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Preparation of biofuels with waste cooking oil by fluid catalytic cracking: The effect of catalyst performance on the products

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  • Wang, Yan
  • Cao, Yang
  • Li, Jin

Abstract

Biofuels were produced with waste cooking oil by Fluid Catalytic Cracking (FCC). The catalytic reactions involved two catalysts of Endurance and CGP-1HN, which were characterized by Scanning Electron Microscopy (SEM), N2 Adsorption-Desorption, X-ray Diffraction (XRD) and Pyridine Fourier Transform Infrared Spectroscopy (Py-FTIR). The results indicated that the structure and properties of Endurance and CGP-1HN were similar, and the most obvious difference between them was a different content of acid sites. The Lewis and Brönsted acid contents of Endurance were 189.39 and 341.69 μmol/g, respectively, and the Lewis and Brönsted acid contents of CGP-1HN were 21.53 and 258.23 μmol/g, respectively. The different acid sites resulted in different distributions of products under the same reaction conditions. A higher diesel yield (32.04 wt%) was achieved using Endurance, and a higher Liquefied Petroleum Gas(LPG) yield (42.71 wt%) was produced using CGP-1HN. The result shows that different type acid and acid contents effect on the product distribution. The Lewis acid sites decreases the catalytic cracking depth of waste cooking oil.

Suggested Citation

  • Wang, Yan & Cao, Yang & Li, Jin, 2018. "Preparation of biofuels with waste cooking oil by fluid catalytic cracking: The effect of catalyst performance on the products," Renewable Energy, Elsevier, vol. 124(C), pages 34-39.
    • Handle: RePEc:eee:renene:v:124:y:2018:i:c:p:34-39
    DOI: 10.1016/j.renene.2017.08.084
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    References listed on IDEAS

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    1. Zhou, Xin & Yan, Hao & Sun, Zongzhuang & Feng, Xiang & Zhao, Hui & Liu, Yibin & Chen, Xiaobo & Yang, Chaohe, 2021. "Opportunities for utilizing waste cooking oil in crude to petrochemical process: Novel process design, optimal strategy, techno-economic analysis and life cycle society-environment assessment," Energy, Elsevier, vol. 237(C).
    2. Le-Phuc, Nguyen & Tran, Tri V. & Phan, Thien T. & Ngo, Phuong T. & Ha, Quan L.M. & Luong, Thuy N. & Tran, Thinh H. & Phan, Tuan T., 2021. "High-efficient production of biofuels using spent fluid catalytic cracking (FCC) catalysts and high acid value waste cooking oils," Renewable Energy, Elsevier, vol. 168(C), pages 57-63.

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