IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v93y2015ip2p1523-1534.html
   My bibliography  Save this article

Theoretical and experimental investigation of a closed sorption thermal storage prototype using LiCl/water

Author

Listed:
  • Yu, N.
  • Wang, R.Z.
  • Wang, L.W.

Abstract

A 1 kWh lab-scale sorption prototype using LiCl-water was theoretically and experimentally investigated for sorption thermal energy storage. A type of consolidated composite matrix is developed for the system by using AC (activated carbon), LiCl, expanded natural graphite treated with sulphuric acid (ENG-TSA) to increase heat transfer and SS (silica solution) to enhance mechanical strength. Thermal conductivity and permeability were measured first. A two-dimensional model considering the combined heat and mass transfer was developed to predict the sorption kinetics of the reactor. Under the operation condition of a charging temperature of 85 °C and a discharging temperature of 40 °C, the experimentally recovered heat is 2517 kJ, resulting a heat storage efficiency of 93%. The heat storage density is 874 kJ/kg consolidated sorbent or 2622 kJ/kg LiCl. The experimental results of the prototype were compared with the simulated results. The established two-dimensional model proves to be effective since the general evolution trends of experimental and simulated outlet fluid temperatures are in good agreement. An average gap of about 0.4 °C between the experimental and simulated outlet temperature may be caused by the heat loss and the constant pressure assumption.

Suggested Citation

  • Yu, N. & Wang, R.Z. & Wang, L.W., 2015. "Theoretical and experimental investigation of a closed sorption thermal storage prototype using LiCl/water," Energy, Elsevier, vol. 93(P2), pages 1523-1534.
  • Handle: RePEc:eee:energy:v:93:y:2015:i:p2:p:1523-1534
    DOI: 10.1016/j.energy.2015.10.001
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544215013560
    Download Restriction: Full text for ScienceDirect subscribers only

