • Park, Se-Yeong
  • Kim, Jong-Chan
  • Jeong, Hanseob
  • Kim, Ho-Yong
  • Choi, In-Gyu

Abstract

The main purpose of this study was simultaneous production of glucose, ethanol organosolv lignin (EOL), and furfural for total utilization of lignocellulosic biomass to improve economics of biorefinery. The glucose production (37.1 g, under conditions of 160 °C with 1% sulfuric acid) was significantly increased after organosolv pretreatment, dissolving 11.4 g of the initial hemicellulose-derived sugars and 22.6 g of the initial lignin. Progressively, organosolv lignin precipitation and furfural production processes were conducted using the liquid hydrolysates obtained after organosolv pretreatment. 12 g of EOL (at 160 °C, 1% sulfuric acid) was yielded with the remaining residues of soluble lignin-derived compounds in the liquid hydrolysates. Also, 7.9 g of furfural (at 160 °C, 1% sulfuric acid) was observed after additional acid-catalyzed treatment from the liquid hydrolysates. Consequently, a high yield of glucose, EOL and furfural can be obtained simultaneously using ethanol organosolv pretreatment.

Suggested Citation

  • Choi, June-Ho & Jang, Soo-Kyeong & Kim, Jong-Hwa & Park, Se-Yeong & Kim, Jong-Chan & Jeong, Hanseob & Kim, Ho-Yong & Choi, In-Gyu, 2019. "Simultaneous production of glucose, furfural, and ethanol organosolv lignin for total utilization of high recalcitrant biomass by organosolv pretreatment," Renewable Energy, Elsevier, vol. 130(C), pages 952-960.
    • Handle: RePEc:eee:renene:v:130:y:2019:i:c:p:952-960
    DOI: 10.1016/j.renene.2018.05.052
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    References listed on IDEAS

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    1. Jang, Soo-Kyeong & Kim, Ho-Yong & Jeong, Han-Seob & Kim, Jae-Young & Yeo, Hwanmyeong & Choi, In-Gyu, 2016. "Effect of ethanol organosolv pretreatment factors on enzymatic digestibility and ethanol organosolv lignin structure from Liriodendron tulipifera in specific combined severity factors," Renewable Energy, Elsevier, vol. 87(P1), pages 599-606.
    2. Christos Nitsos & Ulrika Rova & Paul Christakopoulos, 2017. "Organosolv Fractionation of Softwood Biomass for Biofuel and Biorefinery Applications," Energies, MDPI, vol. 11(1), pages 1-23, December.
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    12. Chu, Qiulu & Tong, Wenyao & Wu, Shufang & Jin, Yongcan & Hu, Jinguang & Song, Kai, 2021. "Modification of lignin by various additives to mitigate lignin inhibition for improved enzymatic digestibility of dilute acid pretreated hardwood," Renewable Energy, Elsevier, vol. 177(C), pages 992-1000.

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