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A new reaction model for low temperature oxidation of heavy oil: Experiments and numerical modeling

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  • Khansari, Zeinab
  • Kapadia, Punitkumar
  • Mahinpey, Nader
  • Gates, Ian D.

Abstract

ISC (in situ combustion) based enhanced heavy oil recovery is complex because there are numerous chemical reactions taking place simultaneously. The complexity arises due to the immense number of components reacting through many different reaction paths where the geology and oil saturation vary spatially within the reservoir. It is known that there are four major classes of reactions taking place within ISC: LTO (low temperature oxidation), HTO (high temperature oxidation), TC (thermal cracking), and aquathermolysis. Within the reservoir, during ISC, LTO and TC reactions play a major role by providing fuel for HTO. In many reaction schemes in the literature, the LTO interval is considered as a single reactive zone spanning a single temperature range. In this work, a new reaction scheme is proposed based on analysis of previously published thermogravimetric data where the LTO reaction temperature range is separated into four temperature subranges each with its own dominant reaction products. The new reaction model was implemented in a numerical model that revealed that it was able to represent the four LTO temperature subranges. In comparison, a numerical model using a previously published LTO reaction model with a single temperature range was not able to represent the behavior of LTO.

Suggested Citation

  • Khansari, Zeinab & Kapadia, Punitkumar & Mahinpey, Nader & Gates, Ian D., 2014. "A new reaction model for low temperature oxidation of heavy oil: Experiments and numerical modeling," Energy, Elsevier, vol. 64(C), pages 419-428.
    • Handle: RePEc:eee:energy:v:64:y:2014:i:c:p:419-428
    DOI: 10.1016/j.energy.2013.11.024
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    References listed on IDEAS

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    1. Versan KOK, Mustafa, 2011. "Thermo-oxidative characterization and kinetics of tar sands," Energy, Elsevier, vol. 36(8), pages 5338-5342.
    2. Murugan, Pulikesi & Mahinpey, Nader & Mani, Thilakavathi & Asghari, Koorosh, 2010. "Effect of low-temperature oxidation on the pyrolysis and combustion of whole oil," Energy, Elsevier, vol. 35(5), pages 2317-2322.
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    Cited by:

    1. Lina Zhang & Dianfa Du & Yaozu Zhang & Xin Liu & Jingang Fu & Yuan Li & Jianhua Ren, 2022. "Steam Cavity Expansion Model for Steam Flooding in Deep Heavy Oil Reservoirs," Energies, MDPI, vol. 15(13), pages 1-15, June.
    2. Sun, Fengrui & Yao, Yuedong & Chen, Mingqiang & Li, Xiangfang & Zhao, Lin & Meng, Ye & Sun, Zheng & Zhang, Tao & Feng, Dong, 2017. "Performance analysis of superheated steam injection for heavy oil recovery and modeling of wellbore heat efficiency," Energy, Elsevier, vol. 125(C), pages 795-804.
    3. Ling, Zhongqian & Zhou, Hao & Ren, Tao, 2015. "Effect of the flue gas recirculation supply location on the heavy oil combustion and NOx emission characteristics within a pilot furnace fired by a swirl burner," Energy, Elsevier, vol. 91(C), pages 110-116.
    4. Xu, Shaotao & Lü, Xiaoshu & Sun, Youhong & Guo, Wei & Li, Qiang & Liu, Lang & Kang, Shijie & Deng, Sunhua, 2023. "Optimization of temperature parameters for the autothermic pyrolysis in-situ conversion process of oil shale," Energy, Elsevier, vol. 264(C).
    5. Zhang, Fengming & Xu, Chunyan & Zhang, Yong & Chen, Shouyan & Chen, Guifang & Ma, Chunyuan, 2014. "Experimental study on the operating characteristics of an inner preheating transpiring wall reactor for supercritical water oxidation: Temperature profiles and product properties," Energy, Elsevier, vol. 66(C), pages 577-587.
    6. Yang, Junyu & Xu, Qianghui & Jiang, Hang & Shi, Lin, 2021. "Reaction model of low asphaltene heavy oil from ramped temperature oxidation experimental analyses and numerical simulations," Energy, Elsevier, vol. 219(C).
    7. Chen, Hao & Liu, Xiliang & Jia, Ninghong & Tian, Xiaofeng & Duncan, Ian & Yang, Ran & Yang, Shenglai, 2020. "The impact of the oil character and quartz sands on the thermal behavior and kinetics of crude oil," Energy, Elsevier, vol. 210(C).
    8. Wang, Dechao & Jin, Lijun & Li, Yang & Yao, Demeng & Wang, Jiaofei & Hu, Haoquan, 2018. "Upgrading of vacuum residue with chemical looping partial oxidation over Ce doped Fe2O3," Energy, Elsevier, vol. 162(C), pages 542-553.
    9. Gu, Hao & Cheng, Linsong & Huang, Shijun & Du, Baojian & Hu, Changhao, 2014. "Prediction of thermophysical properties of saturated steam and wellbore heat losses in concentric dual-tubing steam injection wells," Energy, Elsevier, vol. 75(C), pages 419-429.
    10. Zhao, Shuai & Pu, Wanfen & Peng, Xiaoqiang & Zhang, Jizhou & Ren, Hao, 2021. "Low-temperature oxidation of heavy crude oil characterized by TG, DSC, GC-MS, and negative ion ESI FT-ICR MS," Energy, Elsevier, vol. 214(C).
    11. Sun, Fengrui & Li, Chunlan & Cheng, Linsong & Huang, Shijun & Zou, Ming & Sun, Qun & Wu, Xiaojun, 2017. "Production performance analysis of heavy oil recovery by cyclic superheated steam stimulation," Energy, Elsevier, vol. 121(C), pages 356-371.
    12. Zhao, Shuai & Pu, Wanfen & Jiang, Qi & Yuan, Chengdong & Varfolomeev, Mikhail A. & Sudakov, Vladislav, 2023. "Investigation into the key factors influencing the establishment and propagation of combustion front in ultra-deep high-temperature heavy oil reservoirs," Energy, Elsevier, vol. 283(C).

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