IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v255y2022ics0360544222013779.html
   My bibliography  Save this article

Internally enhanced conductive 3D porous hierarchical biochar framework for lithium sulfur battery

Author

Listed:
  • Wu, Yaqin
  • Wang, Feiyue
  • Fan, Zhupu
  • Wang, Zihang
  • Yang, Wenying
  • Ju, Wenqin
  • Lei, Weixin
  • Zou, Youlan
  • Ma, Zengsheng

Abstract

Due to the insulation of S8 and its discharge product Li2S, the stability of the conductive network in the positive electrode of lithium-sulfur batteries (LSBs) becomes critical. So, an internally enhanced high strength conductive three-dimensional (3D) biochar framework composite of high porosity biochar and carbon nanotube (HPBC/CNTs) is synthesized in this paper. The framework has a “reinforced concrete structure”, HPBC as “concrete” and CNTs as “reinforcement” to promote the strength of the matrix and maintain structural stability, thus improving the cyclic stability of the cathode material. In the designed composite, HPBC is interconnected and can effectively strengthens the physical constraints and traps soluble polysulfides; the CNTs buried in HPBC provides a highly reliable conductive pathway to facilitate electron/ion transport. As a result, the HPBC/CNTs/S composite exhibits good electrochemical performances. It has a high specific capacity of 1227, 1039, 739 and 639 mAh g−1 at 0.5, 1.0, 2.0 and 4.0C, respectively. In long-life cycles, the composite has an initial discharge capacity of 988.41 mAh g−1 at 1.0C, and it is still able to maintain a reversible specific capacity of 482.42 mAh g−1 after 1000 cycles, with a capacity decay rate of 0.051% per cycle.

Suggested Citation

  • Wu, Yaqin & Wang, Feiyue & Fan, Zhupu & Wang, Zihang & Yang, Wenying & Ju, Wenqin & Lei, Weixin & Zou, Youlan & Ma, Zengsheng, 2022. "Internally enhanced conductive 3D porous hierarchical biochar framework for lithium sulfur battery," Energy, Elsevier, vol. 255(C).
  • Handle: RePEc:eee:energy:v:255:y:2022:i:c:s0360544222013779
    DOI: 10.1016/j.energy.2022.124474
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544222013779
    Download Restriction: Full text for ScienceDirect subscribers only

