IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v105y2017icp76-83.html
   My bibliography  Save this article

Deactivation characteristics of Ni and Ru catalysts in tar steam reforming

Author

Listed:
  • Park, Seo Yun
  • Oh, Gunung
  • Kim, Kwangyul
  • Seo, Myung Won
  • Ra, Ho Won
  • Mun, Tae Young
  • Lee, Jae Goo
  • Yoon, Sang Jun

Abstract

Tar formation resulting during lignocellulosic biomass gasification is a major impediment to utilizing biomass energy sources, in that it blocks and fouls the processing equipment; as such, any tar present in the produced syngas much be effectively removed. This study analyzes the ability of commercially available Ni and Ru based CH4 reforming catalysts to effect tar removal and compares deactivation characteristics. Toluene was used as the model biomass tar at concentrations of 30 and 100 g/Nm3. Several additional parameters were also tested, including reaction temperatures (400–800 °C), space velocities (5000–30,000 h−1), and the steam/toluene ratios (2–20). The variation of toluene conversion and product gas composition with reaction conditions was analyzed. Overall, H2 and CO production were favored by the Ru catalyst and generally increased with temperature. Conversion also increased with temperature, with conversions higher than 90% obtained at 800 °C.

Suggested Citation

  • Park, Seo Yun & Oh, Gunung & Kim, Kwangyul & Seo, Myung Won & Ra, Ho Won & Mun, Tae Young & Lee, Jae Goo & Yoon, Sang Jun, 2017. "Deactivation characteristics of Ni and Ru catalysts in tar steam reforming," Renewable Energy, Elsevier, vol. 105(C), pages 76-83.
    • Handle: RePEc:eee:renene:v:105:y:2017:i:c:p:76-83
    DOI: 10.1016/j.renene.2016.12.045
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148116311004
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2016.12.045?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Guan, Guoqing & Kaewpanha, Malinee & Hao, Xiaogang & Abudula, Abuliti, 2016. "Catalytic steam reforming of biomass tar: Prospects and challenges," Renewable and Sustainable Energy Reviews, Elsevier, vol. 58(C), pages 450-461.
    2. An, Lu & Dong, Changqing & Yang, Yongping & Zhang, Junjiao & He, Lei, 2011. "The influence of Ni loading on coke formation in steam reforming of acetic acid," Renewable Energy, Elsevier, vol. 36(3), pages 930-935.
    3. Li, Chunshan & Suzuki, Kenzi, 2009. "Tar property, analysis, reforming mechanism and model for biomass gasification--An overview," Renewable and Sustainable Energy Reviews, Elsevier, vol. 13(3), pages 594-604, April.
    4. Yoon, Sang Jun & Son, Yung-Il & Kim, Yong-Ku & Lee, Jae-Goo, 2012. "Gasification and power generation characteristics of rice husk and rice husk pellet using a downdraft fixed-bed gasifier," Renewable Energy, Elsevier, vol. 42(C), pages 163-167.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Sun, Jing & Wang, Qing & Wang, Wenlong & Wang, Ke, 2018. "Study on the synergism of steam reforming and photocatalysis for the degradation of Toluene as a tar model compound under microwave-metal discharges," Energy, Elsevier, vol. 155(C), pages 815-823.
    2. Liu, Chenlong & Chen, Dong & Cao, Yongan & zhang, Tianxi & Mao, Yangyang & Wang, Wenju & Wang, Zhigang & Kawi, Sibudjing, 2020. "Catalytic steam reforming of in-situ tar from rice husk over MCM-41 supported LaNiO3 to produce hydrogen rich syngas," Renewable Energy, Elsevier, vol. 161(C), pages 408-418.
