IDEAS home Printed from https://ideas.repec.org/a/eee/phsmap/v626y2023ics0378437123005964.html
   My bibliography  Save this article

Configurational entropy of self-propelled glass formers

Author

Listed:
  • C.N., Sachin
  • Joy, Ashwin

Abstract

The configurational entropy is an indispensable tool to describe super-cooled liquids near the glass transition. Its calculation requires the enumeration of basins in the potential energy landscape and when available, it reveals a direct connection with the relaxation time of the liquid. While there are several reports on the measurement of configurational entropy in passive liquids, very little is understood about its role in active liquids undergoing glass transition at low temperatures, even in the limit of low activity. In this paper, we report a careful calculation of the configurational entropy in a model glass former where the constituent units are self propelled. We show that unlike passive liquids, the anharmonic contribution to the glass entropy in these self-propelled liquids can be of the same order as the harmonic contribution, and therefore must be included in calculation of the configurational entropy. Our extracted configurational entropy is in good agreement with the generalized Adam–Gibbs relation predicted by the random first order transition theory enabling us to deduce a scaling relation between configurational entropy and a point-to-set length scale in these active systems. Our findings could be of great utility in conventional active systems such as self-propelled granules, Janus particles and dense bacterial suspensions, to mention a few.

Suggested Citation

  • C.N., Sachin & Joy, Ashwin, 2023. "Configurational entropy of self-propelled glass formers," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 626(C).
  • Handle: RePEc:eee:phsmap:v:626:y:2023:i:c:s0378437123005964
    DOI: 10.1016/j.physa.2023.129041
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0378437123005964
    Download Restriction: Full text for ScienceDirect subscribers only. Journal offers the option of making the article available online on Science direct for a fee of $3,000

