IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v244y2022ipas0360544221029029.html
   My bibliography  Save this article

Combustion and slagging characteristics of hydrochar derived from the co-hydrothermal carbonization of PVC and alkali coal

Author

Listed:
  • Zhao, Peitao
  • Lin, Chuanjin
  • Li, Yilong
  • Zhang, Jing
  • Huang, Neng
  • Cui, Xin
  • Liu, Fang
  • Guo, Qingjie

Abstract

This work investigated on the effect of co-hydrothermal carbonization (co-HTC) of polyvinyl chloride (PVC) and alkali coal on combustion and slagging characteristics of the generated fuels (hydrochar). Fuel properties were assessed in terms of ultimate and proximate analysis, functional groups evolution, and ash melting characteristics. The loss of C–O functional groups in coal would be accompanied by the liberation of some elements such as Na and Ca, which were often associated with such groups. The hydrochars presented higher ignition temperature and average combustion rates compared with raw coal. The hydrochar generated from co-HTC at 250 °C showed the best combustion performance due to the enhancement of air contacting and transformation, which was attributed to its porous structure, smaller uniform particle, and relative higher surface area. The activation energy of hydrochars was increased at the ignition stage while was decreased at the combustion stage according to the kinetic analysis. The fusion temperature was increased resulting from the removal of alkali and alkaline earth metals (AAEMs) during the co-HTC process. From the perspective of waste-to-energy, the co-HTC of high-alkali coal and PVC seems to be a feasible solution to improve combustion and slagging characteristics.

