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Energy saving methods for the separation of a minimum boiling point azeotrope using an intermediate entrainer

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  • Modla, G.

Abstract

In this work two energy saving methods are presented for the separation of a minimum boiling point azeotrope by using an intermediate entrainer. Extractive distillation column configurations with conventional, thermally integrated and dividing-wall columns are used for comparison. These configurations are designed, rigorously simulated and optimized to minimize the Total Annual Cost and to reduce the energy requirement. A novel simple method is proposed based on a Genetic Algorithm to determine the main design and operation parameters of the dividing-wall column. The optimization algorithm is written in Excel Macro interconnected with the ChemCad process flow-sheet simulator. In terms of total annual costs, the extractive dividing-wall column was found to be the most economical scheme, followed by the thermally integrated and conventional extractive distillation methods.

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  • Modla, G., 2013. "Energy saving methods for the separation of a minimum boiling point azeotrope using an intermediate entrainer," Energy, Elsevier, vol. 50(C), pages 103-109.
    • Handle: RePEc:eee:energy:v:50:y:2013:i:c:p:103-109
    DOI: 10.1016/j.energy.2012.12.011
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    2. Yitao Wu & Meiqi Tang & Zeju Wang & Le Shi & Zhangyi Xiong & Zhijie Chen & Jonathan L. Sessler & Feihe Huang, 2023. "Pillararene incorporated metal–organic frameworks for supramolecular recognition and selective separation," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    3. Shahandeh, H. & Ivakpour, J. & Kasiri, N., 2014. "Internal and external HIDiCs (heat-integrated distillation columns) optimization by genetic algorithm," Energy, Elsevier, vol. 64(C), pages 875-886.
    4. Modla, G. & Lang, P., 2013. "Heat pump systems with mechanical compression for batch distillation," Energy, Elsevier, vol. 62(C), pages 403-417.
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    6. Jingyu Chen & Wenjie Zhang & Wenzhi Yang & Fengcheng Xi & Hongyi He & Minghao Liang & Qian Dong & Jiawang Hou & Mengbin Wang & Guocan Yu & Jiong Zhou, 2024. "Separation of benzene and toluene associated with vapochromic behaviors by hybrid[4]arene-based co-crystals," Nature Communications, Nature, vol. 15(1), pages 1-13, December.

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