    3. Dmitrii Glushkov & Galina Nyashina & Anatolii Shvets & Amaro Pereira & Anand Ramanathan, 2021. "Current Status of the Pyrolysis and Gasification Mechanism of Biomass," Energies, MDPI, vol. 14(22), pages 1-24, November.
    4. Čespiva, Jakub & Wnukowski, Mateusz & Niedzwiecki, Lukasz & Skřínský, Jan & Vereš, Ján & Ochodek, Tadeáš & Pawlak-Kruczek, Halina & Borovec, Karel, 2020. "Characterization of tars from a novel, pilot scale, biomass gasifier working under low equivalence ratio regime," Renewable Energy, Elsevier, vol. 159(C), pages 775-785.
    5. Li, Dedi & Liu, Jianzhong & Wang, Shuangni & Cheng, Jun, 2020. "Study on coal water slurries prepared from coal chemical wastewater and their industrial application," Applied Energy, Elsevier, vol. 268(C).
    6. Zhang, Shuping & Yin, Haoxin & Wang, Jiaxing & Zhu, Shuguang & Xiong, Yuanquan, 2021. "Catalytic cracking of biomass tar using Ni nanoparticles embedded carbon nanofiber/porous carbon catalysts," Energy, Elsevier, vol. 216(C).
    7. Xu, Liya & Dong, Kaiming & Guo, Feiqiang & Liu, Sha & Qiao, Qixia & Mao, Songbo & Qian, Lin & Bai, Yonghui, 2023. "Synthesis of zeolite-based porous catalysts from coal gasification fine slag for steam reforming of toluene," Energy, Elsevier, vol. 274(C).
    8. Li, Longzhi & Meng, Bo & Qin, Xiaomin & Yang, Zhijuan & Chen, Jian & Yan, Keshuo & Wang, Fumao, 2020. "Toluene microwave cracking and reforming over bio-char with in-situ activation and ex-situ impregnation of metal," Renewable Energy, Elsevier, vol. 149(C), pages 1205-1213.
    9. Hervy, Maxime & Weiss-Hortala, Elsa & Pham Minh, Doan & Dib, Hadi & Villot, Audrey & Gérente, Claire & Berhanu, Sarah & Chesnaud, Anthony & Thorel, Alain & Le Coq, Laurence & Nzihou, Ange, 2019. "Reactivity and deactivation mechanisms of pyrolysis chars from bio-waste during catalytic cracking of tar," Applied Energy, Elsevier, vol. 237(C), pages 487-499.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Li, Xueqin & Liu, Peng & Lei, Tingzhou & Wu, Youqing & Chen, Wenxuan & Wang, Zhiwei & Shi, Jie & Wu, Shiyong & Li, Yanling & Huang, Sheng, 2022. "Pyrolysis of biomass Tar model compound with various Ni-based catalysts: Influence of promoters characteristics on hydrogen-rich gas formation," Energy, Elsevier, vol. 244(PB).
    2. Rakesh N, & Dasappa, S., 2018. "A critical assessment of tar generated during biomass gasification - Formation, evaluation, issues and mitigation strategies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 91(C), pages 1045-1064.
    3. Sun, Jing & Wang, Qing & Wang, Wenlong & Wang, Ke, 2018. "Study on the synergism of steam reforming and photocatalysis for the degradation of Toluene as a tar model compound under microwave-metal discharges," Energy, Elsevier, vol. 155(C), pages 815-823.
    4. Li, Jian & Tao, Junyu & Yan, Beibei & Jiao, Liguo & Chen, Guanyi & Hu, Jianli, 2021. "Review of microwave-based treatments of biomass gasification tar," Renewable and Sustainable Energy Reviews, Elsevier, vol. 150(C).
    5. Tian, Beile & Du, Shilin & Guo, Feiqiang & Dong, Yichen & Mao, Songbo & Qian, Lin & Liu, Qi, 2021. "Synthesis of biomimetic monolithic biochar-based catalysts for catalytic decomposition of biomass pyrolysis tar," Energy, Elsevier, vol. 222(C).
    6. Li, Jian & Jiao, Liguo & Tao, Junyu & Chen, Guanyi & Hu, Jianli & Yan, Beibei & Mansour, Mohy & Guo, Yaoyu & Ye, Peiwen & Ding, Zheng & Yu, Tianxiao, 2020. "Can microwave treat biomass tar? A comprehensive study based on experimental and net energy analysis," Applied Energy, Elsevier, vol. 272(C).
