IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v267y2023ics0360544222034417.html
   My bibliography  Save this article

Effect analysis on hydrocarbon adsorption enhancement of ZSM-5 zeolite modified by transition metal ions in cold start of gasoline engine

Author

Listed:
  • Feng, Changling
  • Deng, Yuanwang
  • E, Jiaqiang
  • Han, Dandan
  • Tan, Yan

Abstract

The adsorption effects of transition metal modified ZSM-5 zeolite on the main hydrocarbon emission components of gasoline engine cold start include acetylene (C2H2), ethylene (C2H4), acetaldehyde (C2H4O), propylene (C3H6), 1-butene (C4H8) and benzene (C6H6) carbon monoxide (CO), carbon dioxide (CO2) and water vapor (H2O) were studied by experiments and molecular simulation. Through the hydrocarbon adsorption breakthrough experiment, the promotion effect of Fe-ZSM-5 zeolite on the adsorption of hydrocarbon emissions from cold start was confirmed. Results showed that the Fe modification improved the adsorption rate of zeolite on C4H8 and C2H4O. With the increase of Fe mass fraction, the adsorption capacity of zeolite for C2H4O increased, while the adsorption capacity for C4H8 decreased. The adsorption mechanisms of 9 main exhaust components from cold start on M2+ (M = Fe, Cu and Zn) modified ZSM-5 zeolite were studied by molecular simulation. Under the cold start condition, the adsorption capacity of H2O is the largest, between 1.5 and 4 mmol/gzeo, one order of magnitude higher than that of CO2 (0–0.3 mmol/gzeo), C6H6 (0–0.16 mmol/gzeo), C2H4O (0–0.5 mmol/gzeo) and C4H8 (0–1.6 mmol/gzeo), and 3–4 orders of magnitude higher than that of CO, C2H2, C2H4, C3H6. Results showed that the adsorption priority of molecules on transition metal ion modified ZSM-5 zeolite was determined by functional group charge number, molecular weight and molecular polarity. The zeolite with higher ion exchange ratio has a larger adsorption capacity for oxygen-containing molecules such as H2O, CO2 and C2H4O. Reducing the ion exchange ratio was conducive to the adsorption of hydrocarbons such as C4H8.