    File URL: https://libkey.io/10.1016/j.energy.2015.10.001?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Zhang, L.Z. & Wang, L., 1999. "Momentum and heat transfer in the adsorbent of a waste-heat adsorption cooling system," Energy, Elsevier, vol. 24(7), pages 605-624.
    2. Michel, Benoit & Mazet, Nathalie & Neveu, Pierre, 2014. "Experimental investigation of an innovative thermochemical process operating with a hydrate salt and moist air for thermal storage of solar energy: Global performance," Applied Energy, Elsevier, vol. 129(C), pages 177-186.
    3. Zondag, Herbert & Kikkert, Benjamin & Smeding, Simon & Boer, Robert de & Bakker, Marco, 2013. "Prototype thermochemical heat storage with open reactor system," Applied Energy, Elsevier, vol. 109(C), pages 360-365.
    4. Cot-Gores, Jaume & Castell, Albert & Cabeza, Luisa F., 2012. "Thermochemical energy storage and conversion: A-state-of-the-art review of the experimental research under practical conditions," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(7), pages 5207-5224.
    5. N’Tsoukpoe, K. Edem & Le Pierrès, Nolwenn & Luo, Lingai, 2012. "Numerical dynamic simulation and analysis of a lithium bromide/water long-term solar heat storage system," Energy, Elsevier, vol. 37(1), pages 346-358.
    6. Yu, N. & Wang, R.Z. & Lu, Z.S. & Wang, L.W. & Ishugah, T.F., 2014. "Evaluation of a three-phase sorption cycle for thermal energy storage," Energy, Elsevier, vol. 67(C), pages 468-478.
    7. Michel, Benoit & Mazet, Nathalie & Mauran, Sylvain & Stitou, Driss & Xu, Jing, 2012. "Thermochemical process for seasonal storage of solar energy: Characterization and modeling of a high density reactive bed," Energy, Elsevier, vol. 47(1), pages 553-563.
    8. N'Tsoukpoe, K.E. & Le Pierrès, N. & Luo, L., 2013. "Experimentation of a LiBr–H2O absorption process for long-term solar thermal storage: Prototype design and first results," Energy, Elsevier, vol. 53(C), pages 179-198.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Min, Haye & Choi, Hyung Won & Jeong, Jaehui & Jeong, Jinhee & Kim, Young & Kang, Yong Tae, 2023. "Daily sorption thermal battery cycle for building applications," Energy, Elsevier, vol. 282(C).
    2. Palacios, Anabel & Cong, Lin & Navarro, M.E. & Ding, Yulong & Barreneche, Camila, 2019. "Thermal conductivity measurement techniques for characterizing thermal energy storage materials – A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 108(C), pages 32-52.
    3. Luo, Xinyi & Li, Wei & Zhang, Lianjie & Zeng, Min & Klemeš, Jirí Jaromír & Wang, Qiuwang, 2023. "Effects evaluation of Fin layouts and configurations on discharging performance of double-pipe thermochemical energy storage reactor," Energy, Elsevier, vol. 282(C).
    4. Marín, P.E. & Milian, Y. & Ushak, S. & Cabeza, L.F. & Grágeda, M. & Shire, G.S.F., 2021. "Lithium compounds for thermochemical energy storage: A state-of-the-art review and future trends," Renewable and Sustainable Energy Reviews, Elsevier, vol. 149(C).
    5. Nagel, Thomas & Beckert, Steffen & Lehmann, Christoph & Gläser, Roger & Kolditz, Olaf, 2016. "Multi-physical continuum models of thermochemical heat storage and transformation in porous media and powder beds—A review," Applied Energy, Elsevier, vol. 178(C), pages 323-345.
    6. Li, Shuangjun & Deng, Shuai & Zhao, Li & Zhao, Ruikai & Lin, Meng & Du, Yanping & Lian, Yahui, 2018. "Mathematical modeling and numerical investigation of carbon capture by adsorption: Literature review and case study," Applied Energy, Elsevier, vol. 221(C), pages 437-449.
    7. Gao, J.T. & Xu, Z.Y. & Wang, R.Z., 2020. "Experimental study on a double-stage absorption solar thermal storage system with enhanced energy storage density," Applied Energy, Elsevier, vol. 262(C).
    8. Mikos-Nuszkiewicz, Natalia & Furmański, Piotr & Łapka, Piotr, 2023. "A mathematical model of charging and discharging processes in a thermochemical energy storage reactor using the hydrated potassium carbonate as a thermochemical material," Energy, Elsevier, vol. 263(PA).
    9. Xu, Z.Y. & Wang, R.Z., 2017. "A sorption thermal storage system with large concentration glide," Energy, Elsevier, vol. 141(C), pages 380-388.
    10. Xu, Z.Y. & Wang, R.Z., 2019. "Absorption seasonal thermal storage cycle with high energy storage density through multi-stage output," Energy, Elsevier, vol. 167(C), pages 1086-1096.
    11. Hasila Jarimi & Devrim Aydin & Zhang Yanan & Gorkem Ozankaya & Xiangjie Chen & Saffa Riffat, 2019. "Review on the recent progress of thermochemical materials and processes for solar thermal energy storage and industrial waste heat recovery," International Journal of Low-Carbon Technologies, Oxford University Press, vol. 14(1), pages 44-69.
    12. Jiang, L. & Liu, W. & Lin, Y.C. & Wang, R.Q. & Zhang, X.J. & Hu, M.K., 2022. "Hybrid thermochemical sorption seasonal storage for ultra-low temperature solar energy utilization," Energy, Elsevier, vol. 239(PB).
    13. Yannan Zhang & Ruzhu Wang & Tingxian Li & Yanjie Zhao, 2016. "Thermochemical Characterizations of Novel Vermiculite-LiCl Composite Sorbents for Low-Temperature Heat Storage," Energies, MDPI, vol. 9(10), pages 1-15, October.
