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Deactivation characteristics of Ni and Ru catalysts in tar steam reforming

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  • Park, Seo Yun
  • Oh, Gunung
  • Kim, Kwangyul
  • Seo, Myung Won
  • Ra, Ho Won
  • Mun, Tae Young
  • Lee, Jae Goo
  • Yoon, Sang Jun

Abstract

Tar formation resulting during lignocellulosic biomass gasification is a major impediment to utilizing biomass energy sources, in that it blocks and fouls the processing equipment; as such, any tar present in the produced syngas much be effectively removed. This study analyzes the ability of commercially available Ni and Ru based CH4 reforming catalysts to effect tar removal and compares deactivation characteristics. Toluene was used as the model biomass tar at concentrations of 30 and 100 g/Nm3. Several additional parameters were also tested, including reaction temperatures (400–800 °C), space velocities (5000–30,000 h−1), and the steam/toluene ratios (2–20). The variation of toluene conversion and product gas composition with reaction conditions was analyzed. Overall, H2 and CO production were favored by the Ru catalyst and generally increased with temperature. Conversion also increased with temperature, with conversions higher than 90% obtained at 800 °C.

Suggested Citation

  • Park, Seo Yun & Oh, Gunung & Kim, Kwangyul & Seo, Myung Won & Ra, Ho Won & Mun, Tae Young & Lee, Jae Goo & Yoon, Sang Jun, 2017. "Deactivation characteristics of Ni and Ru catalysts in tar steam reforming," Renewable Energy, Elsevier, vol. 105(C), pages 76-83.
    • Handle: RePEc:eee:renene:v:105:y:2017:i:c:p:76-83
    DOI: 10.1016/j.renene.2016.12.045
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    1. Li, Chunshan & Suzuki, Kenzi, 2009. "Tar property, analysis, reforming mechanism and model for biomass gasification--An overview," Renewable and Sustainable Energy Reviews, Elsevier, vol. 13(3), pages 594-604, April.
    2. Guan, Guoqing & Kaewpanha, Malinee & Hao, Xiaogang & Abudula, Abuliti, 2016. "Catalytic steam reforming of biomass tar: Prospects and challenges," Renewable and Sustainable Energy Reviews, Elsevier, vol. 58(C), pages 450-461.
    3. An, Lu & Dong, Changqing & Yang, Yongping & Zhang, Junjiao & He, Lei, 2011. "The influence of Ni loading on coke formation in steam reforming of acetic acid," Renewable Energy, Elsevier, vol. 36(3), pages 930-935.
    4. Yoon, Sang Jun & Son, Yung-Il & Kim, Yong-Ku & Lee, Jae-Goo, 2012. "Gasification and power generation characteristics of rice husk and rice husk pellet using a downdraft fixed-bed gasifier," Renewable Energy, Elsevier, vol. 42(C), pages 163-167.
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    2. Sun, Jing & Wang, Qing & Wang, Wenlong & Wang, Ke, 2018. "Study on the synergism of steam reforming and photocatalysis for the degradation of Toluene as a tar model compound under microwave-metal discharges," Energy, Elsevier, vol. 155(C), pages 815-823.
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    4. Dmitrii Glushkov & Galina Nyashina & Anatolii Shvets & Amaro Pereira & Anand Ramanathan, 2021. "Current Status of the Pyrolysis and Gasification Mechanism of Biomass," Energies, MDPI, vol. 14(22), pages 1-24, November.
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    6. Zhang, Shuping & Yin, Haoxin & Wang, Jiaxing & Zhu, Shuguang & Xiong, Yuanquan, 2021. "Catalytic cracking of biomass tar using Ni nanoparticles embedded carbon nanofiber/porous carbon catalysts," Energy, Elsevier, vol. 216(C).
    7. Li, Longzhi & Meng, Bo & Qin, Xiaomin & Yang, Zhijuan & Chen, Jian & Yan, Keshuo & Wang, Fumao, 2020. "Toluene microwave cracking and reforming over bio-char with in-situ activation and ex-situ impregnation of metal," Renewable Energy, Elsevier, vol. 149(C), pages 1205-1213.
    8. Hervy, Maxime & Weiss-Hortala, Elsa & Pham Minh, Doan & Dib, Hadi & Villot, Audrey & Gérente, Claire & Berhanu, Sarah & Chesnaud, Anthony & Thorel, Alain & Le Coq, Laurence & Nzihou, Ange, 2019. "Reactivity and deactivation mechanisms of pyrolysis chars from bio-waste during catalytic cracking of tar," Applied Energy, Elsevier, vol. 237(C), pages 487-499.
    9. Li, Dedi & Liu, Jianzhong & Wang, Shuangni & Cheng, Jun, 2020. "Study on coal water slurries prepared from coal chemical wastewater and their industrial application," Applied Energy, Elsevier, vol. 268(C).

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