IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v172y2019icp531-544.html
   My bibliography  Save this article

Furanic biofuels production from biomass using Cu-based heterogeneous catalysts

Author

Listed:
  • Viar, Nerea
  • Requies, Jesús M.
  • Agirre, Ion
  • Iriondo, Aitziber
  • Arias, Pedro L.

Abstract

Biorefineries can be a good alternative to cover the current needs of energy, such as transportation fuels and also fine chemicals. 5-hydroxymethylfurfural (HMF) can be obtained directly from biomass, and it is considered one of the most promising intermediate for the synthesis of biofuels. In this work the production of 2,5-dimethylfuran (DMF) and 2,5-dimethyltetrahydrofuran (DMTHF), two particularly attractive compounds to be used as biofuels due to its similar characteristics to gasoline, has been studied. For this purpose, a continuous fixed bed catalytic reactor was employed using HMF as raw material. Zr-supported Cu, CeCu, RuCu and NiCu catalysts were tested. Moreover, the catalysts textural properties were also measured - before and after the activity tesst - in order to get a deeper understanding of the relationships among the measured DMF yields and the catalyst characteristics. Final DMF, DMTHF and butanol separation was also evaluated.

Suggested Citation

  • Viar, Nerea & Requies, Jesús M. & Agirre, Ion & Iriondo, Aitziber & Arias, Pedro L., 2019. "Furanic biofuels production from biomass using Cu-based heterogeneous catalysts," Energy, Elsevier, vol. 172(C), pages 531-544.
    • Handle: RePEc:eee:energy:v:172:y:2019:i:c:p:531-544
    DOI: 10.1016/j.energy.2019.01.109
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544219301124
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2019.01.109?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Tran, Luc Sy & Sirjean, Baptiste & Glaude, Pierre-Alexandre & Fournet, René & Battin-Leclerc, Frédérique, 2012. "Progress in detailed kinetic modeling of the combustion of oxygenated components of biofuels," Energy, Elsevier, vol. 43(1), pages 4-18.
    2. Qian, Yong & Zhu, Lifeng & Wang, Yue & Lu, Xingcai, 2015. "Recent progress in the development of biofuel 2,5-dimethylfuran," Renewable and Sustainable Energy Reviews, Elsevier, vol. 41(C), pages 633-646.
    3. Tang, Xing & Wei, Junnan & Ding, Ning & Sun, Yong & Zeng, Xianhai & Hu, Lei & Liu, Shijie & Lei, Tingzhou & Lin, Lu, 2017. "Chemoselective hydrogenation of biomass derived 5-hydroxymethylfurfural to diols: Key intermediates for sustainable chemicals, materials and fuels," Renewable and Sustainable Energy Reviews, Elsevier, vol. 77(C), pages 287-296.
    4. Chen, Guisheng & Shen, Yinggang & Zhang, Quanchang & Yao, Mingfa & Zheng, Zunqing & Liu, Haifeng, 2013. "Experimental study on combustion and emission characteristics of a diesel engine fueled with 2,5-dimethylfuran–diesel, n-butanol–diesel and gasoline–diesel blends," Energy, Elsevier, vol. 54(C), pages 333-342.
    5. Yuriy Román-Leshkov & Christopher J. Barrett & Zhen Y. Liu & James A. Dumesic, 2007. "Production of dimethylfuran for liquid fuels from biomass-derived carbohydrates," Nature, Nature, vol. 447(7147), pages 982-985, June.
    6. Chen, Guisheng & Di, Lei & Zhang, Quanchang & Zheng, Zunqing & Zhang, Wei, 2015. "Effects of 2,5-dimethylfuran fuel properties coupling with EGR (exhaust gas recirculation) on combustion and emission characteristics in common-rail diesel engines," Energy, Elsevier, vol. 93(P1), pages 284-293.