    File URL: https://libkey.io/10.1016/j.energy.2022.124474?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Kong, Fanhou & Liang, Xue & Yi, Lanlin & Fang, Xiaohui & Yin, Zhongbin & Wang, Yulong & Zhang, Ruixiang & Liu, Longyang & Chen, Qing & Li, Minghan & Li, Changjiu & Jiang, Hong & Chen, Yongjun, 2021. "Multi-electron reactions for the synthesis of a vanadium-based amorphous material as lithium-ion battery cathode with high specific capacity," Energy, Elsevier, vol. 219(C).
    2. Lee, Won Yeol & Jin, En Mei & Cho, Jung Sang & Kang, Dong-Won & Jin, Bo & Jeong, Sang Mun, 2020. "Freestanding flexible multilayered Sulfur–Carbon nanotubes for Lithium–Sulfur battery cathodes," Energy, Elsevier, vol. 212(C).
    3. Zhao, Xiaojun & Wang, Gang & Zhou, Yixuan & Wang, Hui, 2017. "Flexible free-standing ternary CoSnO3/graphene/carbon nanotubes composite papers as anodes for enhanced performance of lithium-ion batteries," Energy, Elsevier, vol. 118(C), pages 172-180.
    4. Guoxing Li & Jinhua Sun & Wenpeng Hou & Shidong Jiang & Yong Huang & Jianxin Geng, 2016. "Three-dimensional porous carbon composites containing high sulfur nanoparticle content for high-performance lithium–sulfur batteries," Nature Communications, Nature, vol. 7(1), pages 1-10, April.
    5. Jiang, Zhibin & Chen, Ling & Zhang, Wenguang & Chen, Shiyu & Jian, Xiying & Liu, Xiang & Chen, Hongyu & Guo, Chunlei & Li, Weishan, 2021. "Sandwich-like NOCC@S8/rGO composite as cathode for high energy lithium-sulfur batteries," Energy, Elsevier, vol. 220(C).
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Liu, Hongwei & Wang, Yongzhen & Lv, Liang & Liu, Xiao & Wang, Ziqi & Liu, Jun, 2023. "Oxygen-enriched hierarchical porous carbons derived from lignite for high-performance supercapacitors," Energy, Elsevier, vol. 269(C).
    2. Tian, Xiaohui & Che, Lukang & Cheng, Yunnian & Liu, Mengdie & Selabi, Naomie Beolle Songwe & Zhou, Yingke, 2024. "Remarkable chemical adsorption and catalysis of monodisperse metallic cobalt sulfide nanoparticles enable long-cycling Li–S battery with high areal capacity and low shuttle constant," Energy, Elsevier, vol. 288(C).
    3. Olabi, Abdul Ghani & Abbas, Qaisar & Shinde, Pragati A. & Abdelkareem, Mohammad Ali, 2023. "Rechargeable batteries: Technological advancement, challenges, current and emerging applications," Energy, Elsevier, vol. 266(C).
    4. Lv, Chunfei & Ma, Xiaojun & Guo, Ranran & Li, Dongna & Hua, Xuewen & Jiang, Tianyu & Li, Hongpeng & Liu, Yang, 2023. "Polypyrrole-decorated hierarchical carbon aerogel from liquefied wood enabling high energy density and capacitance supercapacitor," Energy, Elsevier, vol. 270(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Tan Thong, Pham & Sadhasivam, T. & Kim, Nam-In & Kim, Yoong Ahm & Roh, Sung-Hee & Jung, Ho-Young, 2021. "Highly conductive current collector for enhancing conductivity and power supply of flexible thin-film Zn–MnO2 battery," Energy, Elsevier, vol. 221(C).
    2. Tian, Xiaohui & Che, Lukang & Cheng, Yunnian & Liu, Mengdie & Selabi, Naomie Beolle Songwe & Zhou, Yingke, 2024. "Remarkable chemical adsorption and catalysis of monodisperse metallic cobalt sulfide nanoparticles enable long-cycling Li–S battery with high areal capacity and low shuttle constant," Energy, Elsevier, vol. 288(C).
    3. Liu, Hongwei & Wang, Yongzhen & Lv, Liang & Liu, Xiao & Wang, Ziqi & Liu, Jun, 2023. "Oxygen-enriched hierarchical porous carbons derived from lignite for high-performance supercapacitors," Energy, Elsevier, vol. 269(C).
    4. Tang, Hong & Jiang, Mengjin & Ren, Erhui & Zhang, Yue & Lai, Xiaoxu & Cui, Ce & Jiang, Shouxiang & Zhou, Mi & Qin, Qin & Guo, Ronghui, 2020. "Integrate electrical conductivity and Li+ ion mobility into hierarchical heterostructure Ti3C2@CoO/ZnO composites toward high-performance lithium ion storage," Energy, Elsevier, vol. 212(C).
    5. Tiwari, Vimal K. & Song, Hyeonjun & Oh, Yeonjae & Jeong, Youngjin, 2020. "Synthesis of sulfur-co-polymer/porous long carbon nanotubes composite cathode by chemical and physical binding for high performance lithium-sulfur batteries," Energy, Elsevier, vol. 195(C).
    6. Wan, Hongri & Shen, Xiran & Jiang, Hao & Zhang, Cheng & Jiang, Kaile & Chen, Teng & Shi, Liluo & Dong, Liming & He, Changchun & Xu, Yan & Li, Jing & Chen, Yan, 2021. "Biomass-derived N/S dual-doped porous hard-carbon as high-capacity anodes for lithium/sodium ions batteries," Energy, Elsevier, vol. 231(C).
    7. Che, Yunhong & Deng, Zhongwei & Li, Penghua & Tang, Xiaolin & Khosravinia, Kavian & Lin, Xianke & Hu, Xiaosong, 2022. "State of health prognostics for series battery packs: A universal deep learning method," Energy, Elsevier, vol. 238(PB).
    8. Wang, Mingyue & Huang, Ying & Wang, Ke & Zhu, Yade & Zhang, Na & Zhang, Hongming & Li, Suping & Feng, Zhenhe, 2018. "PVD synthesis of binder-free silicon and carbon coated 3D α-Fe2O3 nanorods hybrid films as high-capacity and long-life anode for flexible lithium-ion batteries," Energy, Elsevier, vol. 164(C), pages 1021-1029.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:255:y:2022:i:c:s0360544222013779. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.