IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v263y2023ipes0360544222029449.html
   My bibliography  Save this article

Electrospun derived polymer-garnet composite quasi solid state electrolyte with low interface resistance for lithium metal batteries

Author

Listed:
  • Rajamani, Arunkumar
  • Panneerselvam, Thamayanthi
  • Murugan, Ramaswamy
  • Ramaswamy, Arun Prasath

Abstract

Polymer garnet composite electrolyte is a promising stable electrolyte to replace the hazardous/unstable liquid electrolytes in lithium-ion batteries due to their synergistic advantage of solid organic polymer electrolytes and inorganic ceramic electrolytes. Herein, we report polymer blend-based garnet composite quasi solid state electrospun electrolytes for lithium metal batteries. To be specific, Ta doped lithium lanthanum zirconium oxide, Li6·4La3Ta0·6Zr1·4O12 (LLZTO) incorporated with poly (vinyldine fluoride-hexafluro propylene) (PVdF-HFP)/poly butyl methacrylate (PBMA) electrospun membrane as the composite electrolyte, named as Ta-ESM and similarly, LLZTO free electrolyte named as ESM. The inclusion of LLZTO into the polymer matrix enhances the room temperature ionic conductivity from 9.924 × 10−4 (ESM) to 4.858 × 10−3 S cm−1 (Ta-ESM) along with lithium-ion transference number (0.61). Furthermore, polymer garnet composite electrolytes (Ta-ESM) restraint the growth of lithium dendrites, confirmed by the time-dependent impedance method and galvanostatic cycling technique. We have demonstrated the charge-discharge behaviour of lithium-metal battery using LiFePO4 cathode and lithium metal anode using Ta-ESM electrolyte, delivering 178 mA h g−1 at 0.1C and cyclability of 100 cycles. The high electrolyte uptake (582%) and porosity (64.1%) in Ta-ESM help achieve fast ionic migration and thus attain stable cycling.