    File URL: https://libkey.io/10.1016/j.physa.2023.129041?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Silke Henkes & Kaja Kostanjevec & J. Martin Collinson & Rastko Sknepnek & Eric Bertin, 2020. "Dense active matter model of motion patterns in confluent cell monolayers," Nature Communications, Nature, vol. 11(1), pages 1-9, December.
    2. Rituparno Mandal & Pranab Jyoti Bhuyan & Pinaki Chaudhuri & Chandan Dasgupta & Madan Rao, 2020. "Extreme active matter at high densities," Nature Communications, Nature, vol. 11(1), pages 1-8, December.
    3. Sastry, Srikanth & Debenedetti, Pablo G. & Stillinger, Frank H. & Schrøder, Thomas B. & Dyre, Jeppe C. & Glotzer, Sharon C., 1999. "Potential energy landscape signatures of slow dynamics in glass forming liquids," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 270(1), pages 301-308.
    4. Antoine Bricard & Jean-Baptiste Caussin & Debasish Das & Charles Savoie & Vijayakumar Chikkadi & Kyohei Shitara & Oleksandr Chepizhko & Fernando Peruani & David Saintillan & Denis Bartolo, 2015. "Emergent vortices in populations of colloidal rollers," Nature Communications, Nature, vol. 6(1), pages 1-8, November.
    5. Pablo G. Debenedetti & Frank H. Stillinger, 2001. "Supercooled liquids and the glass transition," Nature, Nature, vol. 410(6825), pages 259-267, March.
    6. Srikanth Sastry, 2001. "The relationship between fragility, configurational entropy and the potential energy landscape of glass-forming liquids," Nature, Nature, vol. 409(6817), pages 164-167, January.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. C.N., Sachin & Joy, Ashwin, 2022. "Entropy scaling laws in self propelled glass formers," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 588(C).
    2. Hengwei Luan & Xin Zhang & Hongyu Ding & Fei Zhang & J. H. Luan & Z. B. Jiao & Yi-Chieh Yang & Hengtong Bu & Ranbin Wang & Jialun Gu & Chunlin Shao & Qing Yu & Yang Shao & Qiaoshi Zeng & Na Chen & C. , 2022. "High-entropy induced a glass-to-glass transition in a metallic glass," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    3. Birte Riechers & Amlan Das & Eric Dufresne & Peter M. Derlet & Robert Maaß, 2024. "Intermittent cluster dynamics and temporal fractional diffusion in a bulk metallic glass," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    4. Nicole L. Mandel & Soohyun Lee & Kimyung Kim & Keewook Paeng & Laura J. Kaufman, 2022. "Single molecule demonstration of Debye–Stokes–Einstein breakdown in polystyrene near the glass transition temperature," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    5. Simone Ciarella & Dmytro Khomenko & Ludovic Berthier & Felix C. Mocanu & David R. Reichman & Camille Scalliet & Francesco Zamponi, 2023. "Finding defects in glasses through machine learning," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    6. Lemke, N & de Almeida, R.M.C, 2004. "Diffusion on fractal phase spaces and entropy production," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 340(1), pages 309-315.
    7. Pragya Arora & Souvik Sadhukhan & Saroj Kumar Nandi & Dapeng Bi & A. K. Sood & Rajesh Ganapathy, 2024. "A shape-driven reentrant jamming transition in confluent monolayers of synthetic cell-mimics," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    8. Leo Zella & Jaeyun Moon & Takeshi Egami, 2024. "Ripples in the bottom of the potential energy landscape of metallic glass," Nature Communications, Nature, vol. 15(1), pages 1-7, December.
    9. Lars V. Bock & Helmut Grubmüller, 2022. "Effects of cryo-EM cooling on structural ensembles," Nature Communications, Nature, vol. 13(1), pages 1-13, December.
    10. Giuseppe Cassone & Fausto Martelli, 2024. "Electrofreezing of liquid water at ambient conditions," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    11. Hideaki Murase & Shunto Arai & Tatsuo Hasegawa & Kazuya Miyagawa & Kazushi Kanoda, 2023. "Spatiotemporal observation of quantum crystallization of electrons," Nature Communications, Nature, vol. 14(1), pages 1-7, December.
    12. Jyoti Prasad Banerjee & Rituparno Mandal & Deb Sankar Banerjee & Shashi Thutupalli & Madan Rao, 2022. "Unjamming and emergent nonreciprocity in active ploughing through a compressible viscoelastic fluid," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    13. Roger Farmer & Jean-Philippe Bouchaud, 2020. "Self-Fulfilling Prophecies, Quasi Non-Ergodicity & Wealth Inequality," NBER Working Papers 28261, National Bureau of Economic Research, Inc.
    14. Chung Wing Chan & Daihui Wu & Kaiyao Qiao & Kin Long Fong & Zhiyu Yang & Yilong Han & Rui Zhang, 2024. "Chiral active particles are sensitive reporters to environmental geometry," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    15. Toledo-Marín, J. Quetzalcóatl & Castillo, Isaac Pérez & Naumis, Gerardo G., 2016. "Minimal cooling speed for glass transition in a simple solvable energy landscape model," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 451(C), pages 227-236.
    16. Peng Luo & Yanqin Zhai & Peter Falus & Victoria García Sakai & Monika Hartl & Maiko Kofu & Kenji Nakajima & Antonio Faraone & Y Z, 2022. "Q-dependent collective relaxation dynamics of glass-forming liquid Ca0.4K0.6(NO3)1.4 investigated by wide-angle neutron spin-echo," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    17. Sheykhali, Somaye & Darooneh, Amir Hossein & Jafari, Gholam Reza, 2020. "Partial balance in social networks with stubborn links," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 548(C).
    18. Bo Zhang & Andreas Glatz & Igor S. Aranson & Alexey Snezhko, 2023. "Spontaneous shock waves in pulse-stimulated flocks of Quincke rollers," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    19. Rituparno Mandal & Corneel Casert & Peter Sollich, 2022. "Robust prediction of force chains in jammed solids using graph neural networks," Nature Communications, Nature, vol. 13(1), pages 1-7, December.
    20. Solenn Riedel & Ludwig A. Hoffmann & Luca Giomi & Daniela J. Kraft, 2024. "Designing highly efficient interlocking interactions in anisotropic active particles," Nature Communications, Nature, vol. 15(1), pages 1-9, December.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:phsmap:v:626:y:2023:i:c:s0378437123005964. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/physica-a-statistical-mechpplications/ .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.