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A new insight into the effects of agglomerate parameters on internal dynamics of proton exchange membrane fuel cell by an advanced impedance dimension model

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  • Yuan, Hao
  • Dai, Haifeng
  • Ming, Pingwen
  • Li, Sida
  • Wei, Xuezhe

Abstract

The oxygen reduction reaction with a relatively slow reaction rate is critical for proton exchange membrane (PEM) fuel cell performance. At present, a substantial part of the previous numerical study respecting the optimization design of the cathode catalyst layer (CCL) mainly focuses on the polarization curve output and oxygen local transport. In this paper, for the first time, a two-dimensional multiphase PEM fuel cell impedance model coupled with an improved electrochemical kinetics model considering the cathode agglomerate construction is proposed, which can reproduce the measured electrochemical impedance spectroscopy (EIS) under different current densities, reactant stoichiometries and inlet humidity only with a single boundary set. Based on this, the effects of five CCL design parameters (Pt loading, carbon loading, catalyst layer thickness, ionomer volume fraction, and agglomerate radius) on the EIS and critical internal dynamics are comprehensively investigated. Meanwhile, each dynamics loss of simulated EIS is identified by the distribution of relaxation time and equivalent circuit model to support quantitative analysis. These works offer a deeper understanding and new insight into the effects of CCL parameters on PEM fuel cell internal dynamics, which can help material optimization and system controller design.

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  • Yuan, Hao & Dai, Haifeng & Ming, Pingwen & Li, Sida & Wei, Xuezhe, 2022. "A new insight into the effects of agglomerate parameters on internal dynamics of proton exchange membrane fuel cell by an advanced impedance dimension model," Energy, Elsevier, vol. 253(C).
    • Handle: RePEc:eee:energy:v:253:y:2022:i:c:s0360544222011057
    DOI: 10.1016/j.energy.2022.124202
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    References listed on IDEAS

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    1. Baricci, Andrea & Mereu, Riccardo & Messaggi, Mirko & Zago, Matteo & Inzoli, Fabio & Casalegno, Andrea, 2017. "Application of computational fluid dynamics to the analysis of geometrical features in PEM fuel cells flow fields with the aid of impedance spectroscopy," Applied Energy, Elsevier, vol. 205(C), pages 670-682.
    2. Wu, Horng-Wen, 2016. "A review of recent development: Transport and performance modeling of PEM fuel cells," Applied Energy, Elsevier, vol. 165(C), pages 81-106.
    3. Hosseini, Mirollah & Afrouzi, Hamid Hassanzadeh & Arasteh, Hossein & Toghraie, Davood, 2019. "Energy analysis of a proton exchange membrane fuel cell (PEMFC) with an open-ended anode using agglomerate model: A CFD study," Energy, Elsevier, vol. 188(C).
    4. Xing, Lei & Liu, Xiaoteng & Alaje, Taiwo & Kumar, Ravi & Mamlouk, Mohamed & Scott, Keith, 2014. "A two-phase flow and non-isothermal agglomerate model for a proton exchange membrane (PEM) fuel cell," Energy, Elsevier, vol. 73(C), pages 618-634.
    5. Xing, Lei & Mamlouk, Mohamed & Scott, Keith, 2013. "A two dimensional agglomerate model for a proton exchange membrane fuel cell," Energy, Elsevier, vol. 61(C), pages 196-210.
    6. He, Pu & Mu, Yu-Tong & Park, Jae Wan & Tao, Wen-Quan, 2020. "Modeling of the effects of cathode catalyst layer design parameters on performance of polymer electrolyte membrane fuel cell," Applied Energy, Elsevier, vol. 277(C).
    7. Ismail, M.S. & Ingham, D.B. & Ma, L. & Hughes, K.J. & Pourkashanian, M., 2017. "Effects of catalyst agglomerate shape in polymer electrolyte fuel cells investigated by a multi-scale modelling framework," Energy, Elsevier, vol. 122(C), pages 420-430.
    8. Zeng, Tao & Zhang, Caizhi & Zhou, Anjian & Wu, Qi & Deng, Chenghao & Chan, Siew Hwa & Chen, Jinrui & Foley, Aoife M., 2021. "Enhancing reactant mass transfer inside fuel cells to improve dynamic performance via intelligent hydrogen pressure control," Energy, Elsevier, vol. 230(C).
    9. Yuan, Hao & Dai, Haifeng & Ming, Pingwen & Wang, Xueyuan & Wei, Xuezhe, 2021. "Quantitative analysis of internal polarization dynamics for polymer electrolyte membrane fuel cell by distribution of relaxation times of impedance," Applied Energy, Elsevier, vol. 303(C).
    10. Xing, Lei & Das, Prodip K. & Song, Xueguan & Mamlouk, Mohamed & Scott, Keith, 2015. "Numerical analysis of the optimum membrane/ionomer water content of PEMFCs: The interaction of Nafion® ionomer content and cathode relative humidity," Applied Energy, Elsevier, vol. 138(C), pages 242-257.
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    Cited by:

    1. Li, Li & Wang, Hongkang & Bei, Shaoyi & Li, Yuanjiang & Sun, Yanyun & Zheng, Keqing & Xu, Qiang, 2023. "Unsymmetrical design and operation in counter-flow microfluidic fuel cell: A prospective study," Energy, Elsevier, vol. 262(PB).
    2. Zhao, Lei & Yuan, Hao & Xie, Jiaping & Jiang, Shangfeng & Wei, Xuezhe & Tang, Wei & Ming, Pingwen & Dai, Haifeng, 2023. "Inconsistency evaluation of vehicle-oriented fuel cell stacks based on electrochemical impedance under dynamic operating conditions," Energy, Elsevier, vol. 265(C).
    3. Yuan, Hao & Zhou, Shulin & Zhang, Shaozhe & Tang, Wei & Jiang, Bo & Wei, Xuezhe & Dai, Haifeng, 2024. "Unconventional frequency response analysis of PEM fuel cell based on high-order frequency response function and total harmonic distortion," Applied Energy, Elsevier, vol. 357(C).
    4. Jiaping Xie & Hao Yuan & Yufeng Wu & Chao Wang & Xuezhe Wei & Haifeng Dai, 2023. "Impedance Acquisition of Proton Exchange Membrane Fuel Cell Using Deeper Learning Network," Energies, MDPI, vol. 16(14), pages 1-18, July.

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