    14. Zhao, Y.J. & Wang, R.Z. & Li, T.X. & Nomura, Y., 2016. "Investigation of a 10 kWh sorption heat storage device for effective utilization of low-grade thermal energy," Energy, Elsevier, vol. 113(C), pages 739-747.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. N’Tsoukpoe, Kokouvi Edem & Kuznik, Frédéric, 2021. "A reality check on long-term thermochemical heat storage for household applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 139(C).
    2. Scapino, Luca & Zondag, Herbert A. & Van Bael, Johan & Diriken, Jan & Rindt, Camilo C.M., 2017. "Sorption heat storage for long-term low-temperature applications: A review on the advancements at material and prototype scale," Applied Energy, Elsevier, vol. 190(C), pages 920-948.
    3. Marias, Foivos & Neveu, Pierre & Tanguy, Gwennyn & Papillon, Philippe, 2014. "Thermodynamic analysis and experimental study of solid/gas reactor operating in open mode," Energy, Elsevier, vol. 66(C), pages 757-765.
    4. Fopah Lele, Armand & Kuznik, Frédéric & Rammelberg, Holger U. & Schmidt, Thomas & Ruck, Wolfgang K.L., 2015. "Thermal decomposition kinetic of salt hydrates for heat storage systems," Applied Energy, Elsevier, vol. 154(C), pages 447-458.
    5. Fumey, B. & Weber, R. & Baldini, L., 2019. "Sorption based long-term thermal energy storage – Process classification and analysis of performance limitations: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 111(C), pages 57-74.
    6. Xu, J.X. & Li, T.X. & Chao, J.W. & Yan, T.S. & Wang, R.Z., 2019. "High energy-density multi-form thermochemical energy storage based on multi-step sorption processes," Energy, Elsevier, vol. 185(C), pages 1131-1142.
    7. Ndiaye, Khadim & Ginestet, Stéphane & Cyr, Martin, 2018. "Experimental evaluation of two low temperature energy storage prototypes based on innovative cementitious material," Applied Energy, Elsevier, vol. 217(C), pages 47-55.
    8. N’Tsoukpoe, Kokouvi Edem & Osterland, Thomas & Opel, Oliver & Ruck, Wolfgang K.L., 2016. "Cascade thermochemical storage with internal condensation heat recovery for better energy and exergy efficiencies," Applied Energy, Elsevier, vol. 181(C), pages 562-574.
    9. Isye Hayatina & Amar Auckaili & Mohammed Farid, 2023. "Review on Salt Hydrate Thermochemical Heat Transformer," Energies, MDPI, vol. 16(12), pages 1-23, June.
    10. Ding, Zhixiong & Wu, Wei & Leung, Michael, 2021. "Advanced/hybrid thermal energy storage technology: material, cycle, system and perspective," Renewable and Sustainable Energy Reviews, Elsevier, vol. 145(C).
    11. Zhao, Y.J. & Wang, R.Z. & Li, T.X. & Nomura, Y., 2016. "Investigation of a 10 kWh sorption heat storage device for effective utilization of low-grade thermal energy," Energy, Elsevier, vol. 113(C), pages 739-747.
    12. Ding, Zhixiong & Wu, Wei & Chen, Youming & Leung, Michael, 2020. "Dynamic characteristics and performance improvement of a high-efficiency double-effectthermal battery for cooling and heating," Applied Energy, Elsevier, vol. 264(C).
    13. Li, Wei & Klemeš, Jiří Jaromír & Wang, Qiuwang & Zeng, Min, 2022. "Salt hydrate–based gas-solid thermochemical energy storage: Current progress, challenges, and perspectives," Renewable and Sustainable Energy Reviews, Elsevier, vol. 154(C).
    14. Kuznik, Frédéric & Johannes, Kevyn & Obrecht, Christian & David, Damien, 2018. "A review on recent developments in physisorption thermal energy storage for building applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 94(C), pages 576-586.
    15. Aydin, Devrim & Casey, Sean P. & Riffat, Saffa, 2015. "The latest advancements on thermochemical heat storage systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 41(C), pages 356-367.
    16. Yu, N. & Wang, R.Z. & Lu, Z.S. & Wang, L.W. & Ishugah, T.F., 2014. "Evaluation of a three-phase sorption cycle for thermal energy storage," Energy, Elsevier, vol. 67(C), pages 468-478.
    17. Fopah-Lele, Armand & Rohde, Christian & Neumann, Karsten & Tietjen, Theo & Rönnebeck, Thomas & N'Tsoukpoe, Kokouvi Edem & Osterland, Thomas & Opel, Oliver & Ruck, Wolfgang K.L., 2016. "Lab-scale experiment of a closed thermochemical heat storage system including honeycomb heat exchanger," Energy, Elsevier, vol. 114(C), pages 225-238.
    18. Lizana, Jesús & Chacartegui, Ricardo & Barrios-Padura, Angela & Valverde, José Manuel, 2017. "Advances in thermal energy storage materials and their applications towards zero energy buildings: A critical review," Applied Energy, Elsevier, vol. 203(C), pages 219-239.
    19. N’Tsoukpoe, Kokouvi Edem & Schmidt, Thomas & Rammelberg, Holger Urs & Watts, Beatriz Amanda & Ruck, Wolfgang K.L., 2014. "A systematic multi-step screening of numerous salt hydrates for low temperature thermochemical energy storage," Applied Energy, Elsevier, vol. 124(C), pages 1-16.
    20. Mukherjee, Ankit & Pujari, Ankush Shankar & Shinde, Shraddha Nitin & Kashyap, Uddip & Kumar, Lalit & Subramaniam, Chandramouli & Saha, Sandip K., 2022. "Performance assessment of open thermochemical energy storage system for seasonal space heating in highly humid environment," Renewable Energy, Elsevier, vol. 201(P1), pages 204-223.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:93:y:2015:i:p2:p:1523-1534. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.