IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v197y2022icp432-442.html
   My bibliography  Save this article

Efficiently and directly produce triacetylglycerol from oils and fats over mesoporous polymeric solid acid catalysts

Author

Listed:
  • Su, Lijuan
  • Shao, Xiaojie
  • Chai, Lin
  • Ge, Hui
  • Wang, Hongliang
  • Cui, Xiaojing
  • Deng, Tiansheng
  • Hou, Xianglin

Abstract

A series of mesoporous solid acid catalysts (PDS-x) with large BET surface area, superior thermal stability, strong sulfonic acid groups and tunable Brønsted acidity were synthesized by the copolymerization of divinylbenzene (DVB) and sodium p-styrenesulfonate (SPSS). The PDS-x catalysts showed high activity on the direct and efficient production of triacetylglycerol (TAG) via acyl exchange reaction of oils (fats) and acetic acid. The highest TAG yield of 93.0 mol% was obtained on the PDS-x catalysts at a mild condition of 200 °C. By combining SEM, TEM, FT-IR/DRIFTS, BET, XRD, XPS, EA, 31P MAS NMR and TG-DTG, the key factors that affected the TAG yield were clarified on the PDS-x catalysts. Moreover, the origin of the slow deactivation on these catalysts was elucidated. The large BET surface area and abundant mesopores of catalysts allowed the contact of large-sized oils (fats) with the strong sulfonic acid groups, accounting for the high TAG yield.

