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Theoretical and experimental investigation of a closed sorption thermal storage prototype using LiCl/water

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  • Yu, N.
  • Wang, R.Z.
  • Wang, L.W.

Abstract

A 1 kWh lab-scale sorption prototype using LiCl-water was theoretically and experimentally investigated for sorption thermal energy storage. A type of consolidated composite matrix is developed for the system by using AC (activated carbon), LiCl, expanded natural graphite treated with sulphuric acid (ENG-TSA) to increase heat transfer and SS (silica solution) to enhance mechanical strength. Thermal conductivity and permeability were measured first. A two-dimensional model considering the combined heat and mass transfer was developed to predict the sorption kinetics of the reactor. Under the operation condition of a charging temperature of 85 °C and a discharging temperature of 40 °C, the experimentally recovered heat is 2517 kJ, resulting a heat storage efficiency of 93%. The heat storage density is 874 kJ/kg consolidated sorbent or 2622 kJ/kg LiCl. The experimental results of the prototype were compared with the simulated results. The established two-dimensional model proves to be effective since the general evolution trends of experimental and simulated outlet fluid temperatures are in good agreement. An average gap of about 0.4 °C between the experimental and simulated outlet temperature may be caused by the heat loss and the constant pressure assumption.

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  • Yu, N. & Wang, R.Z. & Wang, L.W., 2015. "Theoretical and experimental investigation of a closed sorption thermal storage prototype using LiCl/water," Energy, Elsevier, vol. 93(P2), pages 1523-1534.
    • Handle: RePEc:eee:energy:v:93:y:2015:i:p2:p:1523-1534
    DOI: 10.1016/j.energy.2015.10.001
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