    7. Jana, Kuntal & Ray, Avishek & Majoumerd, Mohammad Mansouri & Assadi, Mohsen & De, Sudipta, 2017. "Polygeneration as a future sustainable energy solution – A comprehensive review," Applied Energy, Elsevier, vol. 202(C), pages 88-111.
    8. Hu, Fu-Xiang & Yang, Guo-Hua & Ding, Guo-Zhu & Li, Zhen & Du, Ka-Shuai & Hu, Zhi-Fa & Tian, Su-Rui, 2016. "Experimental study on catalytic cracking of model tar compounds in a dual layer granular bed filter," Applied Energy, Elsevier, vol. 170(C), pages 47-57.
    9. Ahmed, A.M.A & Salmiaton, A. & Choong, T.S.Y & Wan Azlina, W.A.K.G., 2015. "Review of kinetic and equilibrium concepts for biomass tar modeling by using Aspen Plus," Renewable and Sustainable Energy Reviews, Elsevier, vol. 52(C), pages 1623-1644.
    10. Buentello-Montoya, D.A. & Duarte-Ruiz, C.A. & Maldonado-Escalante, J.F., 2023. "Co-gasification of waste PET, PP and biomass for energy recovery: A thermodynamic model to assess the produced syngas quality," Energy, Elsevier, vol. 266(C).
    11. Liu, Zhongzhe & Singer, Simcha & Tong, Yiran & Kimbell, Lee & Anderson, Erik & Hughes, Matthew & Zitomer, Daniel & McNamara, Patrick, 2018. "Characteristics and applications of biochars derived from wastewater solids," Renewable and Sustainable Energy Reviews, Elsevier, vol. 90(C), pages 650-664.
    12. Ruivo, Luís & Silva, Tiago & Neves, Daniel & Tarelho, Luís & Frade, Jorge, 2023. "Thermodynamic guidelines for improved operation of iron-based catalysts in gasification of biomass," Energy, Elsevier, vol. 268(C).
    13. Farhad Beik & Leon Williams & Tim Brown & Stuart T. Wagland, 2021. "Managing Non-Sewered Human Waste Using Thermochemical Waste Treatment Technologies: A Review," Energies, MDPI, vol. 14(22), pages 1-22, November.
    14. Di Wu & Heming Dong & Jiyi Luan & Qian Du & Jianmin Gao & Dongdong Feng & Yu Zhang & Ziqi Zhao & Dun Li, 2023. "Reaction Molecular Dynamics Study on the Mechanism of Alkali Metal Sodium at the Initial Stage of Naphthalene Pyrolysis Evolution," Energies, MDPI, vol. 16(17), pages 1-19, August.
    15. Jiao, Liguo & Li, Jian & Yan, Beibei & Chen, Guanyi & Ahmed, Sarwaich, 2022. "Microwave torrefaction integrated with gasification: Energy and exergy analyses based on Aspen Plus modeling," Applied Energy, Elsevier, vol. 319(C).
    16. Song, Hee Gaen & Chun, Young Nam, 2020. "Tar decomposition-reforming conversion on microwave-heating carbon receptor," Energy, Elsevier, vol. 199(C).
    17. Kwofie, E.M. & Ngadi, M., 2016. "Sustainable energy supply for local rice parboiling in West Africa: The potential of rice husk," Renewable and Sustainable Energy Reviews, Elsevier, vol. 56(C), pages 1409-1418.
    18. Pang, Yunji & Wu, Yuting & Chen, Yisheng & Luo, Fuliang & Chen, Junjun, 2020. "Degradation effect of Ce/Al2O3 catalyst on pyrolysis volatility of pine," Renewable Energy, Elsevier, vol. 162(C), pages 134-143.
    19. Al-Rahbi, Amal S. & Williams, Paul T., 2017. "Hydrogen-rich syngas production and tar removal from biomass gasification using sacrificial tyre pyrolysis char," Applied Energy, Elsevier, vol. 190(C), pages 501-509.
    20. Shen, Yafei, 2017. "Rice husk silica derived nanomaterials for sustainable applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 80(C), pages 453-466.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:105:y:2017:i:c:p:76-83. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.