Suggested Citation

  • Su, Lijuan & Shao, Xiaojie & Chai, Lin & Ge, Hui & Wang, Hongliang & Cui, Xiaojing & Deng, Tiansheng & Hou, Xianglin, 2022. "Efficiently and directly produce triacetylglycerol from oils and fats over mesoporous polymeric solid acid catalysts," Renewable Energy, Elsevier, vol. 197(C), pages 432-442.
    • Handle: RePEc:eee:renene:v:197:y:2022:i:c:p:432-442
    DOI: 10.1016/j.renene.2022.07.063
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148122010588
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2022.07.063?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Najafi, Bahman & Akbarian, Eivaz & Lashkarpour, S. Mehdi & Aghbashlo, Mortaza & Ghaziaskar, Hassan S. & Tabatabaei, Meisam, 2019. "Modeling of a dual fueled diesel engine operated by a novel fuel containing glycerol triacetate additive and biodiesel using artificial neural network tuned by genetic algorithm to reduce engine emiss," Energy, Elsevier, vol. 168(C), pages 1128-1137.
    2. Goyal, H.B. & Seal, Diptendu & Saxena, R.C., 2008. "Bio-fuels from thermochemical conversion of renewable resources: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 12(2), pages 504-517, February.
    3. Sansaniwal, S.K. & Rosen, M.A. & Tyagi, S.K., 2017. "Global challenges in the sustainable development of biomass gasification: An overview," Renewable and Sustainable Energy Reviews, Elsevier, vol. 80(C), pages 23-43.
    4. Yusuff, Adeyinka S. & Bhonsle, Aman K. & Trivedi, Jayati & Bangwal, Dinesh P. & Singh, Lok P. & Atray, Neeraj, 2021. "Synthesis and characterization of coal fly ash supported zinc oxide catalyst for biodiesel production using used cooking oil as feed," Renewable Energy, Elsevier, vol. 170(C), pages 302-314.
    5. Panwar, N.L. & Kaushik, S.C. & Kothari, Surendra, 2011. "Role of renewable energy sources in environmental protection: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(3), pages 1513-1524, April.
    6. de Andrade, Taynara S. & Souza, Mariana M.V.M. & Manfro, Robinson L., 2020. "Hydrogenolysis of glycerol to 1,2-propanediol without external H2 addition in alkaline medium using Ni-Cu catalysts supported on Y zeolite," Renewable Energy, Elsevier, vol. 160(C), pages 919-930.
    7. Yang, Xiaoguang & Choi, Han Suk & Park, Chulhwan & Kim, Seung Wook, 2015. "Current states and prospects of organic waste utilization for biorefineries," Renewable and Sustainable Energy Reviews, Elsevier, vol. 49(C), pages 335-349.
    8. Silva, Sónia M. & Peixoto, Andreia F. & Freire, Cristina, 2020. "Organosulfonic acid functionalized montmorillonites as solid catalysts for (trans) esterification of free fatty acids and (waste) oils," Renewable Energy, Elsevier, vol. 146(C), pages 2416-2429.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Sánchez, M. & Clifford, B. & Nixon, J.D., 2018. "Modelling and evaluating a solar pyrolysis system," Renewable Energy, Elsevier, vol. 116(PA), pages 630-638.
    2. Panwar, N.L. & Kothari, Richa & Tyagi, V.V., 2012. "Thermo chemical conversion of biomass – Eco friendly energy routes," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(4), pages 1801-1816.
    3. Ozturk, Munir & Saba, Naheed & Altay, Volkan & Iqbal, Rizwan & Hakeem, Khalid Rehman & Jawaid, Mohammad & Ibrahim, Faridah Hanum, 2017. "Biomass and bioenergy: An overview of the development potential in Turkey and Malaysia," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 1285-1302.
    4. Ishtiaq Ahmed & Muhammad Anjum Zia & Huma Afzal & Shaheez Ahmed & Muhammad Ahmad & Zain Akram & Farooq Sher & Hafiz M. N. Iqbal, 2021. "Socio-Economic and Environmental Impacts of Biomass Valorisation: A Strategic Drive for Sustainable Bioeconomy," Sustainability, MDPI, vol. 13(8), pages 1-32, April.
    5. Mohsin Raza & Abrar Inayat & Ashfaq Ahmed & Farrukh Jamil & Chaouki Ghenai & Salman R. Naqvi & Abdallah Shanableh & Muhammad Ayoub & Ammara Waris & Young-Kwon Park, 2021. "Progress of the Pyrolyzer Reactors and Advanced Technologies for Biomass Pyrolysis Processing," Sustainability, MDPI, vol. 13(19), pages 1-42, October.
    6. Aboagye, D. & Banadda, N. & Kiggundu, N. & Kabenge, I., 2017. "Assessment of orange peel waste availability in ghana and potential bio-oil yield using fast pyrolysis," Renewable and Sustainable Energy Reviews, Elsevier, vol. 70(C), pages 814-821.
    7. Mahtta, Richa & Joshi, P.K. & Jindal, Alok Kumar, 2014. "Solar power potential mapping in India using remote sensing inputs and environmental parameters," Renewable Energy, Elsevier, vol. 71(C), pages 255-262.
    8. Karatayev, Marat & Clarke, Michèle L., 2016. "A review of current energy systems and green energy potential in Kazakhstan," Renewable and Sustainable Energy Reviews, Elsevier, vol. 55(C), pages 491-504.
    9. Hosseini, Seyed Ehsan & Wahid, Mazlan Abdul, 2014. "Development of biogas combustion in combined heat and power generation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 40(C), pages 868-875.
    10. Jun Sheng Teh & Yew Heng Teoh & Heoy Geok How & Thanh Danh Le & Yeoh Jun Jie Jason & Huu Tho Nguyen & Dong Lin Loo, 2021. "The Potential of Sustainable Biomass Producer Gas as a Waste-to-Energy Alternative in Malaysia," Sustainability, MDPI, vol. 13(7), pages 1-31, April.
    11. Dey, Subhashish & Sreenivasulu, Anduri & Veerendra, G.T.N. & Rao, K. Venkateswara & Babu, P.S.S. Anjaneya, 2022. "Renewable energy present status and future potentials in India: An overview," Innovation and Green Development, Elsevier, vol. 1(1).
    12. Aikifa Raza & Jin-You Lu & Safa Alzaim & Hongxia Li & TieJun Zhang, 2018. "Novel Receiver-Enhanced Solar Vapor Generation: Review and Perspectives," Energies, MDPI, vol. 11(1), pages 1-29, January.
    13. Qi, Jianhui & Zhao, Jianli & Xu, Yang & Wang, Yongjia & Han, Kuihua, 2018. "Segmented heating carbonization of biomass: Yields, property and estimation of heating value of chars," Energy, Elsevier, vol. 144(C), pages 301-311.
    14. Sofia Dahlgren & Jonas Ammenberg, 2021. "Sustainability Assessment of Public Transport, Part II—Applying a Multi-Criteria Assessment Method to Compare Different Bus Technologies," Sustainability, MDPI, vol. 13(3), pages 1-30, January.
    15. Zang, Guiyan & Zhang, Jianan & Jia, Junxi & Lora, Electo Silva & Ratner, Albert, 2020. "Life cycle assessment of power-generation systems based on biomass integrated gasification combined cycles," Renewable Energy, Elsevier, vol. 149(C), pages 336-346.
    16. Fanta Barry & Marie Sawadogo & Maïmouna Bologo (Traoré) & Igor W. K. Ouédraogo & Thomas Dogot, 2021. "Key Barriers to the Adoption of Biomass Gasification in Burkina Faso," Sustainability, MDPI, vol. 13(13), pages 1-14, June.
    17. Fang, Yiping & Wei, Yanqiang, 2013. "Climate change adaptation on the Qinghai–Tibetan Plateau: The importance of solar energy utilization for rural household," Renewable and Sustainable Energy Reviews, Elsevier, vol. 18(C), pages 508-518.
    18. Zhang, Zhonghao & Guo, Mengdi & Yu, Zhonghao & Yao, Siyue & Wang, Jin & Qiu, Diankai & Peng, Linfa, 2022. "A novel cooperative design with optimized flow field on bipolar plates and hybrid wettability gas diffusion layer for proton exchange membrane unitized regenerative fuel cell," Energy, Elsevier, vol. 239(PD).
    19. Field, John L. & Tanger, Paul & Shackley, Simon J. & Haefele, Stephan M., 2016. "Agricultural residue gasification for low-cost, low-carbon decentralized power: An empirical case study in Cambodia," Applied Energy, Elsevier, vol. 177(C), pages 612-624.
    20. Rawat, Rahul & Kaushik, S.C. & Lamba, Ravita, 2016. "A review on modeling, design methodology and size optimization of photovoltaic based water pumping, standalone and grid connected system," Renewable and Sustainable Energy Reviews, Elsevier, vol. 57(C), pages 1506-1519.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:197:y:2022:i:c:p:432-442. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.