    7. Zheng, Zunqing & Xia, Mingtao & Liu, Haifeng & Wang, Xiaofeng & Yao, Mingfa, 2018. "Experimental study on combustion and emissions of dual fuel RCCI mode fueled with biodiesel/n-butanol, biodiesel/2,5-dimethylfuran and biodiesel/ethanol," Energy, Elsevier, vol. 148(C), pages 824-838.
    8. Zheng, Zunqing & Wang, XiaoFeng & Zhong, Xiaofan & Hu, Bin & Liu, Haifeng & Yao, Mingfa, 2016. "Experimental study on the combustion and emissions fueling biodiesel/n-butanol, biodiesel/ethanol and biodiesel/2,5-dimethylfuran on a diesel engine," Energy, Elsevier, vol. 115(P1), pages 539-549.
    9. Liu, Haifeng & Xu, Jia & Zheng, Zunqing & Li, Shanju & Yao, Mingfa, 2013. "Effects of fuel properties on combustion and emissions under both conventional and low temperature combustion mode fueling 2,5-dimethylfuran/diesel blends," Energy, Elsevier, vol. 62(C), pages 215-223.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Mourad, M. & Mahmoud, K., 2019. "Investigation into SI engine performance characteristics and emissions fuelled with ethanol/butanol-gasoline blends," Renewable Energy, Elsevier, vol. 143(C), pages 762-771.
    2. Viar, Nerea & Requies, Jesus M. & Agirre, Ion & Iriondo, Aitziber & García-Sancho, Cristina & Arias, Pedro L., 2022. "HMF hydrogenolysis over carbon-supported Ni–Cu catalysts to produce hydrogenated biofuels," Energy, Elsevier, vol. 255(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Mazen A. Eldeeb & Benjamin Akih-Kumgeh, 2018. "Recent Trends in the Production, Combustion and Modeling of Furan-Based Fuels," Energies, MDPI, vol. 11(3), pages 1-47, February.
    2. Ya, Yuchen & Nie, Xiaokang & Han, Weiwei & Xiang, Longkai & Gu, Mingyan & Chu, Huaqiang, 2020. "Effects of 2, 5–dimethylfuran/ethanol addition on soot formation in n-heptane/iso-octane/air coflow diffusion flames," Energy, Elsevier, vol. 210(C).
    3. Zheng, Zunqing & Xia, Mingtao & Liu, Haifeng & Wang, Xiaofeng & Yao, Mingfa, 2018. "Experimental study on combustion and emissions of dual fuel RCCI mode fueled with biodiesel/n-butanol, biodiesel/2,5-dimethylfuran and biodiesel/ethanol," Energy, Elsevier, vol. 148(C), pages 824-838.
    4. Zheng, Zunqing & Wang, XiaoFeng & Zhong, Xiaofan & Hu, Bin & Liu, Haifeng & Yao, Mingfa, 2016. "Experimental study on the combustion and emissions fueling biodiesel/n-butanol, biodiesel/ethanol and biodiesel/2,5-dimethylfuran on a diesel engine," Energy, Elsevier, vol. 115(P1), pages 539-549.
    5. Qianqian Mu & Fuwu Yan & Jizhou Zhang & Lei Xu & Yu Wang, 2021. "Experimental and Numerical Study on the Sooting Behaviors of Furanic Biofuels in Laminar Counterflow Diffusion Flames," Energies, MDPI, vol. 14(18), pages 1-16, September.
    6. Puneet Verma & Svetlana Stevanovic & Ali Zare & Gaurav Dwivedi & Thuy Chu Van & Morgan Davidson & Thomas Rainey & Richard J. Brown & Zoran D. Ristovski, 2019. "An Overview of the Influence of Biodiesel, Alcohols, and Various Oxygenated Additives on the Particulate Matter Emissions from Diesel Engines," Energies, MDPI, vol. 12(10), pages 1-25, May.
    7. Bergthorson, Jeffrey M. & Thomson, Murray J., 2015. "A review of the combustion and emissions properties of advanced transportation biofuels and their impact on existing and future engines," Renewable and Sustainable Energy Reviews, Elsevier, vol. 42(C), pages 1393-1417.
    8. Pachiannan, Tamilselvan & Zhong, Wenjun & Rajkumar, Sundararajan & He, Zhixia & Leng, Xianying & Wang, Qian, 2019. "A literature review of fuel effects on performance and emission characteristics of low-temperature combustion strategies," Applied Energy, Elsevier, vol. 251(C), pages 1-1.
