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Energy efficiency of a hybrid membrane/condensation process for VOC (Volatile Organic Compounds) recovery from air: A generic approach

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  • Belaissaoui, Bouchra
  • Le Moullec, Yann
  • Favre, Eric

Abstract

The recovery of VOC (Volatile Organic Compounds) from air is a major issue in terms of minimizing the environmental impact of numerous industrial processes (chemistry, food, pharmaceutical, metallurgy, refrigeration…). Non destructive VOC capture technologies are preferentially used in order to enable the recycling of a large ratio of the emitted compounds. To that respect, condensation is attractive because it offers the possibility to recover the VOC from the air stream under liquid state thanks to a physical, non destructive, separation process. Nevertheless, a very low (cryogenic) condensation temperature is often required in order to achieve that target. In that case, a membrane VOC pre-concentration step can be of major interest in order to increase the VOC content of the condensation unit and possibly improve the energy efficiency of the overall operation. In this study, a systematic analysis of the energy efficiency (overall electrical energy needed per kg of recovered VOC) of a standalone condensation process is compared to a hybrid process based on membrane concentration + condensation. It is shown that the standalone condensation remains more energy efficient for high boiling VOC (e.g. toluene, octane, acetone), while a significant improvement of the energy efficiency is obtained with the hybrid process for intermediate to low boiling temperature VOC (e.g. propane, ethane, ethylene…). A generic map of the most energy efficient VOC recovery process as a function of the VOC boiling temperature is finally proposed and potential improvement of the hybrid approach, based on a retentate recycling strategy is discussed.

Suggested Citation

  • Belaissaoui, Bouchra & Le Moullec, Yann & Favre, Eric, 2016. "Energy efficiency of a hybrid membrane/condensation process for VOC (Volatile Organic Compounds) recovery from air: A generic approach," Energy, Elsevier, vol. 95(C), pages 291-302.
    • Handle: RePEc:eee:energy:v:95:y:2016:i:c:p:291-302
    DOI: 10.1016/j.energy.2015.12.006
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    References listed on IDEAS

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    1. Ghoreyshi, Ali Asghar & Sadeghifar, Hamidreza & Entezarion, Fereshteh, 2014. "Efficiency assessment of air stripping packed towers for removal of VOCs (volatile organic compounds) from industrial and drinking waters," Energy, Elsevier, vol. 73(C), pages 838-843.
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    1. Yuan Wang & Bin Zhou & Mengrong Yang & Gao Xiao & Hang Xiao & Xiaorong Dai, 2023. "Bibliometrics and Knowledge Map Analysis of Research Progress on Biological Treatments for Volatile Organic Compounds," Sustainability, MDPI, vol. 15(12), pages 1-17, June.
    2. Grisales Díaz, Victor Hugo & Willis, Mark J. & von Stosch, Moritz & Olivar Tost, Gerard & Prado-Rubio, Oscar, 2020. "Assessing the energy requirements for butanol production using fermentation tanks-in-series operated under vacuum," Renewable Energy, Elsevier, vol. 160(C), pages 1253-1264.
    3. Xu, Hao & Xu, Xiafan & Chen, Liubiao & Guo, Jia & Wang, Junjie, 2022. "A novel cryogenic condensation system combined with gas turbine with low carbon emission for volatile compounds recovery," Energy, Elsevier, vol. 248(C).
    4. Juexiu Li & Hongbo Zhang & Diwen Ying & Yalin Wang & Tonghua Sun & Jinping Jia, 2019. "In Plasma Catalytic Oxidation of Toluene Using Monolith CuO Foam as a Catalyst in a Wedged High Voltage Electrode Dielectric Barrier Discharge Reactor: Influence of Reaction Parameters and Byproduct C," IJERPH, MDPI, vol. 16(5), pages 1-14, February.

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