IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v36y2011i3p1582-1589.html
   My bibliography  Save this article

Synthesis of Mo/TNU-9 (TNU-9 Taejon National University No. 9) catalyst and its catalytic performance in methane non-oxidative aromatization

Author

Listed:
  • Liu, Heng
  • Yang, Shuang
  • Wu, Shujie
  • Shang, Fanpeng
  • Yu, Xiaofang
  • Xu, Chen
  • Guan, Jingqi
  • Kan, Qiubin

Abstract

Mo-modified catalysts of Mo/TNU-9 were prepared for the non-oxidative aromatization of methane. The effects of different Si/Al ratios, Mo loadings and temperatures on the catalytic performance of Mo/TNU-9 catalysts were also investigated. Furthermore, for comparison, Mo/ZSM-5 was synthesized for the same reaction. The physical properties and acidities of the samples were characterized by XRD (X-ray diffraction), SEM (scanning electron microscopy), BET (Brunauer–Emmett–Teller method) and IR (infrared) spectroscopy. The best conditions for methane aromatization with Mo/TNU-9 are as follows: Si/Al ratio = 50, 6 wt.% MoO3 loading, and reaction temperature = 973 K. Compared with Mo/ZSM-5, the Mo/TNU-9 catalyst showed both a higher conversion of methane and higher selectivity to benzene. In addition, the stability of Mo/TNU-9 was also better than that of Mo/ZSM-5. The superior catalytic behavior of Mo/TNU-9 may be attributed to its unique three-dimensional 10-member-ring channel structure with the presence of large 12-member-ring cavities.