Suggested Citation

  • Feng, Changling & Deng, Yuanwang & E, Jiaqiang & Han, Dandan & Tan, Yan, 2023. "Effect analysis on hydrocarbon adsorption enhancement of ZSM-5 zeolite modified by transition metal ions in cold start of gasoline engine," Energy, Elsevier, vol. 267(C).
    • Handle: RePEc:eee:energy:v:267:y:2023:i:c:s0360544222034417
    DOI: 10.1016/j.energy.2022.126554
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544222034417
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2022.126554?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Wu, Tian & Shen, Qu & Xu, Ming & Peng, Tianduo & Ou, Xunmin, 2018. "Development and application of an energy use and CO2 emissions reduction evaluation model for China's online car hailing services," Energy, Elsevier, vol. 154(C), pages 298-307.
    2. Zuo, Hongyan & Zhang, Bin & Huang, Zhonghua & Wei, Kexiang & Zhu, Hong & Tan, Jiqiu, 2022. "Effect analysis on SOC values of the power lithium manganate battery during discharging process and its intelligent estimation," Energy, Elsevier, vol. 238(PB).
    3. Hu, Wenyu & E, Jiaqiang & Leng, Erwei & Zhang, Feng & Chen, Jingwei & Ma, Yinjie, 2023. "Investigation on harvesting characteristics of convective wind energy from vehicle driving on multi-lane highway," Energy, Elsevier, vol. 263(PE).
    4. Ren, Lei & Zhou, Sheng & Peng, Tianduo & Ou, Xunmin, 2022. "Greenhouse gas life cycle analysis of China's fuel cell medium- and heavy-duty trucks under segmented usage scenarios and vehicle types," Energy, Elsevier, vol. 249(C).
    5. Zhao, Xiaohuan & Jiang, Jiang & Zuo, Hongyan & Jia, Guohai, 2023. "Soot combustion characteristics of oxygen concentration and regeneration temperature effect on continuous pulsation regeneration in diesel particulate filter for heavy-duty truck," Energy, Elsevier, vol. 264(C).
    6. Zuo, Hongyan & Tan, Jiqiu & Wei, Kexiang & Huang, Zhonghua & Zhong, Dingqing & Xie, Fuchun, 2021. "Effects of different poses and wind speeds on wind-induced vibration characteristics of a dish solar concentrator system," Renewable Energy, Elsevier, vol. 168(C), pages 1308-1326.
    7. Feng, Changling & E, Jiaqiang & Han, Wei & Deng, Yuanwang & Zhang, Bin & Zhao, Xiaohuan & Han, Dandan, 2021. "Key technology and application analysis of zeolite adsorption for energy storage and heat-mass transfer process: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 144(C).
    8. Peng, Tianduo & Ou, Xunmin & Yuan, Zhiyi & Yan, Xiaoyu & Zhang, Xiliang, 2018. "Development and application of China provincial road transport energy demand and GHG emissions analysis model," Applied Energy, Elsevier, vol. 222(C), pages 313-328.
    9. Feng, Changling & Deng, Yuanwang & E, Jiaqiang & Han, Dandan & Tan, Yan & Luo, Xiaoyu, 2022. "Effects of the ZSM-5 zeolites on hydrocarbon emission control of gasoline engine under cold start," Energy, Elsevier, vol. 260(C).
    10. Ou, Xunmin & Xiaoyu, Yan & Zhang, Xiliang, 2011. "Life-cycle energy consumption and greenhouse gas emissions for electricity generation and supply in China," Applied Energy, Elsevier, vol. 88(1), pages 289-297, January.
    11. Zhao, Dan & Ji, Chenzhen & Teo, C. & Li, Shihuai, 2014. "Performance of small-scale bladeless electromagnetic energy harvesters driven by water or air," Energy, Elsevier, vol. 74(C), pages 99-108.
    12. Feng, Changling & Deng, Yuanwang & Chen, Lehan & Han, Wei & E, Jiaqiang & Wei, Kexiang & Han, Dandan & Zhang, Bin, 2022. "Hydrocarbon emission control of a hydrocarbon adsorber and converter under cold start of the gasoline engine," Energy, Elsevier, vol. 239(PB).
    13. Qian Zhang & Xunmin Ou & Xiaoyu Yan & Xiliang Zhang, 2017. "Electric Vehicle Market Penetration and Impacts on Energy Consumption and CO 2 Emission in the Future: Beijing Case," Energies, MDPI, vol. 10(2), pages 1-15, February.
    14. Wang, Hailin & Ou, Xunmin & Zhang, Xiliang, 2017. "Mode, technology, energy consumption, and resulting CO2 emissions in China's transport sector up to 2050," Energy Policy, Elsevier, vol. 109(C), pages 719-733.
