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Thermogravimetric pyrolysis of waste polyethylene-terephthalate and polystyrene: A critical assessment of kinetics modelling

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  • Brems, Anke
  • Baeyens, Jan
  • Beerlandt, Johan
  • Dewil, Raf

Abstract

Pyrolysis is considered as possible technique to thermally convert waste plastics into chemicals and energy. Literature on experimental findings is extensive, although experiments are mostly performed in a dynamic heating mode, using thermogravimetric analysis (TGA) and at low values of the heating rate (mostly below 30K/min). The present research differs from literature through the application of far higher heating rates, up to 120K/min. The use of these dynamic results to define the reaction kinetics necessitates the selection of an appropriate reaction mechanism, and 21 models have been proposed in literature considering the rate limiting step being diffusion, nucleation or the reaction itself.

Suggested Citation

  • Brems, Anke & Baeyens, Jan & Beerlandt, Johan & Dewil, Raf, 2011. "Thermogravimetric pyrolysis of waste polyethylene-terephthalate and polystyrene: A critical assessment of kinetics modelling," Resources, Conservation & Recycling, Elsevier, vol. 55(8), pages 772-781.
    • Handle: RePEc:eee:recore:v:55:y:2011:i:8:p:772-781
    DOI: 10.1016/j.resconrec.2011.03.003
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    References listed on IDEAS

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    1. Van de Velden, Manon & Baeyens, Jan & Brems, Anke & Janssens, Bart & Dewil, Raf, 2010. "Fundamentals, kinetics and endothermicity of the biomass pyrolysis reaction," Renewable Energy, Elsevier, vol. 35(1), pages 232-242.
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    Cited by:

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    2. Sánchez-Jiménez, Pedro E. & Pérez-Maqueda, Luis A. & Perejón, Antonio & Criado, José M., 2013. "Limitations of model-fitting methods for kinetic analysis: Polystyrene thermal degradation," Resources, Conservation & Recycling, Elsevier, vol. 74(C), pages 75-81.
    3. Kim, D. & Hadigheh, S.A., 2024. "Oxidative pyrolysis of biosolid: Air concentration effects on biochar formation and kinetics," Renewable Energy, Elsevier, vol. 224(C).
    4. Escalante, Jamin & Chen, Wei-Hsin & Tabatabaei, Meisam & Hoang, Anh Tuan & Kwon, Eilhann E. & Andrew Lin, Kun-Yi & Saravanakumar, Ayyadurai, 2022. "Pyrolysis of lignocellulosic, algal, plastic, and other biomass wastes for biofuel production and circular bioeconomy: A review of thermogravimetric analysis (TGA) approach," Renewable and Sustainable Energy Reviews, Elsevier, vol. 169(C).
    5. Agnieszka Kijo-Kleczkowska & Adam Gnatowski, 2022. "Recycling of Plastic Waste, with Particular Emphasis on Thermal Methods—Review," Energies, MDPI, vol. 15(6), pages 1-21, March.
    6. Li, Weizhen & Huang, Yanqin & Liu, Huacai & Zhang, Yan & Jiang, Yang & Wang, Yan & Wan, Junfeng & Yin, Xiuli, 2022. "Kinetic and thermodynamic studies of biomass pseudo-components under thermo-oxidative degradation conditions using asymmetric function of Bi-Gaussian as deconvolution technique," Renewable Energy, Elsevier, vol. 188(C), pages 491-503.

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