Suggested Citation

  • Liu, Heng & Yang, Shuang & Wu, Shujie & Shang, Fanpeng & Yu, Xiaofang & Xu, Chen & Guan, Jingqi & Kan, Qiubin, 2011. "Synthesis of Mo/TNU-9 (TNU-9 Taejon National University No. 9) catalyst and its catalytic performance in methane non-oxidative aromatization," Energy, Elsevier, vol. 36(3), pages 1582-1589.
    • Handle: RePEc:eee:energy:v:36:y:2011:i:3:p:1582-1589
    DOI: 10.1016/j.energy.2010.12.073
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544210007796
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2010.12.073?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Szargut, Jan & Szczygiel, Ireneusz, 2009. "Utilization of the cryogenic exergy of liquid natural gas (LNG) for the production of electricity," Energy, Elsevier, vol. 34(7), pages 827-837.
    2. Han, Wei & Jin, Hongguang & Xu, Wei, 2007. "A novel combined cycle with synthetic utilization of coal and natural gas," Energy, Elsevier, vol. 32(8), pages 1334-1342.
    3. Fabian Gramm & Christian Baerlocher & Lynne B. McCusker & Stewart J. Warrender & Paul A. Wright & Bada Han & Suk Bong Hong & Zheng Liu & Tetsu Ohsuna & Osamu Terasaki, 2006. "Complex zeolite structure solved by combining powder diffraction and electron microscopy," Nature, Nature, vol. 444(7115), pages 79-81, November.
    4. Indarto, Antonius & Choi, Jae-Wook & Lee, Hwaung & Song, Hyung Keun, 2006. "Effect of additive gases on methane conversion using gliding arc discharge," Energy, Elsevier, vol. 31(14), pages 2986-2995.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Huang, Z.F. & Wan, Y.D. & Soh, K.Y. & Islam, M.R. & Chua, K.J., 2022. "Off-design and flexibility analyses of combined cooling and power based liquified natural gas (LNG) cold energy utilization system under fluctuating regasification rates," Applied Energy, Elsevier, vol. 310(C).
    2. Szczygiel, Ireneusz & Bulinski, Zbigniew, 2018. "Overview of the liquid natural gas (LNG) regasification technologies with the special focus on the Prof. Szargut's impact," Energy, Elsevier, vol. 165(PB), pages 999-1008.
    3. Wang, Jiangfeng & Yan, Zhequan & Wang, Man & Dai, Yiping, 2013. "Thermodynamic analysis and optimization of an ammonia-water power system with LNG (liquefied natural gas) as its heat sink," Energy, Elsevier, vol. 50(C), pages 513-522.
    4. Chung, Wei-Chieh & Chang, Moo-Been, 2016. "Review of catalysis and plasma performance on dry reforming of CH4 and possible synergistic effects," Renewable and Sustainable Energy Reviews, Elsevier, vol. 62(C), pages 13-31.
    5. Yoonho, Lee, 2019. "LNG-FSRU cold energy recovery regasification using a zeotropic mixture of ethane and propane," Energy, Elsevier, vol. 173(C), pages 857-869.
    6. Choi, In-Hwan & Lee, Sangick & Seo, Yutaek & Chang, Daejun, 2013. "Analysis and optimization of cascade Rankine cycle for liquefied natural gas cold energy recovery," Energy, Elsevier, vol. 61(C), pages 179-195.
    7. Joy, Jubil & Kochunni, Sarun Kumar & Chowdhury, Kanchan, 2022. "Size reduction and enhanced power generation in ORC by vaporizing LNG at high supercritical pressure irrespective of delivery pressure," Energy, Elsevier, vol. 260(C).
    8. Kumar, Satish & Kwon, Hyouk-Tae & Choi, Kwang-Ho & Lim, Wonsub & Cho, Jae Hyun & Tak, Kyungjae & Moon, Il, 2011. "LNG: An eco-friendly cryogenic fuel for sustainable development," Applied Energy, Elsevier, vol. 88(12), pages 4264-4273.
    9. Park, Chansaem & Song, Kiwook & Lee, Sangho & Lim, Youngsub & Han, Chonghun, 2012. "Retrofit design of a boil-off gas handling process in liquefied natural gas receiving terminals," Energy, Elsevier, vol. 44(1), pages 69-78.
    10. Rafiq, M.H. & Hustad, J.E., 2011. "Experimental and thermodynamic studies of the catalytic partial oxidation of model biogas using a plasma-assisted gliding arc reactor," Renewable Energy, Elsevier, vol. 36(11), pages 2878-2887.
    11. Lee, Ung & Kim, Kyeongsu & Han, Chonghun, 2014. "Design and optimization of multi-component organic rankine cycle using liquefied natural gas cryogenic exergy," Energy, Elsevier, vol. 77(C), pages 520-532.
    12. Ahmad, Abdalqader & Al-Dadah, Raya & Mahmoud, Saad, 2016. "Air conditioning and power generation for residential applications using liquid nitrogen," Applied Energy, Elsevier, vol. 184(C), pages 630-640.
    13. Ouyang, Tiancheng & Xu, Jisong & Qin, Peijia & Cheng, Liang, 2022. "Utilizing flue gas low-grade waste heat and furnace excess heat to produce syngas and sulfuric acid recovery in coal-fired power plant," Energy, Elsevier, vol. 258(C).
    14. Sun, Heng & Zhu, Hongmei & Liu, Feng & Ding, He, 2014. "Simulation and optimization of a novel Rankine power cycle for recovering cold energy from liquefied natural gas using a mixed working fluid," Energy, Elsevier, vol. 70(C), pages 317-324.
    15. Lee, Inkyu & Park, Jinwoo & You, Fengqi & Moon, Il, 2019. "A novel cryogenic energy storage system with LNG direct expansion regasification: Design, energy optimization, and exergy analysis," Energy, Elsevier, vol. 173(C), pages 691-705.
    16. Abdo, Rodrigo F. & Pedro, Hugo T.C. & Koury, Ricardo N.N. & Machado, Luiz & Coimbra, Carlos F.M. & Porto, Matheus P., 2015. "Performance evaluation of various cryogenic energy storage systems," Energy, Elsevier, vol. 90(P1), pages 1024-1032.
    17. Rahmati, Hamed & Ghorbanzadeh, Atamalek, 2021. "Parallel electrodes gliding plasma: Working principles and application in dry reforming of methane," Energy, Elsevier, vol. 230(C).
    18. Khan, Mohd Shariq & I.A. Karimi, & Bahadori, Alireza & Lee, Moonyong, 2015. "Sequential coordinate random search for optimal operation of LNG (liquefied natural gas) plant," Energy, Elsevier, vol. 89(C), pages 757-767.
    19. Tomasz Banaszkiewicz & Maciej Chorowski & Wojciech Gizicki & Artur Jedrusyna & Jakub Kielar & Ziemowit Malecha & Agnieszka Piotrowska & Jaroslaw Polinski & Zbigniew Rogala & Korneliusz Sierpowski & Ja, 2020. "Liquefied Natural Gas in Mobile Applications—Opportunities and Challenges," Energies, MDPI, vol. 13(21), pages 1-35, October.
    20. Gao, Yuan & Zhang, Shuai & Sun, Hao & Wang, Ruixue & Tu, Xin & Shao, Tao, 2018. "Highly efficient conversion of methane using microsecond and nanosecond pulsed spark discharges," Applied Energy, Elsevier, vol. 226(C), pages 534-545.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:36:y:2011:i:3:p:1582-1589. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.