    15. Deng, Yuanwang & Feng, Changling & E, Jiaqiang & Wei, Kexiang & Zhang, Bin & Zhang, Zhiqing & Han, Dandan & Zhao, Xiaohuan & Xu, Wenwen, 2019. "Performance enhancement of the gasoline engine hydrocarbon catchers for reducing hydrocarbon emission during the cold-start period," Energy, Elsevier, vol. 183(C), pages 869-879.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Feng, Changling & E, Jiaqiang & Kou, Chuanfu & Han, Dandan & Han, Chang & Tan, Yan & Deng, Yuanwang, 2024. "Investigation on the hydrocarbon adsorption performance enhancement of the ZSM-5 zeolite with different Si/Al ratio in the cold start process of the gasoline engine," Energy, Elsevier, vol. 300(C).
    2. Yu, Junjie & Kou, Chuanfu & Ma, Yinjie & E, Jiaqiang & Feng, Changling, 2024. "Effect analysis on hydrocarbon adsorption enhancement of different zeolites in cold start of gasoline engine based on Monte Carlo method," Energy, Elsevier, vol. 294(C).
    3. Zhang, Zhiqing & Dong, Rui & Tan, Dongli & Duan, Lin & Jiang, Feng & Yao, Xiaoxue & Yang, Dixin & Hu, Jingyi & Zhang, Jian & Zhong, Weihuang & Zhao, Ziheng, 2023. "Effect of structural parameters on diesel particulate filter trapping performance of heavy-duty diesel engines based on grey correlation analysis," Energy, Elsevier, vol. 271(C).
    4. Han, Dandan & E, Jiaqiang & Feng, Changling & Han, Chang & Kou, Chuanfu & Tan, Yan & Peng, Yanchun & Wei, Lingyun, 2024. "Experimental and simulation investigation on the different iron content beta zeolite for controlling the cold-start hydrocarbon emission from a gasoline vehicle," Energy, Elsevier, vol. 294(C).
    5. Hu, Wenyu & E, Jiaqiang & Han, Dandan & Feng, Changling & Luo, Xiaoyu, 2023. "Investigation on distribution characteristics of convective wind energy from vehicle driving on multi-lane highway," Energy, Elsevier, vol. 271(C).
    6. Zhao, Xiaohuan & Jiang, Jiang & Zuo, Hongyan & Mao, Zhengsong, 2023. "Performance analysis of diesel particulate filter thermoelectric conversion mobile energy storage system under engine conditions of low-speed and light-load," Energy, Elsevier, vol. 282(C).
    7. Han, Dandan & Deng, Yuanwang & E, Jiaqiang & Feng, Changling & Tan, Yan, 2023. "Experimental and simulation study on Fe-beta controlling of hydrocarbon emission during cold start of gasoline vehicle world light vehicle test cycle," Energy, Elsevier, vol. 277(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Zhang, Zhiqing & Dong, Rui & Tan, Dongli & Duan, Lin & Jiang, Feng & Yao, Xiaoxue & Yang, Dixin & Hu, Jingyi & Zhang, Jian & Zhong, Weihuang & Zhao, Ziheng, 2023. "Effect of structural parameters on diesel particulate filter trapping performance of heavy-duty diesel engines based on grey correlation analysis," Energy, Elsevier, vol. 271(C).
    2. Hu, Wenyu & E, Jiaqiang & Han, Dandan & Feng, Changling & Luo, Xiaoyu, 2023. "Investigation on distribution characteristics of convective wind energy from vehicle driving on multi-lane highway," Energy, Elsevier, vol. 271(C).
    3. Hu, Wenyu & E, Jiaqiang & Leng, Erwei & Zhang, Feng & Chen, Jingwei & Ma, Yinjie, 2023. "Investigation on harvesting characteristics of convective wind energy from vehicle driving on multi-lane highway," Energy, Elsevier, vol. 263(PE).
    4. Ma, Ying & Yang, Heng & Zuo, Hongyan & Zuo, Qingsong & He, Xiaoxiang & Chen, Wei & Wei, Rongrong, 2023. "EG@Bi-MOF derived porous carbon/lauric acid composite phase change materials for thermal management of batteries," Energy, Elsevier, vol. 272(C).
    5. Hu, Wenyu & E, Jiaqiang & Zhang, Feng & Chen, Jingwei & Ma, Yinjie & Leng, Erwei, 2022. "Investigation on cooperative mechanism between convective wind energy harvesting and dust collection during vehicle driving on the highway," Energy, Elsevier, vol. 260(C).
    6. Zhang, Zhiqing & Li, Jiangtao & Tian, Jie & Dong, Rui & Zou, Zhi & Gao, Sheng & Tan, Dongli, 2022. "Performance, combustion and emission characteristics investigations on a diesel engine fueled with diesel/ ethanol /n-butanol blends," Energy, Elsevier, vol. 249(C).
