IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v255y2022ics0360544222013408.html
   My bibliography  Save this article

HMF hydrogenolysis over carbon-supported Ni–Cu catalysts to produce hydrogenated biofuels

Author

Listed:
  • Viar, Nerea
  • Requies, Jesus M.
  • Agirre, Ion
  • Iriondo, Aitziber
  • García-Sancho, Cristina
  • Arias, Pedro L.

Abstract

Non-noble monometallic and bimetallic catalysts supported in biomass-derived carbon were tested in the 2,5-dimethylfuran (DMF) and 2,5-dimethyltetrahydrofuran (DMTHF) production from 5-hydroxymethylfurfural (HMF) hydrogenolysis using a fixed-bed continuous-flow reactor. These support and reaction system were selected in order to obtain a more sustainable catalyst development and to implement a continuous flow reaction system. The carbon-supported biomass-derived catalysts were compared with catalysts supported on commercial carbons, which were treated with acid to remove impurities. All the bimetallic catalysts exhibited high stability after 25 h-on stream, achieving DMF yields above 50% and complete HMF conversion. Biomass-derived carbon supported catalysts seems more selective toward DMF during the 8-9 h-on stream than commercial carbon supported ones. The good activity and stability of the bimetallic catalysts seems to be related to the synergistic effect between acid and metallic sites, exhibiting the most promising ones an excellent stability for 46 h on stream. Monometallic catalysts exhibited high yields, above 70%, at the beginning of the reaction. However, they suffer from partial deactivation, probably due to metal sintering. Finally, the obtained catalytic activities and selectivities toward target products are close to the reported ones for discontinuous systems, being an important aspect for its possible industrial application.

Suggested Citation

  • Viar, Nerea & Requies, Jesus M. & Agirre, Ion & Iriondo, Aitziber & García-Sancho, Cristina & Arias, Pedro L., 2022. "HMF hydrogenolysis over carbon-supported Ni–Cu catalysts to produce hydrogenated biofuels," Energy, Elsevier, vol. 255(C).
  • Handle: RePEc:eee:energy:v:255:y:2022:i:c:s0360544222013408
    DOI: 10.1016/j.energy.2022.124437
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544222013408
    Download Restriction: Full text for ScienceDirect subscribers only

    File URL: https://libkey.io/10.1016/j.energy.2022.124437?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Viar, Nerea & Requies, Jesús M. & Agirre, Ion & Iriondo, Aitziber & Arias, Pedro L., 2019. "Furanic biofuels production from biomass using Cu-based heterogeneous catalysts," Energy, Elsevier, vol. 172(C), pages 531-544.
    2. de Andrade, Taynara S. & Souza, Mariana M.V.M. & Manfro, Robinson L., 2020. "Hydrogenolysis of glycerol to 1,2-propanediol without external H2 addition in alkaline medium using Ni-Cu catalysts supported on Y zeolite," Renewable Energy, Elsevier, vol. 160(C), pages 919-930.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Tang, Xincheng & Wu, Yanxiao & Fang, Zhenchang & Dong, Xinyu & Du, Zhongxuan & Deng, Bicai & Sun, Chunhua & Zhou, Feng & Qiao, Xinqi & Li, Xinling, 2024. "Syntheses, catalytic performances and DFT investigations: A recent review of copper-based catalysts of methanol steam reforming for hydrogen production," Energy, Elsevier, vol. 295(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Mourad, M. & Mahmoud, K., 2019. "Investigation into SI engine performance characteristics and emissions fuelled with ethanol/butanol-gasoline blends," Renewable Energy, Elsevier, vol. 143(C), pages 762-771.
    2. Su, Lijuan & Shao, Xiaojie & Chai, Lin & Ge, Hui & Wang, Hongliang & Cui, Xiaojing & Deng, Tiansheng & Hou, Xianglin, 2022. "Efficiently and directly produce triacetylglycerol from oils and fats over mesoporous polymeric solid acid catalysts," Renewable Energy, Elsevier, vol. 197(C), pages 432-442.
    3. Singh, Vijendra & Arumugam, Selvamani & Tathod, Anup Prakash & Kuldeep, & Vempatapu, Bhanu Prasad & Viswanadham, Nagabhatla, 2023. "Sustainable production of aromatics-rich gasoline stock from bio-glycerol over hierarchically porous Zn-decorated HZSM-5 catalyst," Renewable Energy, Elsevier, vol. 217(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:255:y:2022:i:c:s0360544222013408. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.