    9. Thanigaivelan Vadivelu & Lavanya Ramanujam & Rajesh Ravi & Shivaprasad K. Vijayalakshmi & Manoranjitham Ezhilchandran, 2022. "An Exploratory Study of Direct Injection (DI) Diesel Engine Performance Using CNSL—Ethanol Biodiesel Blends with Hydrogen," Energies, MDPI, vol. 16(1), pages 1-13, December.
    10. Liu, Kaimin & Fu, Jianqin & Deng, Banglin & Yang, Jing & Tang, Qijun & Liu, Jingping, 2014. "The influences of pressure and temperature on laminar flame propagations of n-butanol, iso-octane and their blends," Energy, Elsevier, vol. 73(C), pages 703-715.
    11. Loganathan, S. & Leenus Jesu Martin, M. & Nagalingam, B. & Prabhu, L., 2018. "Heat release rate and performance simulation of DME fuelled diesel engine using oxygenate correction factor and load correction factor in double Wiebe function," Energy, Elsevier, vol. 150(C), pages 77-91.
    12. Chen, Guisheng & Di, Lei & Zhang, Quanchang & Zheng, Zunqing & Zhang, Wei, 2015. "Effects of 2,5-dimethylfuran fuel properties coupling with EGR (exhaust gas recirculation) on combustion and emission characteristics in common-rail diesel engines," Energy, Elsevier, vol. 93(P1), pages 284-293.
    13. Hu, Lei & Lin, Lu & Wu, Zhen & Zhou, Shouyong & Liu, Shijie, 2017. "Recent advances in catalytic transformation of biomass-derived 5-hydroxymethylfurfural into the innovative fuels and chemicals," Renewable and Sustainable Energy Reviews, Elsevier, vol. 74(C), pages 230-257.
    14. Haifeng Liu & Xichang Wang & Diping Zhang & Fang Dong & Xinlu Liu & Yong Yang & Haozhong Huang & Yang Wang & Qianlong Wang & Zunqing Zheng, 2019. "Investigation on Blending Effects of Gasoline Fuel with N-Butanol, DMF, and Ethanol on the Fuel Consumption and Harmful Emissions in a GDI Vehicle," Energies, MDPI, vol. 12(10), pages 1-21, May.
    15. Wang, Haiyong & Zhu, Changhui & Li, Dan & Liu, Qiying & Tan, Jin & Wang, Chenguang & Cai, Chiliu & Ma, Longlong, 2019. "Recent advances in catalytic conversion of biomass to 5-hydroxymethylfurfural and 2, 5-dimethylfuran," Renewable and Sustainable Energy Reviews, Elsevier, vol. 103(C), pages 227-247.
    16. Tuan Hoang, Anh & Viet Pham, Van, 2021. "2-Methylfuran (MF) as a potential biofuel: A thorough review on the production pathway from biomass, combustion progress, and application in engines," Renewable and Sustainable Energy Reviews, Elsevier, vol. 148(C).
    17. Wei Tian & Yunlu Chu & Zhiqiang Han & Xiang Wang & Wenbin Yu & Xueshun Wu, 2019. "Experimental Study of the Effect of Intake Oxygen Concentration on Engine Combustion Process and Hydrocarbon Emissions with N-Butanol-Diesel Blended Fuel," Energies, MDPI, vol. 12(7), pages 1-17, April.
    18. Huang, Yuhan & Surawski, Nic C. & Zhuang, Yuan & Zhou, John L. & Hong, Guang, 2021. "Dual injection: An effective and efficient technology to use renewable fuels in spark ignition engines," Renewable and Sustainable Energy Reviews, Elsevier, vol. 143(C).
    19. Xu, Nan & Gong, Jing & Huang, Zuohua, 2016. "Review on the production methods and fundamental combustion characteristics of furan derivatives," Renewable and Sustainable Energy Reviews, Elsevier, vol. 54(C), pages 1189-1211.
    20. Qian, Yong & Zhu, Lifeng & Wang, Yue & Lu, Xingcai, 2015. "Recent progress in the development of biofuel 2,5-dimethylfuran," Renewable and Sustainable Energy Reviews, Elsevier, vol. 41(C), pages 633-646.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:172:y:2019:i:c:p:531-544. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.