    7. Ma, Ying & Yang, Heng & Zuo, Hongyan & Ma, Yi & Zuo, Qingsong & Chen, Ying & He, Xiaoxiang & Wei, Rongrong, 2023. "Three-dimensional EG@MOF matrix composite phase change materials for high efficiency battery cooling," Energy, Elsevier, vol. 278(C).
    8. Zhang, Zhiqing & Lv, Junshuai & Xie, Guanglin & Wang, Su & Ye, Yanshuai & Huang, Gaohua & Tan, Donlgi, 2022. "Effect of assisted hydrogen on combustion and emission characteristics of a diesel engine fueled with biodiesel," Energy, Elsevier, vol. 254(PA).
    9. E, Shengxin & Cui, Yaxin & Liu, Yuxian & Yin, Huichun, 2023. "Effects of the different phase change materials on heat dissipation performances of the ternary polymer Li-ion battery pack in hot climate," Energy, Elsevier, vol. 282(C).
    10. Tan, Dongli & Li, Dongmei & Wang, Su & Zhang, Zhiqing & Tian, Jie & Li, Jiangtao & Lv, Junshuai & Zheng, Wenling & Ye, Yanshuai, 2023. "Evaluation and optimization of hydrogen addition on the performance and emission for biodiesel dual-fuel engines with different blend ratios based on the response surface method," Energy, Elsevier, vol. 283(C).
    11. Hu, Wenyu & E, Jiaqiang & Tan, Yan & Zhang, Feng & Liao, Gaoliang, 2022. "Modified wind energy collection devices for harvesting convective wind energy from cars and trucks moving in the highway," Energy, Elsevier, vol. 247(C).
    12. Tan, Yan & Kou, Chuanfu & E, Jiaqiang & Feng, Changlin & Han, Dandan, 2024. "Effect of different exhaust parameters on conversion efficiency enhancement of a Pd–Rh three-way catalytic converter for heavy-duty natural gas engines," Energy, Elsevier, vol. 292(C).
    13. E, Shengxin & Liu, Yuxian & Cui, Yaxin & Wu, Aojin & Yin, Huichun, 2023. "Effects of composite cooling strategy including phase change material and cooling air on the heat dissipation performance improvement of lithium ion power batteries pack in hot climate and its catastr," Energy, Elsevier, vol. 283(C).
    14. Tan, Dongli & Meng, Yujun & Tian, Jie & Zhang, Chengtao & Zhang, Zhiqing & Yang, Guanhua & Cui, Shuwan & Hu, Jingyi & Zhao, Ziheng, 2023. "Utilization of renewable and sustainable diesel/methanol/n-butanol (DMB) blends for reducing the engine emissions in a diesel engine with different pre-injection strategies," Energy, Elsevier, vol. 269(C).
    15. Gao, Sheng & Zhang, Yanhui & Zhang, Zhiqing & Tan, Dongli & Li, Junming & Yin, Zibin & Hu, Jingyi & Zhao, Ziheng, 2023. "Multi-objective optimization of the combustion chamber geometry for a highland diesel engine fueled with diesel/n-butanol/PODEn by ANN-NSGA III," Energy, Elsevier, vol. 282(C).
    16. Tan, Dongli & Wu, Yao & Lv, Junshuai & Li, Jian & Ou, Xiaoyu & Meng, Yujun & Lan, Guanglin & Chen, Yanhui & Zhang, Zhiqing, 2023. "Performance optimization of a diesel engine fueled with hydrogen/biodiesel with water addition based on the response surface methodology," Energy, Elsevier, vol. 263(PC).
    17. Yu, Junjie & Kou, Chuanfu & Ma, Yinjie & E, Jiaqiang & Feng, Changling, 2024. "Effect analysis on hydrocarbon adsorption enhancement of different zeolites in cold start of gasoline engine based on Monte Carlo method," Energy, Elsevier, vol. 294(C).
    18. Yin, Zibin & Cai, Wenwei & Zhang, Zhuo & Deng, Zijin & Li, Zhiyong, 2022. "Effects of hydrogen-rich products from methanol steam reforming on the performance enhancement of a medium-speed marine engine," Energy, Elsevier, vol. 256(C).
    19. Zhao, Xiaohuan & Jiang, Jiang & Mao, Zhengsong, 2023. "Effect of filter material and porosity on the energy storage capacity characteristics of diesel particulate filter thermoelectric conversion mobile energy storage system," Energy, Elsevier, vol. 283(C).
    20. Li, Jiangtao & Zhang, Zhiqing & Ye, Yanshuai & Li, Weiqing & Yuan, Tao & Wang, Haijiao & Li, Yongtao & Tan, Dongli & Zhang, Chengtao, 2022. "Effects of different injection timing on the performance, combustion and emission characteristics of diesel/ethanol/n-butanol blended diesel engine based on multi-objective optimization theory," Energy, Elsevier, vol. 260(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:267:y:2023:i:c:s0360544222034417. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.