Suggested Citation

  • Rajamani, Arunkumar & Panneerselvam, Thamayanthi & Murugan, Ramaswamy & Ramaswamy, Arun Prasath, 2023. "Electrospun derived polymer-garnet composite quasi solid state electrolyte with low interface resistance for lithium metal batteries," Energy, Elsevier, vol. 263(PE).
    • Handle: RePEc:eee:energy:v:263:y:2023:i:pe:s0360544222029449
    DOI: 10.1016/j.energy.2022.126058
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544222029449
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2022.126058?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Yang Jin & Kai Liu & Jialiang Lang & Denys Zhuo & Zeya Huang & Chang-an Wang & Hui Wu & Yi Cui, 2018. "An intermediate temperature garnet-type solid electrolyte-based molten lithium battery for grid energy storage," Nature Energy, Nature, vol. 3(9), pages 732-738, September.
    2. Shahjalal, Mohammad & Roy, Probir Kumar & Shams, Tamanna & Fly, Ashley & Chowdhury, Jahedul Islam & Ahmed, Md. Rishad & Liu, Kailong, 2022. "A review on second-life of Li-ion batteries: prospects, challenges, and issues," Energy, Elsevier, vol. 241(C).
    3. J.-M. Tarascon & M. Armand, 2001. "Issues and challenges facing rechargeable lithium batteries," Nature, Nature, vol. 414(6861), pages 359-367, November.
    4. Singh, Shishir Kumar & Shalu, & Balo, Liton & Gupta, Himani & Singh, Varun Kumar & Tripathi, Alok Kumar & Verma, Yogendra Lal & Singh, Rajendra Kumar, 2018. "Improved electrochemical performance of EMIMFSI ionic liquid based gel polymer electrolyte with temperature for rechargeable lithium battery," Energy, Elsevier, vol. 150(C), pages 890-900.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Guo, Fei & Wu, Xiongwei & Liu, Lili & Ye, Jilei & Wang, Tao & Fu, Lijun & Wu, Yuping, 2023. "Prediction of remaining useful life and state of health of lithium batteries based on time series feature and Savitzky-Golay filter combined with gated recurrent unit neural network," Energy, Elsevier, vol. 270(C).
    2. Zhi Chang & Huijun Yang & Xingyu Zhu & Ping He & Haoshen Zhou, 2022. "A stable quasi-solid electrolyte improves the safe operation of highly efficient lithium-metal pouch cells in harsh environments," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    3. Chao Wang & Ming Liu & Michel Thijs & Frans G. B. Ooms & Swapna Ganapathy & Marnix Wagemaker, 2021. "High dielectric barium titanate porous scaffold for efficient Li metal cycling in anode-free cells," Nature Communications, Nature, vol. 12(1), pages 1-11, December.
    4. Liao, Xiaolin & Sun, Peiyi & Xu, Mengqing & Xing, Lidan & Liao, Youhao & Zhang, Liping & Yu, Le & Fan, Weizhen & Li, Weishan, 2016. "Application of tris(trimethylsilyl)borate to suppress self-discharge of layered nickel cobalt manganese oxide for high energy battery," Applied Energy, Elsevier, vol. 175(C), pages 505-511.
    5. Ma, Mina & Wang, Yu & Duan, Qiangling & Wu, Tangqin & Sun, Jinhua & Wang, Qingsong, 2018. "Fault detection of the connection of lithium-ion power batteries in series for electric vehicles based on statistical analysis," Energy, Elsevier, vol. 164(C), pages 745-756.
    6. Guo-Rui Zhu & Qin Zhang & Qing-Song Liu & Qi-Yao Bai & Yi-Zhou Quan & You Gao & Gang Wu & Yu-Zhong Wang, 2023. "Non-flammable solvent-free liquid polymer electrolyte for lithium metal batteries," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    7. Navaratnarajah Kuganathan & Alexander Chroneos, 2020. "Lithium Storage in Nanoporous Complex Oxide 12CaO•7Al 2 O 3 (C12A7)," Energies, MDPI, vol. 13(7), pages 1-10, March.
    8. Sai Vinayak Ganesh & Matilde D’Arpino, 2023. "Critical Comparison of Li-Ion Aging Models for Second Life Battery Applications," Energies, MDPI, vol. 16(7), pages 1-23, March.
    9. Zhi Chang & Huijun Yang & Anqiang Pan & Ping He & Haoshen Zhou, 2022. "An improved 9 micron thick separator for a 350 Wh/kg lithium metal rechargeable pouch cell," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    10. Zhu, Xiaoqing & Wang, Zhenpo & Wang, Yituo & Wang, Hsin & Wang, Cong & Tong, Lei & Yi, Mi, 2019. "Overcharge investigation of large format lithium-ion pouch cells with Li(Ni0.6Co0.2Mn0.2)O2 cathode for electric vehicles: Thermal runaway features and safety management method," Energy, Elsevier, vol. 169(C), pages 868-880.
    11. Wang, Wei & Wu, Yufeng, 2017. "An overview of recycling and treatment of spent LiFePO4 batteries in China," Resources, Conservation & Recycling, Elsevier, vol. 127(C), pages 233-243.
    12. Xiaozhe Zhang & Pan Xu & Jianing Duan & Xiaodong Lin & Juanjuan Sun & Wenjie Shi & Hewei Xu & Wenjie Dou & Qingyi Zheng & Ruming Yuan & Jiande Wang & Yan Zhang & Shanshan Yu & Zehan Chen & Mingsen Zhe, 2024. "A dicarbonate solvent electrolyte for high performance 5 V-Class Lithium-based batteries," Nature Communications, Nature, vol. 15(1), pages 1-18, December.
    13. Pinelopi Angelopoulou & Spyros Kassavetis & Joan Papavasiliou & Dimitris Karfaridis & Grzegorz Słowik & Panos Patsalas & George Avgouropoulos, 2021. "Enhanced Performance of LiAl 0.1 Mn 1.9 O 4 Cathode for Li-Ion Battery via TiN Coating," Energies, MDPI, vol. 14(4), pages 1-14, February.
    14. Xinxin Wang & Jingjing Chen & Dajian Wang & Zhiyong Mao, 2021. "Improving the alkali metal electrode/inorganic solid electrolyte contact via room-temperature ultrasound solid welding," Nature Communications, Nature, vol. 12(1), pages 1-8, December.
    15. Dong Hou & Zhengrui Xu & Zhijie Yang & Chunguang Kuai & Zhijia Du & Cheng-Jun Sun & Yang Ren & Jue Liu & Xianghui Xiao & Feng Lin, 2022. "Effect of the grain arrangements on the thermal stability of polycrystalline nickel-rich lithium-based battery cathodes," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    16. Beata Kurc & Xymena Gross & Ewelina Rudnicka & Łukasz Rymaniak, 2024. "Thermal Studies of Lithium-Ion Cells: Ensuring Safe and Efficient Energy Storage," Energies, MDPI, vol. 17(9), pages 1-17, April.
    17. He, Lihua & Xu, Shengming & Zhao, Zhongwei, 2017. "Suppressing the formation of Fe2P: Thermodynamic study on the phase diagram and phase transformation for LiFePO4 synthesis," Energy, Elsevier, vol. 134(C), pages 962-967.
    18. Qingyuan Li & De Ning & Deniz Wong & Ke An & Yuxin Tang & Dong Zhou & Götz Schuck & Zhenhua Chen & Nian Zhang & Xiangfeng Liu, 2022. "Improving the oxygen redox reversibility of Li-rich battery cathode materials via Coulombic repulsive interactions strategy," Nature Communications, Nature, vol. 13(1), pages 1-13, December.
    19. Huimin Zhang & Jingyi Qiu & Jie Pang & Gaoping Cao & Bingsen Zhang & Li Wang & Xiangming He & Xuning Feng & Shizhou Ma & Xinggao Zhang & Hai Ming & Zhuangnan Li & Feng Li & Hao Zhang, 2024. "Sub-millisecond lithiothermal synthesis of graphitic meso–microporous carbon," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    20. Shriram S. Rangarajan & Suvetha Poyyamani Sunddararaj & AVV Sudhakar & Chandan Kumar Shiva & Umashankar Subramaniam & E. Randolph Collins & Tomonobu Senjyu, 2022. "Lithium-Ion Batteries—The Crux of Electric Vehicles with Opportunities and Challenges," Clean Technol., MDPI, vol. 4(4), pages 1-23, September.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:263:y:2023:i:pe:s0360544222029449. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.