Suggested Citation

  • Zhao, Peitao & Lin, Chuanjin & Li, Yilong & Zhang, Jing & Huang, Neng & Cui, Xin & Liu, Fang & Guo, Qingjie, 2022. "Combustion and slagging characteristics of hydrochar derived from the co-hydrothermal carbonization of PVC and alkali coal," Energy, Elsevier, vol. 244(PA).
    • Handle: RePEc:eee:energy:v:244:y:2022:i:pa:s0360544221029029
    DOI: 10.1016/j.energy.2021.122653
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544221029029
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2021.122653?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Li, Wei & Younger, Paul L. & Cheng, Yuanping & Zhang, Baoyong & Zhou, Hongxing & Liu, Qingquan & Dai, Tao & Kong, Shengli & Jin, Kan & Yang, Quanlin, 2015. "Addressing the CO2 emissions of the world's largest coal producer and consumer: Lessons from the Haishiwan Coalfield, China," Energy, Elsevier, vol. 80(C), pages 400-413.
    2. Zhang, Yongsheng & Zahid, Ibrar & Danial, Ali & Minaret, Jamie & Cao, Yijun & Dutta, Animesh, 2021. "Hydrothermal carbonization of miscanthus: Processing, properties, and synergistic Co-combustion with lignite," Energy, Elsevier, vol. 225(C).
    3. Ullah, Habib & Liu, Guijian & Yousaf, Balal & Ali, Muhammad Ubaid & Abbas, Qumber & Zhou, Chuncai & Rashid, Audil, 2018. "Hydrothermal dewatering of low-rank coals: Influence on the properties and combustion characteristics of the solid products," Energy, Elsevier, vol. 158(C), pages 1192-1203.
    4. Huang, Neng & Zhao, Peitao & Ghosh, Sudip & Fedyukhin, Alexander, 2019. "Co-hydrothermal carbonization of polyvinyl chloride and moist biomass to remove chlorine and inorganics for clean fuel production," Applied Energy, Elsevier, vol. 240(C), pages 882-892.
    5. Kim, Daegi & Park, Seyong & Park, Ki Young, 2017. "Upgrading the fuel properties of sludge and low rank coal mixed fuel through hydrothermal carbonization," Energy, Elsevier, vol. 141(C), pages 598-602.
    6. Yao, Zhongliang & Ma, Xiaoqian, 2017. "A new approach to transforming PVC waste into energy via combined hydrothermal carbonization and fast pyrolysis," Energy, Elsevier, vol. 141(C), pages 1156-1165.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Rocío García-Morato & Silvia Román & Beatriz Ledesma & Charles Coronella, 2023. "Co-Hydrothermal Carbonization of Grass and Olive Stone as a Means to Lower Water Input to HTC," Resources, MDPI, vol. 12(7), pages 1-14, July.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Yao, Zhongliang & Ma, Xiaoqian & Xiao, Zhiyuan, 2020. "The effect of two pretreatment levels on the pyrolysis characteristics of water hyacinth," Renewable Energy, Elsevier, vol. 151(C), pages 514-527.
    2. Wei, Yingyuan & Fakudze, Sandile & Zhang, Yiming & Ma, Ru & Shang, Qianqian & Chen, Jianqiang & Liu, Chengguo & Chu, Qiulu, 2022. "Co-hydrothermal carbonization of pomelo peel and PVC for production of hydrochar pellets with enhanced fuel properties and dechlorination," Energy, Elsevier, vol. 239(PD).
    3. Ullah, Habib & Liu, Guijian & Yousaf, Balal & Ali, Muhammad Ubaid & Abbas, Qumber & Zhou, Chuncai & Rashid, Audil, 2018. "Hydrothermal dewatering of low-rank coals: Influence on the properties and combustion characteristics of the solid products," Energy, Elsevier, vol. 158(C), pages 1192-1203.
    4. Zhang, Deli & Wang, Fang & Shen, Xiuli & Yi, Weiming & Li, Zhihe & Li, Yongjun & Tian, Chunyan, 2018. "Comparison study on fuel properties of hydrochars produced from corn stalk and corn stalk digestate," Energy, Elsevier, vol. 165(PB), pages 527-536.
    5. Ning, Xiaojun & Dang, Han & Xu, Runsheng & Wang, Guangwei & Zhang, Jianliang & Zhang, Nan & Wang, Chuan, 2022. "Co-hydrothermal carbonization of biomass and PVC for clean blast furnace injection fuel production: Experiment and DFT calculation," Renewable Energy, Elsevier, vol. 187(C), pages 156-168.
    6. Yang, Jie & Liu, Xiangrong & Yang, Zaiwen & Zhao, Shunsheng, 2023. "Biodegradation of Dananhu low-rank coal by Planomicrobium huatugouensis: Target metabolites possessing degradation abilities and their biodegradation pathways," Energy, Elsevier, vol. 276(C).
    7. Dilvin Cebi & Melih Soner Celiktas & Hasan Sarptas, 2022. "A Review on Sewage Sludge Valorization via Hydrothermal Carbonization and Applications for Circular Economy," Circular Economy and Sustainability, Springer, vol. 2(4), pages 1345-1367, December.
    8. Yongkang Yang & Qiaoyi Du & Chenlong Wang & Yu Bai, 2020. "Research on the Method of Methane Emission Prediction Using Improved Grey Radial Basis Function Neural Network Model," Energies, MDPI, vol. 13(22), pages 1-15, November.
    9. Lu, Xiaoluan & Ma, Xiaoqian & Chen, Xinfei, 2021. "Co-hydrothermal carbonization of sewage sludge and lignocellulosic biomass: Fuel properties and heavy metal transformation behaviour of hydrochars," Energy, Elsevier, vol. 221(C).
    10. Dang, Han & Xu, Runsheng & Zhang, Jianliang & Wang, Mingyong & Ye, Lian & Jia, Guoli, 2023. "Removal of oxygen-containing functional groups during hydrothermal carbonization of biomass: Experimental and DFT study," Energy, Elsevier, vol. 276(C).
    11. Lee, Jongkeun & Lee, Kwanyong & Sohn, Donghwan & Kim, Young Mo & Park, Ki Young, 2018. "Hydrothermal carbonization of lipid extracted algae for hydrochar production and feasibility of using hydrochar as a solid fuel," Energy, Elsevier, vol. 153(C), pages 913-920.
    12. Evgeny Chupakhin & Olga Babich & Stanislav Sukhikh & Svetlana Ivanova & Ekaterina Budenkova & Olga Kalashnikova & Olga Kriger, 2021. "Methods of Increasing Miscanthus Biomass Yield for Biofuel Production," Energies, MDPI, vol. 14(24), pages 1-30, December.
    13. Von Cossel, M. & Lebendig, F. & Müller, M. & Hieber, C. & Iqbal, Y. & Cohnen, J. & Jablonowski, N.D., 2022. "Improving combustion quality of Miscanthus by adding biomass from perennial flower-rich wild plant species," Renewable and Sustainable Energy Reviews, Elsevier, vol. 168(C).
    14. Lin, Yousheng & Ge, Ya & Xiao, Hanmin & He, Qing & Wang, Wenhao & Chen, Baiman, 2020. "Investigation of hydrothermal co-carbonization of waste textile with waste wood, waste paper and waste food from typical municipal solid wastes," Energy, Elsevier, vol. 210(C).
    15. Gavenas, Ekaterina & Rosendahl, Knut Einar & Skjerpen, Terje, 2015. "CO2-emissions from Norwegian oil and gas extraction," Energy, Elsevier, vol. 90(P2), pages 1956-1966.
    16. Zhao, Jun & Mangi, Hassan Nasir & Zhang, Zhenyue & Chi, Ru'an & Zhang, Haochen & Xian, Mengyu & Liu, Hong & Zuo, Haibin & Wang, Guangwei & Xu, Zhigao & Wu, Ming, 2022. "The structural characteristics and gasification performance of cokes of modified coal extracted from the mixture of low-rank coal and biomass," Energy, Elsevier, vol. 258(C).
    17. Eunhye Song & Ho Kim & Kyung Woo Kim & Young-Man Yoon, 2023. "Characteristic Evaluation of Different Carbonization Processes for Hydrochar, Torrefied Char, and Biochar Produced from Cattle Manure," Energies, MDPI, vol. 16(7), pages 1-14, April.
    18. Park, Jonghyun & Yim, Jun Ho & Cho, Seong-Heon & Jung, Sungyup & Tsang, Yiu Fai & Chen, Wei-Hsin & Jeon, Young Jae & Kwon, Eilhann E., 2024. "A virtuous cycle for thermal treatment of polyvinyl chloride and fermentation of lignocellulosic biomass," Applied Energy, Elsevier, vol. 362(C).
    19. Gao, Mingqiang & Cheng, Cheng & Miao, Zhenyong & Wan, Keji & He, Qiongqiong, 2023. "Physicochemical properties, combustion kinetics and thermodynamics of oxidized lignite," Energy, Elsevier, vol. 268(C).
    20. Cheng, Chen & Ding, Lu & Guo, Qinghua & He, Qing & Gong, Yan & Alexander, Kozlov N. & Yu, Guangsuo, 2022. "Process analysis and kinetic modeling of coconut shell hydrothermal carbonization," Applied Energy, Elsevier, vol. 315(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:244:y:2022:i:pa:s0360544221029029. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.