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Assessment of boundary lubrication in biodiesels by nanotribological tests

Author

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  • Maru, Marcia M.
  • Almeida, Clara M.
  • Silva, Rui F.
  • Achete, Carlos A.

Abstract

Nanoscale measurements using atomic force microscopy are performed in order to scrutinize the friction phenomena observed in microscale ball-on-disc tribological tests under (boundary lubrication) BL regime. Two reference biodiesels, one derived from a vegetable source (soybean) and the other from animal fat, are compared. A linear dependence of the friction coefficient (μ) with the Stribeck parameter (S = viscosity × velocity/load) is observed: μ = 0.11 − 26.54 × S for the animal fat and μ = 0.12 − 51.56 × S for the soybean biodiesel. The nanotribological tests allowed highlighting the cohesion component of friction force in the BL regime that is associated to the intrinsic characteristics of the biodiesels, the respective friction coefficients being μ = 0.0206 for the animal fat and μ = 0.0233 for the soybean biodiesel. The better lubricity of the animal fat biodiesel compared to the soybean observed in microscale is attributed to the presence of sulfur and to the higher amount of mono- and di-glycerides contaminants in it. The polarity and/or chemical affinity of the respective sulfur and OH groups facilitate them to reacting with the steel surfaces during the rubbing action. At nanoscale level, the same ranking in friction is observed among the biodiesels, being that here the friction phenomena are attributed to the cohesive forces other than those related to viscosity.

Suggested Citation

  • Maru, Marcia M. & Almeida, Clara M. & Silva, Rui F. & Achete, Carlos A., 2013. "Assessment of boundary lubrication in biodiesels by nanotribological tests," Energy, Elsevier, vol. 55(C), pages 273-277.
    • Handle: RePEc:eee:energy:v:55:y:2013:i:c:p:273-277
    DOI: 10.1016/j.energy.2013.03.036
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    References listed on IDEAS

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    1. Maru, Marcia M. & Trommer, Rafael M. & Cavalcanti, Kátia F. & Figueiredo, Elizabeth S. & Silva, Rui F. & Achete, Carlos A., 2014. "The Stribeck curve as a suitable characterization method of the lubricity of biodiesel and diesel blends," Energy, Elsevier, vol. 69(C), pages 673-681.
    2. Xu, Chengyuan & Yan, Xiaopeng & Kang, Yili & You, Lijun & You, Zhenjiang & Zhang, Hao & Zhang, Jingyi, 2019. "Friction coefficient: A significant parameter for lost circulation control and material selection in naturally fractured reservoir," Energy, Elsevier, vol. 174(C), pages 1012-1025.

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